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Vision and Voyages for Planetary Science in the - Solar System ...

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Astrobiology is <strong>the</strong> study of <strong>the</strong> orig<strong>in</strong>, evolution, <strong>and</strong> distribution of life <strong>in</strong> <strong>the</strong> universe.<br />

Although it is unrealistic to look <strong>for</strong> life on primitive bodies, we know from <strong>the</strong> study of meteorites that<br />

many of <strong>the</strong>m conta<strong>in</strong> <strong>the</strong> organic <strong>in</strong>gredients <strong>for</strong> life. These organic compounds were <strong>for</strong>med as mantles<br />

on dust gra<strong>in</strong>s <strong>in</strong> cold <strong>in</strong>terstellar clouds <strong>and</strong> <strong>in</strong> <strong>the</strong> outer reaches of <strong>the</strong> solar nebula, <strong>and</strong> <strong>in</strong> rocks with<strong>in</strong><br />

<strong>the</strong> warmed <strong>in</strong>teriors of planetesimals as <strong>the</strong> ices <strong>in</strong> <strong>the</strong>se bodies melted. The compounds are surpris<strong>in</strong>gly<br />

complex <strong>and</strong> <strong>in</strong>clude am<strong>in</strong>o acids <strong>and</strong> o<strong>the</strong>r molecules that are central to life on Earth. The accretion of<br />

such materials, late <strong>in</strong> <strong>the</strong> assembly of planets, is thought to have been a possible first step <strong>in</strong> <strong>the</strong> poorly<br />

understood path from organic matter to organisms. Studies of <strong>the</strong> molecular <strong>for</strong>ms <strong>and</strong> isotopic<br />

compositions of <strong>the</strong> organic matter <strong>in</strong> meteorites <strong>and</strong> samples returned by spacecraft provide a prebiotic<br />

start<strong>in</strong>g po<strong>in</strong>t <strong>for</strong> <strong>the</strong> orig<strong>in</strong> <strong>and</strong> evolution of life or an <strong>in</strong>dependent channel of abiologic organic<br />

chemistry.<br />

Specific objectives <strong>for</strong> cont<strong>in</strong>ued advancement of this field <strong>in</strong> <strong>the</strong> com<strong>in</strong>g decade <strong>in</strong>clude <strong>the</strong><br />

follow<strong>in</strong>g:<br />

• Determ<strong>in</strong>e <strong>the</strong> composition, orig<strong>in</strong> <strong>and</strong> primordial distribution of volatiles <strong>and</strong> organic matter<br />

<strong>in</strong> <strong>the</strong> <strong>Solar</strong> <strong>System</strong>;<br />

• Underst<strong>and</strong> how <strong>and</strong> when planetesimals were assembled to <strong>for</strong>m planets; <strong>and</strong><br />

• Constra<strong>in</strong> <strong>the</strong> dynamical evolution of planets by <strong>the</strong>ir effects on <strong>the</strong> distribution of primitive<br />

bodies.<br />

Subsequent sections exam<strong>in</strong>es each of <strong>the</strong>se objectives <strong>in</strong> turn, <strong>and</strong> identify critical questions to<br />

be addressed <strong>and</strong> future <strong>in</strong>vestigations <strong>and</strong> measurements that could provide answers.<br />

Composition, Orig<strong>in</strong>, <strong>and</strong> Primordial Distribution<br />

of Volatiles <strong>and</strong> Organic Matter <strong>in</strong> <strong>the</strong> <strong>Solar</strong> <strong>System</strong><br />

Meteorites <strong>and</strong> <strong>in</strong>terplanetary dust particles are readily available sources of extraterrestrial<br />

organic matter from asteroids <strong>and</strong> comets, although <strong>the</strong> volatile species <strong>and</strong> organic components of<br />

comets <strong>and</strong> KBOs rema<strong>in</strong> poorly understood. <strong>System</strong>atic depletions <strong>in</strong> highly volatile elements <strong>in</strong><br />

meteorites testify to an important elemental fractionation <strong>in</strong> <strong>the</strong> early solar system, but it is not well<br />

understood. Some organic matter <strong>in</strong> chondrites, <strong>in</strong>terstellar dust particles, <strong>and</strong> Stardust comet samples has<br />

been structurally <strong>and</strong> isotopically characterized, although <strong>the</strong> <strong>in</strong>soluble organic fractions, consist<strong>in</strong>g of<br />

huge complex molecules, are extremely difficult to analyze. Underst<strong>and</strong><strong>in</strong>g <strong>the</strong> <strong>for</strong>mation <strong>and</strong> evolution<br />

of organic molecules <strong>in</strong> space <strong>and</strong> <strong>in</strong> planetesimals is essential to astrobiology. Telescopic spectral<br />

observations of primitive bodies provide at best a tantaliz<strong>in</strong>g but <strong>in</strong>complete picture of <strong>the</strong> orbital<br />

distribution of organic matter <strong>in</strong> <strong>the</strong> early solar system.<br />

The planetary science community has made progress <strong>in</strong> characteriz<strong>in</strong>g <strong>the</strong> <strong>in</strong>soluble<br />

(macromolecular) organic matter <strong>and</strong> <strong>in</strong> analyz<strong>in</strong>g <strong>the</strong> isotopic compositions of specific organic<br />

compounds <strong>in</strong> chondrites. 21,22,23 The changes <strong>in</strong> organic matter caused by parent body alteration are now<br />

better understood, <strong>and</strong> <strong>the</strong> fractionation of isotopes dur<strong>in</strong>g <strong>the</strong> evaporation of volatile elements has been<br />

modeled. Cometary organic matter <strong>and</strong> volatile elements have been analyzed <strong>in</strong> samples returned by <strong>the</strong><br />

Stardust spacecraft, 24,25,26 <strong>and</strong> cometary volatiles are now recognized to be heterogeneous as determ<strong>in</strong>ed<br />

by <strong>the</strong> Deep Impact spacecraft. 27 Spectroscopy of recently discovered KBOs has provided some<br />

constra<strong>in</strong>ts on <strong>the</strong>ir surface compositions. 28 Comparison of meteoritic <strong>and</strong> cometary organic matter<br />

<strong>in</strong>ventories with <strong>the</strong> composition of young circumstellar disks has been facilitated by recent Spitzer<br />

telescope observations. 29<br />

PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION<br />

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