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health and safety plan solid waste management unit assessment

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JP-4 (JET FUEL 4) 64-21<br />

Volatilization of JP-4 hydrocarbons in soil is another potential<br />

source of human exposure. Exposures may be more intensive when the<br />

soil is contaminated directly from leaking underground storage tanks<br />

<strong>and</strong> pipes, rather than from spills. In such cases, the more volatile<br />

components do not have an opport<strong>unit</strong>y to evaporate before penetrating<br />

the soil. Once in the soil, the hydrocarbons evaporate, saturating the<br />

air in the soil pores, <strong>and</strong> the vapors diffuse in all directions<br />

including upward to the surface. The vapors may diffuse into the<br />

basements of homes or other structures in the area, resulting in<br />

inhalation exposures to the buildings' occupants.<br />

64.2.4 Other Sources of Human Exposure<br />

The volatile nature of JP-4 fuel suggests that inhalation exposures<br />

to residents in the vicinity of air fields may occur during<br />

large spills. Volatilization also occurs during routine fuel h<strong>and</strong>ling<br />

operations <strong>and</strong> from fuel losses during the cooling of jet engines<br />

(1811) t but these sources are expected to result in negligible<br />

exposures to residents in the area. Workers in the immediate area<br />

could receive much greater exposures, however.<br />

Human exposure to JP-4 fuel may result from fuel-jettisoning by<br />

aircraft. The effect of the evaporated fuel vapors is considered<br />

negligible (1912), but several exposure pathways exist for the fraction<br />

reaching the ground.<br />

The composition <strong>and</strong> fraction of the jettisoned JP-4 fuel that<br />

reaches the ground depends upon the altitude of its release <strong>and</strong> the<br />

temperature at ground level. For example, at a ground temperature of<br />

-20-C, over 20% of the JP-4 released below 400 meters may reach the<br />

ground but at a ground temperature of 2O'C, less that 1% of the JP-4<br />

fraction will reach the ground regardless of the altitude of release.<br />

At altitudes above 3000 meters, release height has almost no effect on<br />

the JP-4 fraction reaching the ground: however the surface area of fuel<br />

distribution will be affected (1913).<br />

Because the volume of fuel released in a jettison may range from a<br />

few thous<strong>and</strong> to over 50,000 liters (1912), the amount reaching the<br />

ground may lead to significant human exposure if released at a lov<br />

altitude. Contamination of surface water, crops <strong>and</strong> pasture l<strong>and</strong> may<br />

result in human ingestion. However, significant human exposure is<br />

expected to be rare since Air Force directives specify that, whenever<br />

possible, release be made over unpopulated areas <strong>and</strong> at altitudes above<br />

1500 meters (6000 meters in some aircrafts) (1912).<br />

6/87

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