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health and safety plan solid waste management unit assessment

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AUTOMOTIVE GASOLINE 65-l<br />

COMMON SYNONYMS:<br />

Petrol<br />

Motor spirits<br />

Benxin<br />

CAS REG. NO.:<br />

8006-61-g<br />

NIOSH NO.:<br />

LX3300000<br />

APPROXIMATE COMPOSITION:<br />

n-alkanas B-17% branched alkanes 28-360<br />

cycloalkanes<br />

benxenes <strong>and</strong><br />

3-5% olefins l-11%<br />

naphthalanes ~1%<br />

alkylbenxenes 20-498<br />

AIR W/V CONVERSION<br />

FACTORS at 25'C (2228)<br />

4.5 mg/d - 1 ppm<br />

0.222 ppm - 1 mg/Il<br />

Several sources indicate that strong acids or strong<br />

oxidizers are incompatible with gasoline <strong>and</strong> that vigorous<br />

reactions, ignition, <strong>and</strong>/or explosion may be expected. The<br />

NFPA specifically notes such events when chlorine, fluorine,<br />

or magnesium perchlorate are mixed with hydrocarbons.<br />

REACTIVITY<br />

Gasoline is considered a miscellaneous combustible or<br />

flaamaable material for compatibility classification<br />

purposes. Such substances typically evolve heat, fire, <strong>and</strong><br />

toxic or flammable gases in reactions with oxidizing mineral<br />

acids, alkali or alkaline earth elemental metals, nitrides,<br />

organic peroxides or hydroperoxides, or strong oxidizing<br />

agents. Reactions with explosive materials may result in an<br />

explosion, while those with strong reducing agents may<br />

evolve heat <strong>and</strong> flammable gaseo. Non-oxidizing mineral<br />

acids generally evolve heat <strong>and</strong> innocuous gases<br />

(51,505,507,511).<br />

PHYSICO-<br />

CHEMICAL<br />

DATA<br />

l Physical State (at 2O'C): liquid<br />

Color: colorless to pale brown or pink<br />

Odor: characteristic<br />

Odor Threshold: 0.25 ppm<br />

Liquid Density (g/ml at 20-C): 0.7321<br />

Freezing/Melting Point ('C): no data<br />

Boiling Point ('C): 60-199, 38-204<br />

Flash Point ('C): -38 to -46, closed cup,<br />

&pending on grade<br />

Flammable Limits in Air, 8 by Volume: 1.2-1.5%<br />

to 7.1-7.69 &pending on grade<br />

0 Autoignition Temperature ('C): 257-471, varies<br />

with grade<br />

l Vapor Pressure (nnr Hg at 38'C): 263-675<br />

0 Saturated Concentration in Air<br />

0<br />

0<br />

0<br />

bg/ms at 20-C): no data ( ><br />

Solubility in Water (mg/L at 2O'C): insoluble (60)<br />

Vfscosity (cp at 2O'C): 0.451 (60)<br />

Surface Tension (dyne/cm at 2O'C): 19-23 (60)<br />

(60)<br />

(60)<br />

(54960)<br />

(60)<br />

(60)<br />

(60)<br />

(60,391<br />

(60,506,<br />

507)<br />

(60,504,<br />

506,507)<br />

(51,60,507.<br />

510,513)<br />

(1932).<br />

6/87<br />

-~_-<br />

--.- .___Lc~--_____--

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