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health and safety plan solid waste management unit assessment

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METHYL ETHYL KETONE 41-2<br />

PERSISTENCE<br />

IN THE SOIL-<br />

WATER SYSTEM<br />

J<br />

Methyl ethyl ketone is expected to migrate in the<br />

soil/ground-water system with very little retardation.<br />

Volatilization from near-surface soils may occur: however,<br />

vapor concentrations in soil are expected to be very low<br />

whenever water is present. Biodegradation of methyl ethyl<br />

ketone has been demonstrated <strong>and</strong> persistence in environments<br />

with active microbial populations is not expected.<br />

The primary pathway of concern from a soil/ground-water<br />

PATHWAYS system is the migration of methyl ethyl ketone to ground-<br />

OF water drinking water supplies. Inhalation may be important<br />

EXPOSURE in some situations. Bioaccumulation of methyl ethyl ketone<br />

is not likely to be an important exposure pathway.<br />

I I 1<br />

HEALTH '<br />

<strong>and</strong> Svmotoms of Short w term Hmosure (131 .<br />

Eye, nose <strong>and</strong> throat irritation are usually the first<br />

symptoms to appear in methyl ethyl ketone exposure.' At high<br />

concentrations, CNS depression <strong>and</strong> narcosis along with congestion<br />

of the lungs, liver <strong>and</strong> kidneys are observed.<br />

.<br />

1 Studies .<br />

DATA<br />

WO h/W Us0 h3/ms)<br />

.oral 2737 [rat] (47) inhalation [mouse]<br />

skin 13,000 [rabbit] (47) 40,000*2 hr (47)<br />

HANDLING<br />

PRECAUTIONS<br />

(54)<br />

H<strong>and</strong>le chemical only with adequate ventilation l Vapor concentration<br />

of 200 - 1000 ppm: chemical cartridge respirator<br />

with organic vapor cartridge <strong>and</strong> full facepiece l 1000 -<br />

30,000 ppm: gas mask with organic vapor canister, any supplied<br />

air respirator or self-contained breathing apparatus<br />

with full facepiece l Butyl, natural rubber, neoprene, nitrile,<br />

PE, WA or WC gloves, apron <strong>and</strong> boots to prevent repeated<br />

or prolonged skin contact with the liquid l Chemical<br />

goggles if there is probability of eye contact.<br />

m: Give large quantities of salt water <strong>and</strong> induce<br />

EMERGENCY vomiting if victim is conscious. Get medical attention<br />

FIRST AID l -ation: Move victim to fresh air immediately <strong>and</strong> per-<br />

TREATMENT form artifical respiration if necessary l u: Remove con-<br />

(54) taminated clothing. Wash skin with soap <strong>and</strong> water l Eya:<br />

Irrigate with large amounts of water immediately.<br />

I I I<br />

5/87

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