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AUTOMOTIVE GASOLINE 65-11 TABLE 65-2 GASODE - Continued ADDITIVESa Corrosion Inhibitors MIL-I-25017/QPL-25017= Carboxylic acids Phosphoric acids Sulfonic acids e erences 1409,2325,2326,2327,2328,1847 baRf Compounds addressed in other chapters of IRP Toxicology Guide 'As cited in 2328 65.2 ENVIRONMENTAL FATE AND EXPOSURE PATHWAYS In this chapter, the discussions of the environmental behavior of gasoline will be limited to a' tiiscussion of its major components; the environmental behavior of the trace elements and the many diverse additives will not specifically be addressed. Many of the hydrocarbons characteristics of gasoline hava been addressed previously in the more extensive environmental fate section of the JP-4 chapter since these hydrocarbons are common to both petroleum fuels. The general discussions of aliphatic and aromatic hydrocarbons and their behavior in soil/ground-water systems will not be repeated here; the reader is referred to the relevant sections of Chapter 64. Transport and transformation of individual gasoline constituents will depend on the physicochemical (and biological) properties of the constituents. Some constituents will dissolve more quickly (in the percolating ground waters), be sorbed less strongly on the soils (thus being transported more rapidly), and may be more or less susceptible to degradation by chemical or biological action. Thus, as shown in Figure 65-1, the relative concentrations of the constituents of the fuel will vary with time and distance from the site of contamination. This effect is called "weathering." (This term is also used to describe the changes to oil following spills into surface waters where film spreading and breakup, and differential volatilization, dissolution and degradation are all involved.) 65.2.1 Transport in Soil/Ground-water Systems 65.2.1.1 Equilibrium Partitioning Model In general, soil/ground-water transport pathways for low concentrations of pollutants in soil can be assessed by using an equilibrium partitioning model. For the purposes of assessing the environmental transport of automotivs gasoline, a group of specific 6/87 “_
AUTOMOTIVE GASOLINE 65-12 a. initial ‘Spike’ profile after release to environment . at Point x. A, 8, and C are chemicals in the mixture (e.g., gasoline). Well X Distance - (and direction of ground water flow) b. Profiles of A, 8, C after transport with flowing ground water for some time. Well X Distance - FIGURE 65-l SCHEMATIC SHOWING DIFFERING DEGREES OF RETARDATION OF MIXTURE CHEMICALS TEANSPORTEL'BY F'UJWING GROUND WATER NOTE: Effects of degradation are not shown; but they would have the effect of lowering peak heights and area under each curve. 6/87
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Environmental and Safety Designs, I
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Table of Contents 1.0 2.0 3.0 4.0 5
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1.0 INTRODUCTION The following Heal
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3.0 SITE CHARACTERIZATION Health an
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CAMP LEJEUNE NORTH CAROLINA I
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Health and Safety Plan Solid Waste
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5.0 HAZARD EVALUATION Health and Sa
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Marine Health and Safety Plan Solid
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Health ana’ Safety Plan Solid Was
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6.0 EMPLOYEE PROTECTION Health and
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l a Standard safe operating procedu
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7.0 TEMPERATURE EXPOSURE GUIDELINES
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9.0 EXPOSURE EVALUATION Health and
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12.0 SITE CONTINGENCY PLAN Health a
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12.3 Site Resources Health and Safe
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PLAN ACCEPTANCE Health and Safety P
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APPENDIX A MSDS ..,~. .- _ - -__..
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FUEL OILS 66-2 l Physical State (at
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FUEL OILS 66-4 bIR EXPOSURE LIMITS:
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FTJELOILS 66-6 l State Water Progra
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FUEL OILS 66-8 66.1 MAJOR USES Fuel
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FUELOILS 66-10 TABLE 66-2 COMMON AD
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TABLE 66-3 EQUILIRRIUN PAPllOWlYt O
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FUEL OILS Migration through soils m
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PUEL OILS 66-16 relatively small fr
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FUEL OILS 66-18 TABLE 66-4 POTENCIE
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FUEL OILS 66-20 66.3.1.4 Other Toxi
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FUELOILS 66-22 66.3.1.4.2 Chronic T
Page 93 and 94: FUEL OILS 66-24 TABLE 66-5 ACUTE TO
Page 95 and 96: FUEL OILS 66-26 Iso-octg~lf: (2,2,4
Page 97 and 98: FUEL OILS 66-28 Ethyl benzene is pr
Page 99 and 100: FUEL OILS 66-30 AC d Methemoglobine
Page 101 and 102: JP-4 (JET FUEL 4) 64-1 APPROXIMATE
Page 103 and 104: JP-4 (JET FUEL 4) 64-3 HANDLING PRE
Page 105 and 106: JP-4 (JET FUEL 4) 64-5 REGULATORY S
Page 107 and 108: JP-4 (JET FUEL 4) 64-7 64.1 MAJOR U
Page 109 and 110: JP-4 (JET FUEL 4) 64-9 TABLE 64-1 -
Page 111 and 112: JP-4 (JET FUEL 4) 64-11 TABLE 64-2
Page 113 and 114: JP-4 (JET FUEL 4) 64-13 solubility.
Page 115 and 116: JP-4 (JET FUEL 4) 64-15 Compared wi
Page 117 and 118: JP-4 (JET FUEL 4) 64-17 TABLE 64-5
Page 119 and 120: JP-4 (JET FUEL 4) 64-19 Although th
Page 121 and 122: JP-4 (JET FUEL 4) 64-21 Volatilizat
Page 123 and 124: JP-4 (JET NEL 4) 64-23 In tests con
Page 125 and 126: JP-4 (JET FUEL 4) headache, nausea,
Page 127 and 128: JP-4 (JET FUEL 4) 64-27 Paralysis d
Page 129 and 130: JP-4 (JET FUEL 4) 64-29 exposed to
Page 131 and 132: JP-4 (JET FUEL 4) 64-31 mg/kg and 1
Page 133 and 134: JP-4 (JET FUEL 4) 64-33 various col
Page 135 and 136: AUTOMOTIVE GASOLINE 65-2 PHYSICO- C
Page 137 and 138: AUTOMOTIVE GASOLINE 65-4 kIR EXPOSU
Page 139 and 140: AUTOMOTIVE GASOLINE 65-6 Directives
Page 141 and 142: AUTOMOTIVE GASOLINE 65-8 65.1 MAJOR
Page 143: AUTOMOTIVE GASOLINE 65-10 TABLE 65-
Page 147 and 148: TABLE 65-3 EQUILIBRIUN PARflOYlYG O
Page 149 and 150: AUTOMOTIVE GASOLIt@i 65-16 Some res
Page 151 and 152: 65-18 Although the microbiota of mo
Page 153 and 154: AUTOMOTIVE GASOLINE 65-20 higher. A
Page 155 and 156: AUTOHOTIVE GASOLINE 65-22 Tests for
Page 157 and 158: AUTOMOTIVE GASOLINE 65-24 experimen
Page 159 and 160: AUTOMOTIVE GASOLINE 65-26 cancer hy
Page 161 and 162: AUTOMOTIVE GASOLINE 65-28 10 months
Page 163 and 164: AUTOMOTIVE GASOLINE 65-30 The trime
Page 165 and 166: AUTOMOTIVE GASOLINE 65-32 spontaneo
Page 167 and 168: AUTOMOTIVE GASOLINE 65-34 even the
Page 169 and 170: STODDARD SOLVENT 67-2 0 Log (Octano
Page 171 and 172: STODDARD SOLVENT 67-L JR EXPOSURE L
Page 173 and 174: STODDARD SOLVENT 67-6 EEC Directive
Page 175 and 176: STODDARD SOLVENT 67-8 67.1 MAJOR US
Page 177 and 178: TARLE 67-2 EQUlLlSRlUN PARlIOYIY6 O
Page 179 and 180: STODDARD SOLVENT 67-12 aliphatics,
Page 181 and 182: STODDARD SOLVENT 67-14 incidence co
Page 183 and 184: STODDARD SOLVENT 67-16 67.3.2 Human
Page 185 and 186: STODDARD SOLVENT 67-18 the site of
Page 187 and 188: STODDARD SOLVENT 67-2 l Log (Octano
Page 189 and 190: STODDARD SOLVENT 67-G RNVTRONBENTAL
Page 191 and 192: STODDARD SOLVENT 67-6 (538) Direct
Page 193 and 194: STODDARD SOLVENT 67-8 67.1 MAJOR US
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IAOLE 67-2 EQUILI~RIUI PARflOYIYG O
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STODDARD SOLVENT 67-12 aliphatics.
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STODDARD SOLVENT 67-14 incidence we
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STODDARD SOLVENT 67-16 67.3.2 Human
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STODDARD SOLVENT 67-18 the site of
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HYDRAULIC FLUID 68-2 I PERSISTENCE
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~RALJLIC FLUID 68-32 the constituen
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HYDRAULIC FLUID 6814 REGULATORY STA
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HYDRAULIC FLUID 68-6 Directive on T
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TABLE 68-l 3 $ HYDRAULIC OILS 3 Fa
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TABLE 68-l - Continued HYDRAULIC OI
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. TABLE 68-1 - Continued HYDRAULIC
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TABLE 68-l - Continued HYDRAULIC OI
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HYDRAULIC FLUID 68-16 TABLE 68-2 -
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HYDRAULIC FLUID 68-18 TABLE 68-3 SO
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HYDRAULIC FLUID 68-20 Transport and
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HYDRAULIC FLUID 68-22 high volatili
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HYDRAULIC FLUID 68-24 reaction at 2
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HYDSWJLIC FLUID 68-26 TABLE,68-4 AC
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HYDRAULIC FLUID 68-28 transient irr
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HYDRAULIC FLUID 68-30 BHT is mildly
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METHYL ETHYL KETONE 41-a TABLE 41-1
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METMYL ETHYL KETONE 41-6 EEC DfrGti
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METHYL ETRYL KETONE 41-4 Promubted
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METHYL ETHYL KETONE 41-2 PERSISTENC
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MBTHYL ETHYL KETONE 41-10 ketone th
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METHYL ETHYL KETONE 41-12 41.3.1.2
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METHYiL ETHYL KETONE 41-14 axons in
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METHYL ETHYL KETONE 41-16 41.3.4 Ha
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ETHYLENE GLYCOL 43-l COMMON SYNONYM
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ETHYLENE CLYCOL 43-3 ENVIRONMENTAL
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ETWLENE GLYCOL 43-5 43.1 MAJOR USES
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EIWLENE GLYCOL 43-7 Data on ethylen
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ETHYLENE GLYCOL 43-9 animals) verte
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ETHYLmE GLYCOL 43-11 The effect of
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- .-.- ---_ -. _ I_T_-- ETHYLENE GL
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