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STODDARD SOLVENT 67-7 fuels), they are considered preparations and their labeling shall be done in accordance with the procedures outlined in the Directive Relating to the Classification, Packaging and Labeling of Dangerous Preparations (solvents). Directives - ProooseQ proDosa1 for a Coq&JJ&rDfrcctive on m of- at Sea (1793) EEC has proposed that the dumping carbons, lubricants and hydraulic of crude oil. fluids at sea petroleum hydrobe prohibited. 6/87
STODDARD SOLVENT 67-8 67.1 MAJOR USES AND COHPOSITION 67.1.1 Major Uses Stoddard solvent is produced from a straight-run distillate of paraffinic or mixed base crude oil. It is used as a diluent in paints, coatings and waxes: as a dry cleaning agent: as a degreaser and cleaner and as a herbicide (2). 67.1.2 Composition Stoddard solvent 1s a mixture of C, through C,, hydrocarbons, predominantly C, through C,,, with a boiling range between 160-C to 210-c. Flashpoint dry-point test and o&r data are used to classify Stoddard solvent into the following four types: regular Stoddard solvent, 140 flash solvent, odorless solvent, and low end point solvent. Chemically, Stoddard solvent is a mixture.of N-50% straight and branched alkanes, 30-409 cycloalkanes, and lo-200 aromatics. Benzene and oleflns are present in trace quantities only (1967,2228). The 140 flash aliphatlc solvent is compased of organic compounds with carbon chain lengths ranging from CS to C12. Its boiling range is MS-207'C and it is composed of 60.8% paraffins, 24.5% monocycloparaffins, 11.2% dlcycloparaffins, 3.03% alkyl benzenes, 0.3% indans and tetralins, and 0.07% benzenes (1967). Both types will be discussed in some sections of the chapter which follows. A characterization of the individual hydrocarbon components of Stoddard solvent was not available. Table 67-l presents the available characterization by chemical classes. 67.2 ENVIRONMENTAL FATE AND EXPOSURE PATHWAYS A dlscusslon.of the environmental behavior of Stoddard solvent is limited by the lack of analytical data defining its specific components. Many of the hydrocarbons expected to be components of Stoddard solvent were addressed previously in the more extensive environmental fate section of Chapter 64. The general discussions of allphatic and aromatic hydrocarbons and their behavior in soil/ground-water systems ~111 not be repeated here; the reader is referred to the relevant sections of Chapter 64. 67.2.1 Equilibrium Partitioning Model In general, soil/ground-water transport pathways for low concentrations of pollutants in sol1 can be assessed by using an equilibrium partitioning model. For the purposes of assessing the environmental transport of Stoddard solvent, a group of specific hydrocarbons within the C,-C,, range was selected from the dominant hydrocarbon classes, i.e., alkanes, cycloalkanes, and aromatics; there are no available data to confirm the presence of the selected 6/87
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Environmental and Safety Designs, I
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Table of Contents 1.0 2.0 3.0 4.0 5
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1.0 INTRODUCTION The following Heal
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3.0 SITE CHARACTERIZATION Health an
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CAMP LEJEUNE NORTH CAROLINA I
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Health and Safety Plan Solid Waste
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5.0 HAZARD EVALUATION Health and Sa
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Marine Health and Safety Plan Solid
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Health ana’ Safety Plan Solid Was
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6.0 EMPLOYEE PROTECTION Health and
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l a Standard safe operating procedu
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7.0 TEMPERATURE EXPOSURE GUIDELINES
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9.0 EXPOSURE EVALUATION Health and
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12.0 SITE CONTINGENCY PLAN Health a
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12.3 Site Resources Health and Safe
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PLAN ACCEPTANCE Health and Safety P
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APPENDIX A MSDS ..,~. .- _ - -__..
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FUEL OILS 66-2 l Physical State (at
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FUEL OILS 66-4 bIR EXPOSURE LIMITS:
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FTJELOILS 66-6 l State Water Progra
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FUEL OILS 66-8 66.1 MAJOR USES Fuel
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FUELOILS 66-10 TABLE 66-2 COMMON AD
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TABLE 66-3 EQUILIRRIUN PAPllOWlYt O
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FUEL OILS Migration through soils m
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PUEL OILS 66-16 relatively small fr
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FUEL OILS 66-18 TABLE 66-4 POTENCIE
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FUEL OILS 66-20 66.3.1.4 Other Toxi
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FUELOILS 66-22 66.3.1.4.2 Chronic T
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FUEL OILS 66-24 TABLE 66-5 ACUTE TO
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FUEL OILS 66-26 Iso-octg~lf: (2,2,4
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FUEL OILS 66-28 Ethyl benzene is pr
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FUEL OILS 66-30 AC d Methemoglobine
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JP-4 (JET FUEL 4) 64-1 APPROXIMATE
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JP-4 (JET FUEL 4) 64-3 HANDLING PRE
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JP-4 (JET FUEL 4) 64-5 REGULATORY S
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JP-4 (JET FUEL 4) 64-7 64.1 MAJOR U
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JP-4 (JET FUEL 4) 64-9 TABLE 64-1 -
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JP-4 (JET FUEL 4) 64-11 TABLE 64-2
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JP-4 (JET FUEL 4) 64-13 solubility.
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JP-4 (JET FUEL 4) 64-15 Compared wi
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JP-4 (JET FUEL 4) 64-17 TABLE 64-5
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JP-4 (JET FUEL 4) 64-19 Although th
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JP-4 (JET FUEL 4) 64-21 Volatilizat
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JP-4 (JET NEL 4) 64-23 In tests con
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JP-4 (JET FUEL 4) headache, nausea,
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JP-4 (JET FUEL 4) 64-27 Paralysis d
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JP-4 (JET FUEL 4) 64-29 exposed to
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JP-4 (JET FUEL 4) 64-31 mg/kg and 1
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JP-4 (JET FUEL 4) 64-33 various col
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AUTOMOTIVE GASOLINE 65-2 PHYSICO- C
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AUTOMOTIVE GASOLINE 65-4 kIR EXPOSU
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AUTOMOTIVE GASOLINE 65-6 Directives
Page 141 and 142: AUTOMOTIVE GASOLINE 65-8 65.1 MAJOR
Page 143 and 144: AUTOMOTIVE GASOLINE 65-10 TABLE 65-
Page 145 and 146: AUTOMOTIVE GASOLINE 65-12 a. initia
Page 147 and 148: TABLE 65-3 EQUILIBRIUN PARflOYlYG O
Page 149 and 150: AUTOMOTIVE GASOLIt@i 65-16 Some res
Page 151 and 152: 65-18 Although the microbiota of mo
Page 153 and 154: AUTOMOTIVE GASOLINE 65-20 higher. A
Page 155 and 156: AUTOHOTIVE GASOLINE 65-22 Tests for
Page 157 and 158: AUTOMOTIVE GASOLINE 65-24 experimen
Page 159 and 160: AUTOMOTIVE GASOLINE 65-26 cancer hy
Page 161 and 162: AUTOMOTIVE GASOLINE 65-28 10 months
Page 163 and 164: AUTOMOTIVE GASOLINE 65-30 The trime
Page 165 and 166: AUTOMOTIVE GASOLINE 65-32 spontaneo
Page 167 and 168: AUTOMOTIVE GASOLINE 65-34 even the
Page 169 and 170: STODDARD SOLVENT 67-2 0 Log (Octano
Page 171 and 172: STODDARD SOLVENT 67-L JR EXPOSURE L
Page 173 and 174: STODDARD SOLVENT 67-6 EEC Directive
Page 175 and 176: STODDARD SOLVENT 67-8 67.1 MAJOR US
Page 177 and 178: TARLE 67-2 EQUlLlSRlUN PARlIOYIY6 O
Page 179 and 180: STODDARD SOLVENT 67-12 aliphatics,
Page 181 and 182: STODDARD SOLVENT 67-14 incidence co
Page 183 and 184: STODDARD SOLVENT 67-16 67.3.2 Human
Page 185 and 186: STODDARD SOLVENT 67-18 the site of
Page 187 and 188: STODDARD SOLVENT 67-2 l Log (Octano
Page 189 and 190: STODDARD SOLVENT 67-G RNVTRONBENTAL
Page 191: STODDARD SOLVENT 67-6 (538) Direct
Page 195 and 196: IAOLE 67-2 EQUILI~RIUI PARflOYIYG O
Page 197 and 198: STODDARD SOLVENT 67-12 aliphatics.
Page 199 and 200: STODDARD SOLVENT 67-14 incidence we
Page 201 and 202: STODDARD SOLVENT 67-16 67.3.2 Human
Page 203 and 204: STODDARD SOLVENT 67-18 the site of
Page 205 and 206: HYDRAULIC FLUID 68-2 I PERSISTENCE
Page 207 and 208: ~RALJLIC FLUID 68-32 the constituen
Page 209 and 210: HYDRAULIC FLUID 6814 REGULATORY STA
Page 211 and 212: HYDRAULIC FLUID 68-6 Directive on T
Page 213 and 214: TABLE 68-l 3 $ HYDRAULIC OILS 3 Fa
Page 215 and 216: TABLE 68-l - Continued HYDRAULIC OI
Page 217 and 218: . TABLE 68-1 - Continued HYDRAULIC
Page 219 and 220: TABLE 68-l - Continued HYDRAULIC OI
Page 221 and 222: HYDRAULIC FLUID 68-16 TABLE 68-2 -
Page 223 and 224: HYDRAULIC FLUID 68-18 TABLE 68-3 SO
Page 225 and 226: HYDRAULIC FLUID 68-20 Transport and
Page 227 and 228: HYDRAULIC FLUID 68-22 high volatili
Page 229 and 230: HYDRAULIC FLUID 68-24 reaction at 2
Page 231 and 232: HYDSWJLIC FLUID 68-26 TABLE,68-4 AC
Page 233 and 234: HYDRAULIC FLUID 68-28 transient irr
Page 235 and 236: HYDRAULIC FLUID 68-30 BHT is mildly
Page 237 and 238: METHYL ETHYL KETONE 41-a TABLE 41-1
Page 239 and 240: METMYL ETHYL KETONE 41-6 EEC DfrGti
Page 241 and 242: METHYL ETRYL KETONE 41-4 Promubted
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METHYL ETHYL KETONE 41-2 PERSISTENC
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MBTHYL ETHYL KETONE 41-10 ketone th
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METHYL ETHYL KETONE 41-12 41.3.1.2
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METHYiL ETHYL KETONE 41-14 axons in
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METHYL ETHYL KETONE 41-16 41.3.4 Ha
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ETHYLENE GLYCOL 43-l COMMON SYNONYM
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ETHYLENE CLYCOL 43-3 ENVIRONMENTAL
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ETWLENE GLYCOL 43-5 43.1 MAJOR USES
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EIWLENE GLYCOL 43-7 Data on ethylen
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ETHYLENE GLYCOL 43-9 animals) verte
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ETHYLmE GLYCOL 43-11 The effect of
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- .-.- ---_ -. _ I_T_-- ETHYLENE GL
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