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health and safety plan solid waste management unit assessment

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STODDARD SOLVENT 67-2<br />

l Log (Octanol-Water Partition Coefficient),<br />

log K : 3.16-7.06 (f)<br />

PHYSICO- l Soil Ad&don Coefficient, Koc:<br />

CHEMICAL 700-5.5 x 10' ("1<br />

DATA l Henry's Law Constant (atm*m3/mol at 2O'C):<br />

(continued) 4.4 x lo-' - 7.4 (*)<br />

l Bioconcentration Factor: no data ( 1<br />

Stoddard solvent hydrocarbons are expected to be relatively<br />

mobile <strong>and</strong> moderately persistent in most soil systems. Persistence<br />

in deep soils <strong>and</strong> ground water may be higher. VOlatilization.<br />

photooxidation <strong>and</strong> biodegradation are potentially<br />

important fate procemses. Surface spills are expected to<br />

PERSISTENCE be weathered by evaporation <strong>and</strong> photooxidation. Downward mi-<br />

IN THE SOIL- gration of weathered surface spills <strong>and</strong> sub-surface dischar-<br />

WATER SYSTEM ges represent a potential threat to underlying ground water.<br />

Biodegradation of C,-C12 hydrocarbons is expected to be.significant<br />

under environmental conditions favorable to microbial<br />

oxidation: naturally-occurring, hydrocarbon-degrading<br />

microorganisms have been isolated from polluted soils <strong>and</strong>,<br />

to a lesser extent, non-polluted soils.<br />

PATHWAYS<br />

OF<br />

EXPOSURE<br />

Tne prrnrry pathway or concern rrom nne sorwgrouna-wa-r<br />

systems is the contamination of ground water drinking water<br />

supplies resulting from large spills of Stoddard solvent or<br />

leaking underground storage tanka. Vapors from leaked or<br />

spilled solvent mey diffuse through soils <strong>and</strong> migrate into<br />

strrrctures resulting In inhalation exposures. Inhalation<br />

exposures may also occur from the direct volatilization of<br />

surface spills. Ingestion with food is not expected to be<br />

significant.<br />

eye8,<br />

nose<br />

cause skin irritation.<br />

-- no data<br />

XL0 (mg/m3)<br />

inhalation [cat] (47)<br />

10,000*2.5 hr.<br />

Kar#O of ValWS for representative hydrocarbons from major component classes<br />

(see Table 67-2).<br />

6/87

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