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FUEL OILS 66-23 observed in the lung, nasal cavity and sinuses, digestive system, brain, skin, pancreas and kidney. Leukemias and lymphomas have also been reported (1817). 66.3.3 Toxicology of Fuel Oil Components A brief overview of the toxicology of the major hydrocarbon components of fuel oils are summarized below (see Table 66-5). n-Hew Hexane may be the most highly toxic member of the alkanes. When ingested, it causes nausea, vertigo, bronchial and general intestinal irritation and CNS effects. It also presents an acute aspiration hazard. Acute exposure occurs primarily through inhalation. Non-specific symptoms such as vertigo, headache, nausea and vomiting are the first to be manifested. At high concentrations, a narcosis-like state appears as a result of CNS depression. Pre-narcotic symptoms occur at vapor concentrations ranging from 1500-2500 ppm. n-Hexane irritates the eyes and mucous membranes. These effects can be seen after an exposure of 880 ppm for 15 minutes. Skin contact primarily causes fat removal an@ cutaneous irritation. Chronic exposure to n-hexane vapors causes peripheral neuropathy. The first clinical sign of neural damage is a feeling of numbness in the toes and fingers. Progression leads to further symmetrical sensory impairment muscular in the stretching distal portions reflexes. of the extremities and to loss of Ultimately, symmetrical muscular weakness Paralysis develops, develops chiefly with in the varying distal degrees portion of the extremities. of impaired grasping and walking; This may include muscular atrophy (sensorimotor polyneuropathy). The development of electrophysiological changes parallels the severity of the clinical. picture. In the most severe cases, neme conductivity is neutralized. In some cases, cranial nerve involvement is also observed. After exposure ceases, recovery begins within 6 to 10 months in mild to moderate cases, but may take up to 3 years in serious cases. The threshold level at which neuropathy occurs has not been people exposed firmly established to concentrations but symptoms have ranging from 10 to been observed in 200 ppm for 9-12 months. In animals, signs of narcosis are seen after mice are exposed to vapor levels of 16,000 ppm for 5 minutes. Death generally occurred at concentrations between 43,800 and 52,000 ppm after 9-119 minutes. The oral ID,, is cited as 24 mL/kg for 14.day-old rats and 49 mL/kg for young adult rats. Long-term inhalation experiments in rats suggest that the first signs of neurotoxicity appear after they are exposed to levels of 200 ppm for 24 weeks. This higher threshold to induce neurotoxicity in animals may be due to differences in metabolism. Specifically, 2-heexanol is the chief metabolite in animals, while 2,5-hexanedione 6/87 -__
FUEL OILS 66-24 TABLE 66-5 ACUTE TOXICITY OF COMPONENTS OF FUEL OILS Component Oral *SO Denaal wo LCSO n-hexane octane dodecane isopentane 24-49 n&/kg [rat) (1935) 28,710 mg/kg [rat] (1937) no data 33,000 04 hr ppm [rat] (1935) < no data > < no data > no data no data 1000 mg/L [mouse] (12) isooctane methylcyclopentane < no data < no data > > methycyclohexane cyclohexane 2250 q/kg [rat] (47) no data 29,820 tag/kg (rat1 no data (1935) -- - no data no data benzene toluene xylenes 4300 q/kg [rat] (471 ethyl benzene 3900 mg/kg [rat] (47) 3800 mg/kg [rat] (59) no data 10 ) 000 PPm 4700 mg/kg [mouse] (47) l 7 hr [rat 1 (47) 5000 u&kg [rat] (47) 12,124 _ mg/kg _ .-. 5320 ppm [rabbir] (47) -8 hr [mouse] (47) trimethylbenzenea no data no data l-methylnaphthalene 1840 q/kg [rat] (47) 2-methylnaphthalene 1630 r&kg (rat] (47) no data SOOO.mg/kg (rabbit] (59) no data no data so00 ppm 04 hr [rat] (47) no data 18 rag/m3 04 hr [rat] (47) no data no data 6/87
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Environmental and Safety Designs, I
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Table of Contents 1.0 2.0 3.0 4.0 5
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1.0 INTRODUCTION The following Heal
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3.0 SITE CHARACTERIZATION Health an
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CAMP LEJEUNE NORTH CAROLINA I
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Health and Safety Plan Solid Waste
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5.0 HAZARD EVALUATION Health and Sa
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Marine Health and Safety Plan Solid
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Health ana’ Safety Plan Solid Was
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Page 45 and 46: 6.0 EMPLOYEE PROTECTION Health and
Page 49 and 50: l a Standard safe operating procedu
Page 51 and 52: 7.0 TEMPERATURE EXPOSURE GUIDELINES
Page 53 and 54: 9.0 EXPOSURE EVALUATION Health and
Page 59 and 60: 12.0 SITE CONTINGENCY PLAN Health a
Page 61 and 62: 12.3 Site Resources Health and Safe
Page 65 and 66: PLAN ACCEPTANCE Health and Safety P
Page 69 and 70: APPENDIX A MSDS ..,~. .- _ - -__..
Page 71 and 72: FUEL OILS 66-2 l Physical State (at
Page 73 and 74: FUEL OILS 66-4 bIR EXPOSURE LIMITS:
Page 75 and 76: FTJELOILS 66-6 l State Water Progra
Page 77 and 78: FUEL OILS 66-8 66.1 MAJOR USES Fuel
Page 79 and 80: FUELOILS 66-10 TABLE 66-2 COMMON AD
Page 81 and 82: TABLE 66-3 EQUILIRRIUN PAPllOWlYt O
Page 83 and 84: FUEL OILS Migration through soils m
Page 85 and 86: PUEL OILS 66-16 relatively small fr
Page 87 and 88: FUEL OILS 66-18 TABLE 66-4 POTENCIE
Page 89 and 90: FUEL OILS 66-20 66.3.1.4 Other Toxi
Page 91: FUELOILS 66-22 66.3.1.4.2 Chronic T
Page 95 and 96: FUEL OILS 66-26 Iso-octg~lf: (2,2,4
Page 97 and 98: FUEL OILS 66-28 Ethyl benzene is pr
Page 99 and 100: FUEL OILS 66-30 AC d Methemoglobine
Page 101 and 102: JP-4 (JET FUEL 4) 64-1 APPROXIMATE
Page 103 and 104: JP-4 (JET FUEL 4) 64-3 HANDLING PRE
Page 105 and 106: JP-4 (JET FUEL 4) 64-5 REGULATORY S
Page 107 and 108: JP-4 (JET FUEL 4) 64-7 64.1 MAJOR U
Page 109 and 110: JP-4 (JET FUEL 4) 64-9 TABLE 64-1 -
Page 111 and 112: JP-4 (JET FUEL 4) 64-11 TABLE 64-2
Page 113 and 114: JP-4 (JET FUEL 4) 64-13 solubility.
Page 115 and 116: JP-4 (JET FUEL 4) 64-15 Compared wi
Page 117 and 118: JP-4 (JET FUEL 4) 64-17 TABLE 64-5
Page 119 and 120: JP-4 (JET FUEL 4) 64-19 Although th
Page 121 and 122: JP-4 (JET FUEL 4) 64-21 Volatilizat
Page 123 and 124: JP-4 (JET NEL 4) 64-23 In tests con
Page 125 and 126: JP-4 (JET FUEL 4) headache, nausea,
Page 127 and 128: JP-4 (JET FUEL 4) 64-27 Paralysis d
Page 129 and 130: JP-4 (JET FUEL 4) 64-29 exposed to
Page 131 and 132: JP-4 (JET FUEL 4) 64-31 mg/kg and 1
Page 133 and 134: JP-4 (JET FUEL 4) 64-33 various col
Page 135 and 136: AUTOMOTIVE GASOLINE 65-2 PHYSICO- C
Page 137 and 138: AUTOMOTIVE GASOLINE 65-4 kIR EXPOSU
Page 139 and 140: AUTOMOTIVE GASOLINE 65-6 Directives
Page 141 and 142: AUTOMOTIVE GASOLINE 65-8 65.1 MAJOR
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AUTOMOTIVE GASOLINE 65-10 TABLE 65-
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AUTOMOTIVE GASOLINE 65-12 a. initia
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TABLE 65-3 EQUILIBRIUN PARflOYlYG O
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AUTOMOTIVE GASOLIt@i 65-16 Some res
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65-18 Although the microbiota of mo
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AUTOMOTIVE GASOLINE 65-20 higher. A
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AUTOHOTIVE GASOLINE 65-22 Tests for
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AUTOMOTIVE GASOLINE 65-24 experimen
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AUTOMOTIVE GASOLINE 65-26 cancer hy
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AUTOMOTIVE GASOLINE 65-28 10 months
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AUTOMOTIVE GASOLINE 65-30 The trime
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AUTOMOTIVE GASOLINE 65-32 spontaneo
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AUTOMOTIVE GASOLINE 65-34 even the
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STODDARD SOLVENT 67-2 0 Log (Octano
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STODDARD SOLVENT 67-L JR EXPOSURE L
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STODDARD SOLVENT 67-6 EEC Directive
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STODDARD SOLVENT 67-8 67.1 MAJOR US
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TARLE 67-2 EQUlLlSRlUN PARlIOYIY6 O
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STODDARD SOLVENT 67-12 aliphatics,
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STODDARD SOLVENT 67-14 incidence co
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STODDARD SOLVENT 67-16 67.3.2 Human
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STODDARD SOLVENT 67-18 the site of
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STODDARD SOLVENT 67-2 l Log (Octano
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STODDARD SOLVENT 67-G RNVTRONBENTAL
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STODDARD SOLVENT 67-6 (538) Direct
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STODDARD SOLVENT 67-8 67.1 MAJOR US
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IAOLE 67-2 EQUILI~RIUI PARflOYIYG O
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STODDARD SOLVENT 67-12 aliphatics.
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STODDARD SOLVENT 67-14 incidence we
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STODDARD SOLVENT 67-16 67.3.2 Human
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STODDARD SOLVENT 67-18 the site of
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HYDRAULIC FLUID 68-2 I PERSISTENCE
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~RALJLIC FLUID 68-32 the constituen
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HYDRAULIC FLUID 6814 REGULATORY STA
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HYDRAULIC FLUID 68-6 Directive on T
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TABLE 68-l 3 $ HYDRAULIC OILS 3 Fa
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TABLE 68-l - Continued HYDRAULIC OI
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. TABLE 68-1 - Continued HYDRAULIC
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TABLE 68-l - Continued HYDRAULIC OI
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HYDRAULIC FLUID 68-16 TABLE 68-2 -
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HYDRAULIC FLUID 68-18 TABLE 68-3 SO
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HYDRAULIC FLUID 68-20 Transport and
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HYDRAULIC FLUID 68-22 high volatili
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HYDRAULIC FLUID 68-24 reaction at 2
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HYDSWJLIC FLUID 68-26 TABLE,68-4 AC
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HYDRAULIC FLUID 68-28 transient irr
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HYDRAULIC FLUID 68-30 BHT is mildly
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METHYL ETHYL KETONE 41-a TABLE 41-1
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METMYL ETHYL KETONE 41-6 EEC DfrGti
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METHYL ETRYL KETONE 41-4 Promubted
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METHYL ETHYL KETONE 41-2 PERSISTENC
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MBTHYL ETHYL KETONE 41-10 ketone th
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METHYL ETHYL KETONE 41-12 41.3.1.2
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METHYiL ETHYL KETONE 41-14 axons in
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METHYL ETHYL KETONE 41-16 41.3.4 Ha
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ETHYLENE GLYCOL 43-l COMMON SYNONYM
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ETHYLENE CLYCOL 43-3 ENVIRONMENTAL
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ETWLENE GLYCOL 43-5 43.1 MAJOR USES
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EIWLENE GLYCOL 43-7 Data on ethylen
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ETHYLENE GLYCOL 43-9 animals) verte
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ETHYLmE GLYCOL 43-11 The effect of
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- .-.- ---_ -. _ I_T_-- ETHYLENE GL
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