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TABLE 68-l<br />

- Continued<br />

HYDRAULIC OILS<br />

Base Stock Structure/Comn~ion Pros eristics<br />

5. Phosphate esters'<br />

R'O-P<br />

ii<br />

-OR*<br />

I<br />

OR<br />

R can be H or organic groups.<br />

At least 1 R must be an organic<br />

group.<br />

Three classes:<br />

trialkylphosphates, triaryl<br />

phosphates, alkyl-aryl<br />

phosphates; i.e.,:<br />

Excellent fire resistance<br />

properties. MW typically<br />

200-600. Densities approximately<br />

0.9-1.5 g/mL. Boiling points<br />

for trialkylphosphates<br />

approximately 190-3OO'C. Used<br />

in extreme temperature<br />

applications.<br />

;3<br />

i<br />

u<br />

6. Silicate estersC<br />

R)3<br />

(a triaryl phosphate)<br />

Oxygen(s) may be replaced by<br />

sulfur to give thiophosphates.<br />

Two classes:<br />

OR2<br />

I<br />

R1° -si. -OR3<br />

I<br />

OR4<br />

(Orthosilicates)<br />

UW typically 300-800. Densities<br />

approximately 0.8-1.1 g/mL at<br />

2O'C. Vapor pressures 0.1-5.0<br />

mm Hg at 205'C. Boiling points<br />

approximately 93'-482'C. Used<br />

in extreme temperature<br />

applications.

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