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NASA Scientific and Technical Aerospace Reports

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We have recorded time-resolved LII signals from a laminar ethylene diffusion flame over a wide range of laser fluences<br />

at 532 nm. We have performed these experiments using an injection-seeded NdYAG laser with a pulse duration of 7 ns. The<br />

beam was spatially filtered <strong>and</strong> imaged into the flame to provide a homogeneous spatial profile. These data were used to aid<br />

in the development of a model, which will be used to test the validity of the LII technique under varying environmental<br />

conditions. The new model describes the heating of soot particles during the laser pulse <strong>and</strong> the subsequent cooling of the<br />

particles by radiative emission, sublimation, <strong>and</strong> conduction. The model additionally includes particle heating by oxidation,<br />

accounts for the likelihood of particle annealing, <strong>and</strong> incorporates a mechanism for nonthermal photodesorption, which is<br />

required for good agreement with our experimental results. In order to investigate the fast photodesorption mechanism in more<br />

detail, we have recorded LII temporal profiles using a regeneratively amplified Nd:YAG laser with a pulse duration of 70 ps<br />

to heat the particles <strong>and</strong> a streak camera with a temporal resolution of -65 ps to collect the signal. Preliminary results confirm<br />

earlier indications of a fast mechanism leading to signal decay rates of much less than a nanosecond. Parameters to which the<br />

model is sensitive include the initial soot temperature, the temperature of the ambient gas, <strong>and</strong> the partial pressure of oxygen.<br />

In order to narrow the model uncertainties, we have developed a source of soot that allows us to determine <strong>and</strong> control these<br />

parameters. Soot produced by a burner is extracted, diluted, <strong>and</strong> cooled in a flow tube, which is equipped with a Scanning<br />

Mobility Particle Sizer (SMPS) for characterization of the aggregates.<br />

NTIS<br />

Diesel Engines; Soot; Combustion Products<br />

20040111175 Lawrence Livermore National Lab., Livermore, CA<br />

Detailed Chemical Kinetic Reaction Mechanisms for Combustion of Isomers of Heptane<br />

Westbrook, C. K.; Pitz, W. J.; Curran, H. C.; Boercker, J.; Kunrath, E.; Mar. 26, 2001; In English<br />

Report No.(s): DE2003-15005667; UCRL-JC-143290; No Copyright; Avail: National <strong>Technical</strong> Information Service (NTIS)<br />

Detailed chemical kinetic reaction mechanisms are developed for all nine chemical isomers of heptane (C(sub 7)H(sub<br />

16)), following techniques <strong>and</strong> models developed previously for other smaller alkane hydrocarbon species. These reaction<br />

mechanisms are tested at high temperatures by computing shock tube ignition delay times <strong>and</strong> at lower temperatures by<br />

simulating ignition in a rapid compression machine. Although the corresponding experiments have not been reported in the<br />

literature for most of these isomers of heptane, intercomparisons between the computed results for these isomers <strong>and</strong><br />

comparisons with available experimental results for other alkane fuels are used to validate the reaction mechanisms as much<br />

as possible. Differences in the overall reaction rates of these fuels are discussed in terms of differences in their molecular<br />

structure <strong>and</strong> the resulting variations in rates of important elementary reactions. Reaction mechanisms in this study are works<br />

in progress <strong>and</strong> the results reported here are subject to change, based on model improvements <strong>and</strong> corrections of errors not<br />

yet discovered.<br />

NTIS<br />

Combustion; Error Analysis; Hydrocarbons; Isomers; Heptanes<br />

20040111517 Air Univ., Maxwell AFB, AL<br />

Airpower as a Tool of Foreign Policy, Two Case Studies of Airpower’s Use: The Philippines in 1941 <strong>and</strong> Berlin in 1948<br />

Therianos, Janet A.; May 1993; 80 pp.; In English<br />

Report No.(s): AD-A425508; No Copyright; Avail: CASI; A05, Hardcopy<br />

The purpose of this work is to provide insight for the operational air planner who must determine the circumstances under<br />

which airpower can be an effective tool of foreign policy. With insight into this issue, both the air strategist <strong>and</strong> diplomat may<br />

be better equipped to evaluate the appropriateness of using airpower in international relations. To accomplish this purpose, this<br />

paper provides an analysis of two specific cases in which USA political leadership called upon airpower to further foreign<br />

policy goals without resorting to war. The first case study centers around the decision to place B-17s on the Philippine Isl<strong>and</strong>s<br />

in October of 1941. The second case study focuses on the use of airpower during the Berlin Blockade of 1948-1949. Both case<br />

studies use a framework for analysis that examines the interrelationships between political, material, <strong>and</strong> military influences<br />

on the ultimate operational air plan. Future students who may wish to pursue exp<strong>and</strong>ed studies of these or other cases may<br />

capitalize on this framework to pursue those studies.<br />

DTIC<br />

Foreign Policy; International Relations; Philippines<br />

20040111571 Massachusetts Inst. of Tech., Cambridge, MA<br />

Fully Coupled Dynamic Analysis of a Floating Wind Turbine System<br />

Withee, Jon E.; Jun. 2004; 151 pp.; In English<br />

Report No.(s): AD-A425623; No Copyright; Avail: CASI; A08, Hardcopy<br />

130

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