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NASA Scientific and Technical Aerospace Reports

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This report summarizes the findings of a reconnaissance effort to determine the extent to which lead-based paint liquid<br />

encapsulants are currently being used for residential lead hazard control <strong>and</strong> to obtain an informal assessment of users<br />

experiences with encapsulants. The effort included a literature search to identify <strong>and</strong> review the relevant literature on<br />

encapsulant use <strong>and</strong> performance, interviews with officials from states that were considered to be likely to regulate encapsulant<br />

use, surveys of major encapsulant users <strong>and</strong> other lead hazard control professionals, <strong>and</strong> site visits to selected users. The most<br />

important outcome of the literature search is that there is no detailed discussion on the long-term performance of encapsulants<br />

in the published literature. In addition, technical reviews <strong>and</strong> theoretical discussions concerning the chemical composition of<br />

encapsulants <strong>and</strong> comparisons between various chemical alternatives are lacking in the published literature. In the past, there<br />

has been a difference of opinion among various encapsulant manufacturers <strong>and</strong> other professionals concerning the optimal<br />

properties of encapsulants; however, results of any research into these issues apparently have not been published. The only<br />

document that reported on the long-term effectiveness of encapsulation looked at cases where products had been installed for<br />

only two years. Encapsulant manufacturers were identified from various state registries <strong>and</strong> other lists compiled between 1993<br />

<strong>and</strong> 1997. New encapsulant manufacturers were sought out using Internet searches, personal contacts, exhibitor lists from lead<br />

conferences, <strong>and</strong> advertisements in various coatings journals <strong>and</strong> lead-oriented newsletters. Fifteen current manufacturers,<br />

which make 19 different encapsulant products, were identified as a result of this effort.<br />

NTIS<br />

Pain; Lead (Metal); Hazards; Chemical Composition<br />

20040120933 Savannah River Ecology Lab., Aiken, SC, USA<br />

Investigation of Plutonium <strong>and</strong> Uranium Precipitation Behavior with Gadolinium as a Neutron Poison<br />

Visser, A. E.; Rudisill, T. S.; Bronikowski, M. G.; May 2003; In English<br />

Report No.(s): DE2004-812302; WSRC-TR-2003-00193; No Copyright; Avail: National <strong>Technical</strong> Information Service<br />

(NTIS)<br />

The neutralization of solutions containing significant quantities of fissile material at the Department of Energy’s Savannah<br />

River Site <strong>and</strong> the subsequent transfer of the slurry to the High Level Waste (HLW) system is accomplished with the addition<br />

of a neutron poison to ensure nuclear safety. Gd, depleted U, Fe, <strong>and</strong> Mn have been used as poisons in the caustic precipitation<br />

of process solutions prior to discarding to HLW. However, the use of Gd is preferred since only small amounts of Gd are<br />

necessary for effective criticality control, smaller volumes of metal hydroxides are produced, <strong>and</strong> the volume of HLW glass<br />

resulting from this process is minimized.<br />

NTIS<br />

Depletion; Fissionable Materials; Gadolinium; Plutonium; Uranium<br />

20040120937 Savannah River Ecology Lab., Aiken, SC, USA<br />

Repair of a Melter Pour Spout using an Exp<strong>and</strong>ing Ring<br />

Peacock, H. B.; Imrich, K. J.; Lam, P. S.; Leader, D. R.; Iverson, D. C.; 2003; 7 pp.; In English<br />

Report No.(s): DE2004-812068; WSRC-MS-2003-00369-REV-0; No Copyright; Avail: Department of Energy Information<br />

Bridge<br />

An exp<strong>and</strong>ing ring was developed that provided remote repair of the pour spout for a radioactive waste vitrification melter.<br />

This passive device used gas pressure to exp<strong>and</strong> a metal ring against the irregularly shaped pour spout wall. Laboratory<br />

modeling <strong>and</strong> testing were performed for proof of concept <strong>and</strong> optimization before final design <strong>and</strong> field deployment. The ring<br />

exp<strong>and</strong>ed radially more than 4.8 mm <strong>and</strong> successfully repaired the melter pour spout allowing continued glass pouring<br />

operation.<br />

NTIS<br />

Radioactive Wastes; Vitrification; Maintenance<br />

20040120957 <strong>NASA</strong> Langley Research Center, Hampton, VA, USA<br />

Measurement of the Specific Refractivities of CF4 <strong>and</strong> C2F6<br />

Burner, A. W.; Goad, W. K.; [1977]; 2 pp.; In English; No Copyright; Avail: CASI; A01, Hardcopy<br />

In order to relate the measured fringe shift of an interferometer to density, the relation between density rho <strong>and</strong> refractive<br />

index n must be known. For gases where the refractive index is close to unity, this relation between density <strong>and</strong> refractive<br />

index is very closely approximated by (n - 1) = K rho where K is the specific refractivity, or the Gladstone-Dale constant. The<br />

specific refractivity, which is weakly dependent on wavelength <strong>and</strong> temperature, is readily available for a number of common<br />

test gases such as N2 <strong>and</strong> air. For more unique test gases such as CF4 <strong>and</strong> C2F6 for which refractive index data at optical<br />

85

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