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NASA Scientific and Technical Aerospace Reports

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esults show that the membranes exposured at 900 C for 1Hr has the most higher permeation capacity, indicated that our zeolite<br />

membranes has the capacity to permeate hydrogen.<br />

Author<br />

Zeolites; Membrane Structures; Hydrogen; Cleaning; Purification<br />

28<br />

PROPELLANTS AND FUELS<br />

Includes rocket propellants, igniters, <strong>and</strong> oxidizers; their storage <strong>and</strong> h<strong>and</strong>ling procedures; <strong>and</strong> aircraft fuels. For nuclear fuels see 73<br />

Nuclear Physics. For related information see also 07 Aircraft Propulsion <strong>and</strong> Power; 20 Spacecraft Propulsion <strong>and</strong> Power; <strong>and</strong> 44<br />

Energy Production <strong>and</strong> Conversion.<br />

20040111282 Toledo Univ., OH, USA<br />

Chemistry of Aviation Fuels<br />

Knepper, Bryan; Hwang, Soon Muk; DeWitt, Kenneth J.; September 2004; 32 pp.; In English<br />

Contract(s)/Grant(s): NAG3-2338; No Copyright; Avail: CASI; A03, Hardcopy<br />

Minimum ignition energies of various methanol/air mixtures were measured in a temperature controlled constant volume<br />

combustion vessel using a spark ignition method with a spark gap distance of 2 mm. The minimum ignition energies decrease<br />

rapidly as the mixture composition (equivalence ratio, Phi) changes from lean to stoichiometric, reach a minimum value, <strong>and</strong><br />

then increase rather slowly with Phi. The minimum of the minimum ignition energy (MIE) <strong>and</strong> the corresponding mixture<br />

composition were determined to be 0.137 mJ <strong>and</strong> Phi = 1.16, a slightly rich mixture. The variation of minimum ignition energy<br />

with respect to the mixture composition is explained in terms of changes in reaction chemistry.<br />

Author<br />

Aircraft Fuels; Propellant Combustion; Combustion Chemistry; Combustion Effıciency; Ignition<br />

20040111375 <strong>NASA</strong> Glenn Research Center, Clevel<strong>and</strong>, OH, USA<br />

Damage Assessment of Stress-Thermal Cycled High Temperature<br />

Ju, Jach-Yung; Prochazka, Michael; Ronke, Ben; Morgan, Roger; Shin, Eugene; [2003]; 8 pp.; In English; 14th International<br />

Conference on Composite Materials, 14-18 Jul. 2003, San Diego, CA, USA<br />

Contract(s)/Grant(s): 708-31-16<br />

Report No.(s): Paper 1273; Copyright; Avail: CASI; A02, Hardcopy<br />

We report on the characterization of bismaleimide <strong>and</strong> polyimide carbon fiber composite, microcrack development under<br />

stress thermal cycling loading. Such cycle range from cryogenic temperatures associated with cryogenic fuel (LN, LOX)<br />

containment to high temperatures of 300 degrees associated with future hypervelocity aeropropulsion systems. Microcrack<br />

development thresholds as a function of temperature range of the thermal cycle, the number of cycles, <strong>and</strong> the applied stress<br />

level imposed on the composite are reported. We have conducted stress-thermal cycles on thin bismaleimide-woven carbon<br />

fiber foils for three temperature range cycles. The principle findings are that the full cycles from -196 degree celsius up to 250<br />

degree celsius cause the most significant microcrack development. These observations indicate that the high temperature<br />

portion of the cycle under load causes fiber-matrix interface failure <strong>and</strong> subsequent exposure to higher stresses at the<br />

cryogenic, low temperature region results in composite matrix microcracking as a result of the additional stresses associated<br />

with the fiber-matrix thermal expansion mismatch. Our initial studies for 12 ply PMR-II-50 polyimide/M6OJB carbon fabric<br />

[0f, 90f, 90f, 0f, 0f, 90f] composites will be presented. The stress-thermal cycle test procedure for these will be described.<br />

Moisture absorption characteristics between cycles will be used to monitor interconnected microcrack development. The<br />

applied stress level will be 75 percent of the composite cryogenic -196 degree celsius ultimate strength.<br />

Derived from text<br />

Fiber-Matrix Interfaces; Cryogenic Temperature; Thermal Cycling Tests; Carbon Fibers; Damage Assessment; Microcracks<br />

20040111437 Prins Maurits Lab. TNO, Rijswijk, Netherl<strong>and</strong>s<br />

Transportable Desensitizing of Munitions: A Feasibility Study<br />

Stuivinga, M. E. C.; vanHam, N. H. A.; May 2004; 88 pp.; In Dutch<br />

Contract(s)/Grant(s): A02/D/476; TNO Proj. 014.14369<br />

Report No.(s): TD-2004-0028; PML-2004-A28; Copyright; Avail: Other Sources<br />

This report describes a feasibility study for a facility for the destruction of unexploded ordnance (UXO) of the Second<br />

World War. Munitions larger than 35 mm can be decommissioned by removing the initiation mechanism by water jet cutting<br />

87

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