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NASA Scientific and Technical Aerospace Reports

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20040120911 National Renewable Energy Lab., Golden, CO<br />

Polycrystalline Thin Film Photovoltaics: Reseasrch, Development, <strong>and</strong> Technologies<br />

Ullal, H. S.; Zweibel, K.; von Roedern, B.; May 2002; 14 pp.; In English<br />

Report No.(s): DE2004-15007048; NREL/CP-520-32187; No Copyright; Avail: Department of Energy Information Bridge<br />

II-VI binary thin-film solar cells based on cadmium telluride (CdTe) <strong>and</strong> I-III-VI ternary thin-film solar cells based on<br />

copper indium diselenide (CIS) <strong>and</strong> related materials have been the subject of intense research <strong>and</strong> development in the past<br />

few years. Substantial progress has been made thus far in the area of materials research, device fabrication, <strong>and</strong> technology<br />

development, <strong>and</strong> numerous applications based on CdTe <strong>and</strong> CIS have been deployed worldwide. World record efficiency of<br />

16.5% has been achieved by NREL scientists for a thin-film CdTe solar cell using a modified device structure. Also, NREL<br />

scientists achieved world-record efficiency of 21.1% for a thin-film CIGS solar cell under a 14X concentration <strong>and</strong> AM1.5<br />

global spectrum. When measured under a AM1.5 direct spectrum, the efficiency increases to 21.5%. Pathways for achieving<br />

25% efficiency for t<strong>and</strong>em polycrystalline thin-film solar cells are elucidated. R&D issues relating to CdTe <strong>and</strong> CIS are<br />

reported in this paper, such as contact stability <strong>and</strong> accelerated life testing in CdTe, <strong>and</strong> effects of moisture ingress in thin-film<br />

CIS devices. Substantial technology development is currently under way, with various groups reporting power module<br />

efficiencies in the range of 7. 0% to 12.1% <strong>and</strong> power output of 40.0 to 92.5 W. A number of lessons learned during the<br />

scale-up activities of the technology development for fabrication of thin-film power modules are discussed. The major global<br />

players actively involved in the technology development <strong>and</strong> commercialization efforts using both rigid <strong>and</strong> flexible power<br />

modules are highlighted.<br />

NTIS<br />

Photovoltaic Cells; Thin Films; Solar Cells; Research <strong>and</strong> Development<br />

20040120912 National Renewable Energy Lab., Golden, CO<br />

DOE/NREL Fundamental <strong>and</strong> Exploratory Research into Solar Cells<br />

Matson, R.; McConnell, R.; May 2002; 12 pp.; In English<br />

Report No.(s): DE2004-15007046; NREL/CP-520-31484; No Copyright; Avail: Department of Energy Information Bridge<br />

This conference paper describes the U.S. Department of Energy / National Renewable Energy Laboratory supports<br />

fundamental <strong>and</strong> exploratory research into solar cells. The purpose of the following set of research projects is twofold: (1) to<br />

provide fundamental experimental <strong>and</strong> theoretical foundations to existing photovoltaic (PV)/solar cell technologies, <strong>and</strong> (2)<br />

to explore whole new possibilities in PV/solar cell technologies, however revolutionary or unconventional they might be. As<br />

surely as a number of revolutionary new solar cell technologies will most likely involve high-risk, long-term R&D to bring<br />

them to fruition, <strong>and</strong> may also well be needed as a complement to a future energy portfolio, so we also need timely results.<br />

As such, one of the primary driving motives for this effort is the possibility of developing one or more ‘leapfrog’ technologies.<br />

These are technologies that have the distinct possibility of ‘leaping ahead’ of existing technologies rather than taking the more<br />

characteristic development time of 10 to 20 years.<br />

NTIS<br />

Research <strong>and</strong> Development; Solar Cells<br />

45<br />

ENVIRONMENT POLLUTION<br />

Includes atmospheric, water, soil, noise, <strong>and</strong> thermal pollution.<br />

20040111149 Lawrence Livermore National Lab., Livermore, CA<br />

<strong>Technical</strong> Basis Document No. 6: Waste Package <strong>and</strong> Drip Shield Corrosion<br />

Farmer, J.; Pasupathi, V.; Nair, P.; Gordon, G.; McCright, D.; Aug. 01, 2003; In English<br />

Report No.(s): DE2004-15005729; UCRL-LR-155288; No Copyright; Avail: National <strong>Technical</strong> Information Service (NTIS)<br />

The waste package <strong>and</strong> drip shield will experience a wide range of interactive environmental conditions <strong>and</strong> degradation<br />

modes that will determine the overall performance of the waste package <strong>and</strong> repository. The operable modes of degradation<br />

are determined by the temperature regime of operation (region), <strong>and</strong> are summarized here. Dry-Out Region (T(ge) 120 C; 50<br />

to 400 Years): During the pre-closure period, the waste package will be kept dry by ventilation air. During the thermal pulse,<br />

heat generated by radioactive decay will eventually increase the temperature of the waste package, drip shield <strong>and</strong> drift wall<br />

to a level above the boiling point, where the probability of seepage into drifts will become insignificant. Further heating will<br />

push the waste package surface temperature above the deliquescence point of expected salt mixtures, thereby preventing the<br />

formation of deliquescence brines from dust deposits <strong>and</strong> humid air. Phase <strong>and</strong> time-temperature-transformation diagrams<br />

146

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