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Post harvest diseases fruits and vegetables - Xavier University ...

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FREEDOM PALESTINE FREEDOM PALESTINE FREEDOM PALESTINE<br />

152 <strong>Post</strong><strong>harvest</strong> Diseases of Fruits <strong>and</strong> Vegetables<br />

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100<br />

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Fig. 26. Relationship between pH <strong>and</strong> the relative concentration of undissociated<br />

hypochlorous acid (HOCl) in a solution of chlorine. (Reproduced from Bartz <strong>and</strong><br />

Eckert, 1987 with permission of Marcel Dekker Inc.).<br />

conversion (Robbs et al., 1995). Examining the effect of chlorine solutions<br />

on cells of the bacterium, Erwinia caratovora subsp. carotovora <strong>and</strong> the<br />

fungus, Geotrichum c<strong>and</strong>idum suspended in water, Robbs et al. (1995)<br />

showed that the chlorine solution toxicity was correlated with free<br />

chlorine concentrations, the pH of the solution <strong>and</strong> the<br />

oxidation-reduction potential of the solutions. The oxidation-reduction<br />

potential was directly correlated with logic of the chlorine concentration<br />

at each pH. It was also found that cells of JE. carotovora subsp. carotovora<br />

were 50 times more sensitive to chlorine than were conidia of G.<br />

c<strong>and</strong>idum, with populations of 10'^ cells or 10'^ conidia per milliliter,<br />

respectively. Populations of Erwinia were reduced below detectable<br />

levels (> 102 cells ml-i) by approximately 0.5, 0.5 or 0.75 mg l-i of free<br />

chlorine at pH 6.0, 7.0 or 8.0, respectively. With conidia of Geotrichum,<br />

25, 25 <strong>and</strong> more than 3 mg l-i, respectively, were required to produce<br />

similar levels of efficacy.<br />

In addition, the hypochlorous acid attacks organic matter, <strong>and</strong> its<br />

concentration in the solution should always be appropriately determined<br />

(Bartz <strong>and</strong> Eckert, 1987). Although a few ppm active chlorine may be<br />

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