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Appendix D - Dossier (PDF) - Tera

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date: 20–JUL–2005<br />

3. Environmental Fate and Pathways Substance ID: 71–43–2<br />

______________________________________________________________________________<br />

Type: anaerobic<br />

Inoculum: other<br />

Degradation: = 72 % after 10 month<br />

Result: other<br />

Method: other<br />

GLP: no data<br />

Test substance: no data<br />

Remark: After 20 weeks of incubation at 17°C in the dark, benzene<br />

did not show signs of significant degradation. After 40<br />

weeks, the benzene levels were reduced to 28% (i.e. 72%<br />

removal) of the originals and after 120 weeks 99% removal). No evidence of degradation was seen in<br />

the autoclaved controls after 40 weeks.<br />

Source: BP Chemicals Ltd LONDON<br />

German Rapporteur<br />

Test condition: Benzene was studied in aquifer material from Oklahoma, USA.<br />

The living microcosms tested consisted of anaerobic<br />

subsurface materials from aquifers known to support<br />

methanogenesis. Autoclaved samples were used as controls.<br />

Reliability: (4) not assignable<br />

02–SEP–2003 (827) (1258)<br />

Type: anaerobic<br />

Inoculum: other<br />

Concentration: .27 mg/l related to Test substance<br />

Degradation: = 72 % after 10 month<br />

Result: other<br />

Method: other<br />

GLP: no data<br />

Test substance: other TS<br />

Remark: Removal of 0.61 mg/l benzene mixed with 0.55 mg/l toluene,<br />

0.27 mg/l ethylbenzene and 0.26 mg/l o–xylene in<br />

methanogenic aquifer material. Aquifer samples were<br />

collected below a contaminated landfill, which is located on<br />

the bank of a river in Oklahoma, USA. GC–analysis after 0,<br />

6, 12, 20, 40 and 120 weeks of incubation. Autoclaved<br />

samples were used as controls.<br />

Results: After 20 weeks incubation benzene did not show<br />

signs of significant removal. After 40 weeks, elimination of<br />

test substance was 72% and after 120 weeks >99%. No evidence<br />

of elimination was seen in the autoclaved controls after 40<br />

weeks.<br />

Source: Deutsche Shell Chemie GmbH Eschborn<br />

German Rapporteur<br />

Test condition: Incubation at 17 degree C in the dark.<br />

Characteristic of aquifer water: pH 7.3; 0.7 mg/l nitrate;<br />

218 mg/l ammonia; 344 mg/l TOC.<br />

Test substance: High purity<br />

Reliability: (2) valid with restrictions<br />

02–SEP–2003 (1259)<br />

<strong>Appendix</strong> D: Benzene SIDS <strong>Dossier</strong><br />

– 214/957 –

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