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Appendix D - Dossier (PDF) - Tera

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date: 20–JUL–2005<br />

1. General Information Substance ID: 71–43–2<br />

______________________________________________________________________________<br />

13–DEC–1996<br />

Remark: Based on extensive studies in the USA, it appears that<br />

facilities manufacturing chemicals, drinking water, food and<br />

beverages, and petroleum refining operations play only a<br />

minimal role in the total exposure of the general population<br />

to benzene.<br />

Benzene is released into the UK environment as a result of<br />

its production and of oil refining processes in general, its<br />

use as a chemical intermediate (production of ethyl benzene,<br />

cyclohexane, phenol etc.), its presence in gasoline and the<br />

combustion of fossil fuels.<br />

Studies in UK, Canada, Germany and USA estimate the relative<br />

contributions of these sources to be:<br />

Vehicle emissions 79–85 %<br />

Petrol distribution 2–6 %<br />

Chemical industry 4–14 %<br />

Petroleum refineries 1 %<br />

Fossil fuel burning 2–5 %<br />

Germany: In 1986, an extensive investigation programme on<br />

aromatic emissions from gasoline–powered cars was conducted<br />

by TUEV–Rheinland as part of a research project from<br />

DGMK/FVV/UBA. These measurements provide a good basis for<br />

more accurate estimates of car exhaust gas emission in the<br />

FRG. Using these results UBA estimated the total benzene<br />

emission from combustion engine driven vehicles, including<br />

diesel vehicles and motorcycles to be 42,000 t/a.<br />

Source: Deutsche Shell Chemie GmbH Eschborn<br />

03–AUG–2000 (95) (828) (1223)<br />

Country: Italy<br />

Remark: Benzene is used in three sites in Italy in alkylation<br />

processes to produce linear alkylbenzene in close system.<br />

Source: ENICHEM AUGUSTA INDUSTRIALE Srl Milan<br />

13–DEC–1996<br />

Remark: Benzene enters the environment from production, storage,<br />

transport, venting, and combustion of gasoline; and from<br />

production, storage, and transport of benzene itself. Other<br />

sources result from its use as an intermediate in the<br />

production of other chemicals, and as a solvent.. from its<br />

indirect production in coke, from nonferrous metal<br />

manufacture, ore mining, wood processing, coal mining and<br />

textile manufacture, from cigarette smoke..<br />

manufacturing methods:<br />

process from coal tar distillation<br />

manufacturing methods:<br />

Process high temperature carbonisation of coal to coke<br />

Manufacturing methods: process petroleum–derived by<br />

catalytic reforming or by cracking of parafines<br />

Source: ENICHEM SYNTHESIS S.p.A. MILANO<br />

13–DEC–1996 (551)<br />

<strong>Appendix</strong> D: Benzene SIDS <strong>Dossier</strong><br />

– 49/957 –

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