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Environmental Profiles of Chemical Flame-Retardant Alternatives for

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Oxidation/Reduction: No data<br />

Melting Point:<br />

Conclusion: The available melting point data <strong>for</strong> TDCPP are adequate.<br />

Basis <strong>for</strong> Conclusion: The key study (highlighted) was per<strong>for</strong>med according to a reliable<br />

method. It is noted that the other literature data do not agree with the key study; however, the<br />

methods used to measure the melting points are not provided in any <strong>of</strong> the sources. As an<br />

OECD-guideline compliant method, the key study is better described and better supported.<br />

Melting Point (/C) References<br />

-58 Akzo Nobel, 2001a,b: melting point determination by DSC (compliant with OECD<br />

Guideline 102), freezing point was determined to be -40/C, melting point -58/C<br />

27 CERI, 1999<br />

26.66 Akzo Nobel, 2003<br />

Boiling Point:<br />

Conclusion: The boiling point data are adequate.<br />

Basis <strong>for</strong> Conclusion: A variety <strong>of</strong> literature sources report the same value <strong>for</strong> the boiling point,<br />

although there is some indication that the compound may decompose at or near the boiling point.<br />

Since experimental details are not provided in any <strong>of</strong> the sources, it is not possible to determine<br />

whether the temperatures reported are decomposition or boiling temperatures. Nevertheless,<br />

given the high boiling point reported <strong>for</strong> this material, the available data are adequate to<br />

characterize its potential volatility.<br />

Boiling Point (/C/torr) References<br />

236-237/5 SRC, 2004 (PHYSPROP database); Budavari, 2001 (The Merck Index);<br />

Lewis, 2000 (Sax’s Dangerous Properties <strong>of</strong> Industrial Materials);<br />

WHO, 1998<br />

200/4 Akzo Nobel, 2003<br />

Dec. >200/4 WHO, 1998<br />

Gradual Dec. >200 HSDB, 2003<br />

Vapor Pressure:<br />

Conclusion: The available vapor pressure data are not adequate<br />

Basis <strong>for</strong> Conclusion: Although this measured vapor pressure is reported in two sources, it<br />

appears to be very high relative to the boiling points reported <strong>for</strong> this chemical. For comparison,<br />

an estimated vapor pressure (EPIWIN) is also included in the table below. The vapor pressure<br />

remains a data need.<br />

3-41

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