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Thixoforming : Semi-solid Metal Processing

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84j 3 Material Aspects of Steel <strong>Thixoforming</strong><br />

Figure 3.33 Primary structure of the examined 100Cr6 states.<br />

The alloying of titanium results in a reduction in the austenite grain growth in the<br />

<strong>solid</strong> state because of the formation of TiN particles. The experiments in the partial<br />

liquid state at 1400 C showed that this effect disappeared because the cast alloyed<br />

with titanium and the cast without titanium possess very similar grain sizes.<br />

Therefore, TiN cannot be used for the reduction of the unwanted grain growth<br />

during holding in the partial liquid state. Only the indirect effect of the reduction of<br />

the austenite grain growth during heating can be used in the <strong>solid</strong> state. In this case,<br />

the grain size of the titanium-alloyed cast is lower than that of the cast without<br />

titanium, as the examinations of the third test series show. For short holding times in<br />

the partial liquid state, the growth constraint of the TiN particles in the <strong>solid</strong> state still<br />

has an influence on the microstructure in the partial liquid state.<br />

The metallographic image parallel to the rolling direction in the third test series<br />

shows that (bottom left) the carbide bands continue within the austenite grains and<br />

Figure 3.34 Element distribution images (N, Ti, Cr, C) of titaniumdoped<br />

100Cr6 specimens quenched from the partial liquid state.

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