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Thixoforming : Semi-solid Metal Processing

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Table 4.3 Properties of selected Al–Li–X alloys relevant to SSM<br />

processing; calculations made by Scheil–Gulliver approximation.<br />

Alloy<br />

Cu<br />

(wt%)<br />

The important key parameters on the basis of the thermochemical calculations are<br />

summarized in Table 4.3.<br />

4.4.2<br />

Choice of a Suitable Basis System<br />

4.4 Development of Aluminium–Lithium-Alloys for <strong>Semi</strong>-<strong>solid</strong> <strong>Processing</strong>j123<br />

Li<br />

(wt%)<br />

Mg<br />

(wt%)<br />

T 50<br />

( C) dfl/dT<br />

T 50 T s<br />

( C)<br />

Intermetallic<br />

phases<br />

A1 (AA2090) 2.5 2.5 — 637 0.023 105 4.7% T2, 1%T1<br />

A2 4.0 2.5 — 629 0.015 97 4.8%T 2, 2.7%T 1, 0.3% T B<br />

A3 4.0 4.0 — 605 0.008 39 12.5% T2, 0.6% AlLi<br />

A4 4.0 1.3 — 639 0.024 107 2.5% T 1, 2.1% T B<br />

A5 (AA8090) 1.2 2.5 0.7 638 0.026 197 3.3% T2, 0.5% AlLi, 0.4% t<br />

A6 — 2.5 4.0 613 0.012 155 5.2% t, 2.7% g<br />

A7 — 4.0 8.0 542 0.004 84 15.5% t, 5.9% g, 1.1% AlLi<br />

A8 (AA1420) — 2.1 5.5 603 0.010 145 3.4% t, 5.2% g<br />

Since for semi-<strong>solid</strong> workability the formation of a globulitic microstructure is a<br />

prerequisite quench tests were carried out from the partially liquid range. The average<br />

<strong>solid</strong> phase particle diameter should be less than 100 mm in this respect. The grain<br />

structure formations indicate that the grain-refined alloys A1, A2, A4 and A5 formed<br />

thelargerglobulitic particleswith virtuallyidentical <strong>solid</strong> phasecontents.ThealloysA3,<br />

A6, A7 and A8 on the other hand display the desired grain sizes (

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