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Thixoforming : Semi-solid Metal Processing

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170j 6 Modelling the Flow Behaviour of <strong>Semi</strong>-<strong>solid</strong> <strong>Metal</strong> Alloys<br />

Figure 6.1 Viscosity as a function of <strong>solid</strong> content and particle shape.<br />

Figure 6.2 Shear-thinning flow behaviour of a suspension.<br />

X210CrW12 complemented by investigations on the aluminium alloy A356. The lowmelting<br />

tin–lead alloy is just used for supplementary analysis in terms of yield stress<br />

of metallic suspensions and structural evolution during rest.<br />

6.1.1<br />

Structural Phenomena Influencing the Flow Behaviour<br />

The complex flow behaviour of suspensions is directly related to their internal<br />

structure. Figure 6.3 exemplarily shows for different states of the <strong>solid</strong> phase how<br />

structural changes depend on shear rate and result in changes in viscosity. With<br />

increasing shear rate, the particle size may change or particle agglomerates break up.<br />

Emulsions (left field in the boxes in Figure 6.3) even allow for a change in particle<br />

shape with increasing shear rate. Depending on the shear rate, the structural changes<br />

are caused either by structure forces or by hydrodynamic/viscous forces.<br />

In metallic suspensions, the same phenomena can be observed. By decreasing<br />

shear rate agglomeration occurs because particles collide and bonds between them<br />

are formed. The strength of the bonds increases with time. A further lowering of the<br />

shear rate intensifies this process whereas an increase breaks the bonding and the<br />

average agglomeration size diminishes. The inner network of a semi-<strong>solid</strong> alloy billet

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