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The Influence Of Priming Two Cucumber Cultivar Seeds

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J. Duhok Univ. Vol.13, No.1, (Agri. And Vet. Sciences) Pp 139-147, 2010<br />

Table(2): Rate constant(K) , half timr(t1/2) and activation energy(Ea) of ascorbic acid degradation for orange<br />

juice model system stored in various.condition<br />

Packaging materials Temperature ﻩ C Rate constant(K)<br />

month -1<br />

944<br />

Half time(t1/2) month Activation energy(Ea)k.cal/mol<br />

Glass bottle in light 20 0.119 5.819 7.791<br />

Glass bottle in dark<br />

Plastic bottle in light<br />

Plastic bottle in dark<br />

<strong>The</strong> activation energy value (Ea)for ascorbic<br />

acid destruction(table 2), show that the values<br />

indicated that samples stored in plastic bottles in<br />

the light had marginally better retention of<br />

ascorbic acid for samples in glass bottle in the<br />

dark,hence Ea value of samples stored in glass<br />

bottles in the dark was 13.437 k.cal.mol -1 but for<br />

samples in glass bottles in the light was 7.791<br />

k.cal.mol -1 .<strong>The</strong> higher degradation of ascorbic<br />

acid stored in light condition samples in<br />

comparision to samples stored in dark condition<br />

was attributed to more light penetration through<br />

clear bottles.This was perhaps due to synergistic<br />

effect casued by combination of air trapped in<br />

the headspace and dissolved in the samples and<br />

that of light penetration through the bottles.<strong>The</strong><br />

results in the same table indicated that the<br />

values of activation energy(Ea) of ascorbic acid<br />

degradation of samples stored in glass bottles<br />

was higher than samples stored in plastic<br />

bottles.<strong>The</strong>( Ea )value of ascorbic acid<br />

degradation samples for glass bottles stored in<br />

dark was 13.43k.cal.mol -1 ,while for plastic<br />

bottles stored in dark was10.99k.cal.mol -1 .This<br />

results indicate that the material which presented<br />

the best retention of ascorbic acid was glass<br />

30 0.171 4.053<br />

40 0.280 2.475<br />

20 0.052 13.327 13.437<br />

30 0.106 6.538<br />

40 0.227 3.530<br />

20 0.176 3.938 7.641<br />

30 0.233 2.974<br />

40 0.408 1.699<br />

20 0.108 6.417 10.990<br />

30 0.185 3.746<br />

30 0.361 1.920<br />

bottles comparision to plastic bottels.<strong>The</strong> plastic<br />

bottles presented a poor retention of ascorbic<br />

acid . Oxygen one of main factors that<br />

contributes to ascorbic acid degradation.Results<br />

indicate that glass was the material that presents<br />

the lowest oxygen permeability comparision to<br />

plastic.This results agrees with other researchers<br />

(Alwazeer et al.,2003;Baiano and<br />

Del.,2005;Muratore et al.,2005).<br />

Considering the limit for shelf life of<br />

model system indicative to ascorbic acid<br />

degradation (table 3).Taking into account values<br />

from all treatment it is observed that glass<br />

bottles stored in light at 0 ° C hase a longer shelf<br />

life (6.58 months) than those stored at 50 ° C<br />

(0.72 month) when the lost of ascorbic acid was<br />

25%, this mean the shelf life decreased with<br />

increasing the temperature of storage.<strong>The</strong> results<br />

in the same table indicated that the shelf life of<br />

samples in glass bottles stored in dark have<br />

longer shelf life (30.54 months) comparing with<br />

those packed in glass bottles stored in light (6.58<br />

months) when the lost of ascorbic acid was 25%<br />

and stored at the same temperature (0 ° C).This<br />

results agrees with other researchers as(Maria et<br />

al,2001; Al-Zubaidy and Khalil,2007).

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