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handbook of modern sensors

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546 18 Sensor Materials and Technologies<br />

gas, and the gas ions bombard the target. The kinetic energy <strong>of</strong> the bombarding ions<br />

is sufficiently high to free some atoms from the target surface. Hence, the escaped<br />

sputtered atoms deposit on the surface <strong>of</strong> the sample.<br />

The sputtered techniques yields better uniformity, especially if a magnetic field<br />

is introduced into the chamber, allowing for better directing <strong>of</strong> the atoms toward<br />

the anode. Because this method does not require a high temperature <strong>of</strong> the target,<br />

virtually any material, including organic, can be sputtered. Moreover, materials from<br />

more than one target can be deposited at the same time (cosputtering), permitting a<br />

controlled ratio <strong>of</strong> materials. For example, this can be useful for sputtering nichrome<br />

(Ni and Cr) electrodes on the surface <strong>of</strong> the pyroelectric <strong>sensors</strong>.<br />

18.2.5 Chemical Vapor Deposition<br />

A chemical vapor phase deposition (CVD) process is an important technique for the<br />

production <strong>of</strong> optical, optoelectronic, and electronic devices. For sensor technologies,<br />

it is useful for forming optical windows and the fabrication <strong>of</strong> semiconductor <strong>sensors</strong><br />

where thin and thick crystalline layers have to be deposited on the surface.<br />

The CVD process takes place in a deposition (reaction) chamber, one <strong>of</strong> the versions<br />

<strong>of</strong> which is shown in a simplified form in Fig. 18.7. The substrates or wafers are<br />

positioned on a stationary or rotating table (the substrate holder) whose temperature<br />

is elevated up to the required level by the heating elements. The top cover <strong>of</strong> the<br />

chamber has an inlet for the carrier H 2 gas, which can be added by various precursors<br />

and dopants. These additives, while being carried over the heated surface <strong>of</strong> the<br />

substrate, form a film layer. The gas mixture flows from the distribution cone over<br />

the top surface <strong>of</strong> the wafers and exits through the exhaust gas outlets. The average<br />

gas pressure in the chamber may by near 1 atm, or somewhat lower. For example, a<br />

Fig. 18.7. Simplified structure <strong>of</strong> a CVD reactor chamber.

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