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handbook of modern sensors

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3.5 Resistance 63<br />

resistor) and the so-called resistive temperature detector (RTD). 5 The most popular<br />

RTD is a platinum (Pt) sensor which operates over a broad temperature range from<br />

about −200 ◦ C to over 600 ◦ C. The resistance <strong>of</strong> a Pt RTD is shown in Fig. 3.18. For<br />

a calibrating resistance R 0 at 0 ◦ C, the best-fit straight line is given by<br />

R = R 0 (1.00 + 36.79 × 10 −4 t), (3.57)<br />

where t is the temperature in ◦ C and R is in . The multiple at temperature (T ) is the<br />

sensor’s sensitivity (a slope), which may be expressed as +0.3679%/ ◦ C.<br />

There is a slight nonlinearity <strong>of</strong> the resistance curve which, if not corrected, may<br />

lead to an appreciable error. A better approximation <strong>of</strong> Pt resistance is a second-order<br />

polynomial which gives an accuracy better than 0.01 ◦ C:<br />

R = R 0 (1 + 39.08 × 10 −4 t − 5.8 × 10 −7 t 2 ). (3.58)<br />

It should be noted, however, that the coefficients in Eqs. (3.57) and (3.58) somewhat<br />

depend on the material purity and manufacturing technologies. To compare accuracies<br />

<strong>of</strong> the linear and the second-order models <strong>of</strong> the platinum thermometer, consider the<br />

following example. If a Pt RTD sensor at 0 ◦ C has resistivity R 0 = 100,at+150 ◦ C,<br />

the linear approximation gives<br />

R = 100[1.0036 + 36.79 × 10 −4 (150)]=155.55,<br />

whereas for the second-order approximation (Eq. 3.58)<br />

R = 100[1 + 39.08 × 10 −4 150 − 5.8 × 10 −7 (150) 2 ]=157.32.<br />

The difference between the two is 1.76 . This is equivalent to an error <strong>of</strong> −4.8 ◦ Cat<br />

+150 ◦ C.<br />

Thermistors are resistors with large either negative (NTC) or positive (PTC) temperature<br />

coefficients. The thermistors are ceramic semiconductors commonly made<br />

<strong>of</strong> oxides <strong>of</strong> one or more <strong>of</strong> the following metals: nickel, manganese, cobalt, titanium,<br />

iron. Oxides <strong>of</strong> other metals are occasionally used. Resistances vary from a fraction<br />

<strong>of</strong> an ohm to many megohms. Thermistors can be produced in the form <strong>of</strong> disks,<br />

droplets, tubes, flakes, or thin films deposited on ceramic substrates. Recent progress<br />

in thick-film technology allows us to print the thermistor on ceramic substrates.<br />

The NTC thermistors <strong>of</strong>ten are fabricated in the form <strong>of</strong> beads. Usually, bead<br />

thermistors have platinum alloy lead wires which are sintered into the ceramic body.<br />

Platinum is a convenient choice for the thermistor wires because it combines a relatively<br />

low electrical resistance with a relatively high thermal resistance. During the<br />

fabrication process, a small portion <strong>of</strong> mixed metal oxides is placed with a suitable<br />

binder onto a pair <strong>of</strong> platinum alloy wires, which are under slight tension. After the<br />

mixture has been allowed to set, the beads are sintered in a tubular furnace. The metal<br />

oxides shrink around the platinum lead wires and form intimate electrical bonds. The<br />

beads may be left bare or they may be given organic or glass coatings.<br />

5 See Section 16.1 <strong>of</strong> Chapter 16

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