The MBR Book: Principles and Applications of Membrane
The MBR Book: Principles and Applications of Membrane
The MBR Book: Principles and Applications of Membrane
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Fundamentals 87<br />
air cannot be used routinely. Air sparging has been shown to be effective in an <strong>MBR</strong>s<br />
(Lee et al., 2001c) but the duration <strong>of</strong> air sparging was necessarily brief in this study<br />
(5 s every 10 min), providing little permeability promotion overall. Sparging with<br />
head space gas has been shown to be effective for immersed polymeric (Fawehinmi<br />
et al., 2004; Stuckey <strong>and</strong> Hu, 2003) <strong>and</strong> sidestream ceramic (Kayawake et al., 1991)<br />
membranes. As with the aerobic <strong>MBR</strong>s described above, a maximum permeability<br />
was reached at a certain gas flow rate (Imasaka et al., 1989; Stuckey <strong>and</strong> Hu, 2003).<br />
In common with all membrane processes (Section 2.1.4.5), increasing crossflow<br />
increases flux in sidestream an<strong>MBR</strong>s by suppressing the fouling layer concentration<br />
polarisation (Grethlein, 1978; Imasaka et al., 1989; Saw et al., 1986). However, a<br />
plateau has been reported at Reynolds numbers beyond 2000-or-so where no further<br />
increase in permeability takes place (Choo <strong>and</strong> Lee, 1998; Choo et al., 2000; Elmaleh<br />
<strong>and</strong> Abdelmoumni, 1997, 1998). For ceramic membranes, where the fouling layer is<br />
minimal, high crossflows have been reported as having a detrimental effect because the<br />
thinning cake layer <strong>of</strong>fers less protection against internal fouling (Choo <strong>and</strong> Lee, 1998;<br />
Choo et al., 2000; Kang, 1996). Elmaleh <strong>and</strong> Abdelmoumni (1997) have reported close<br />
to zero fouling for crossflows above 3 m/s in an MT organic membrane module sidestream<br />
an<strong>MBR</strong>, with flux increasing linearly with shear stress up to this point. Baffles<br />
were shown by these authors to increase flux by promoting shear, the effect being greatest<br />
in the transition region between laminar <strong>and</strong> turbulent flow. However, the increase<br />
in flux attained by these measures is normally at the expense <strong>of</strong> a punitive increase in<br />
energy dem<strong>and</strong> (Bourgeous et al., 2001) <strong>and</strong> non-uniform, <strong>and</strong> thus sub-optimal, TMP<br />
distribution (Lee et al., 1999). High-shear operation might also be expected to impact<br />
negatively on floc size <strong>and</strong> biomass bioactivity (Brockmann <strong>and</strong> Seyfried, 1996; Choo<br />
<strong>and</strong> Lee, 1998; Ghyoot <strong>and</strong> Verstraete, 1997) with, at the highest shears, cell lysis taking<br />
place, though it has been concluded by Elmaleh <strong>and</strong> Abdelmoumni (1997) that<br />
such effects are less severe for anaerobic than aerobic biomass.<br />
Reports <strong>of</strong> operation at different TMPs indicate that, as with most membrane separation<br />
processes, membrane resistance determines flux at low TMPs, with no impact<br />
<strong>of</strong> crossflow or MLSS concentration above 2.5 g/L (Beaubien et al., 1996). At higher<br />
TMPs, crossflow (<strong>and</strong> thus surface shear) becomes important (Beaubien et al., 1996;<br />
Zhang et al., 2004), the flux increasing linearly with CFV (Beaubien et al., 1996), the<br />
slope decreasing with increasing MLSS partly due to viscosity effects. At very high<br />
TMPs, permeate flux has been shown to decrease with increasing TMP due to compaction<br />
<strong>of</strong> the fouling layer (Elmaleh <strong>and</strong> Abdelmoumni, 1997). However, this effect<br />
appears to depend on the membrane filter; Saw et al. (1986), filtering anerobic<br />
sludge, observed that at very high TMPs the permeate flux decreased with TMP for an<br />
MF membrane but was constant for an 8–20 kDa MWCO UF membrane. <strong>The</strong> authors<br />
suggested that this was due to the impact <strong>of</strong> the membrane substrate on the fouling<br />
layer structure, but a more likely explanation is migration <strong>of</strong> fines through the cake at<br />
higher TMPs into the more porous MF membrane, causing pore plugging (Beaubien<br />
et al., 1996).<br />
<strong>The</strong> use <strong>of</strong> extended intermittent aeration has been reported for nitrification–<br />
denitrification <strong>MBR</strong> systems (Nagaoka <strong>and</strong> Nemoto, 2005; Yeom et al., 1999). In this<br />
less common scenario, a single tank was used for both anoxic <strong>and</strong> aerobic biological<br />
degradation. Filtration was carried out in only the aerobic phase to take advantage