The MBR Book: Principles and Applications of Membrane
The MBR Book: Principles and Applications of Membrane
The MBR Book: Principles and Applications of Membrane
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
Table 2.12 Dynamic effects<br />
Determinants Variables<br />
Fundamentals 89<br />
Flow rate Ultimate flux <strong>and</strong> rate <strong>of</strong> change<br />
Feedwater quality Ultimate composition <strong>and</strong> rate <strong>of</strong> change<br />
MLSS dilution Dilution factor <strong>and</strong> rate <strong>of</strong> concentration change<br />
(Partial) aeration loss Percentage <strong>and</strong> period <strong>of</strong> reduction<br />
Backflush/cleaning loss Period <strong>of</strong> loss<br />
Hydraulic shock Rate <strong>and</strong> level <strong>of</strong> flow increase<br />
Saline intrusion Ultimate concentration factor <strong>and</strong> rate <strong>of</strong><br />
concentration change<br />
in feeding patterns: the addition <strong>of</strong> a pulse <strong>of</strong> acetate in the feedwater has been<br />
shown to significantly decrease the <strong>MBR</strong> biomass filterability due to the increase in<br />
SMP levels produced (Evenblij et al., 2005b).<br />
<strong>The</strong> effects <strong>of</strong> starvation conditions on the biological suspension have been<br />
assessed by incorporating different substrate impulses in batch tests (Lobos et al.,<br />
2005). Exogenous phases were followed by starvation periods, both characterized by<br />
the S:X (substrate to biomass concentration ratio) where high ratios led to multiplication<br />
<strong>of</strong> bacteria cells whilst at low ratios MLVSS decreased, SMPp production was<br />
absent <strong>and</strong> bacteria lysis ceased. S:X closely relates to F:M ratio (Equation (2.11)),<br />
<strong>and</strong> the low F:M values generally used in <strong>MBR</strong>s are thus theoretically close to starvation<br />
conditions which are in turn likely to be beneficial to <strong>MBR</strong> operation on the<br />
basis <strong>of</strong> the reduced SMPp production <strong>and</strong> correspondingly reduced fouling.<br />
<strong>The</strong> principal period <strong>of</strong> unsteady-state operation is during start-up when the system<br />
is acclimatising. Cho et al. (2005b) reported temporal changes <strong>of</strong> the bound EPS<br />
levels when the <strong>MBR</strong> was acclimatised at three different SRTs (8, 20, 80 days). As<br />
expected from general trends described in Section 2.3.6.5, the EPS concentration was<br />
lower at the longer SRT (83 vs. 26 mgTOC/gSS for SRTs <strong>of</strong> 8 <strong>and</strong> 80 days, respectively).<br />
An initial latent phase was observed in which EPS concentration did not vary<br />
significantly. However, EPS levels increased exponentially after 40 days <strong>of</strong> operation<br />
at an SRT <strong>of</strong> 8 days, <strong>and</strong> after 70 days when the <strong>MBR</strong> was operated at 20-day SRT. No<br />
change in EPS levels was observed during the 80 days <strong>of</strong> operation at 80-day SRT. For<br />
another <strong>MBR</strong> operated at infinite SRT, no significant changes in SMP concentration<br />
during 100 days <strong>of</strong> operation were observed, over which time period the MLSS<br />
increased from 1.8 to 4.5 g/L ( Jinhua et al., 2004). In a further study, following a latent<br />
phase <strong>of</strong> 30 days, MLSS <strong>and</strong> SMP levels started to significantly increase <strong>and</strong> stabilised<br />
after 140 days <strong>of</strong> operation at infinite SRT, whereas EPS levels increased continuously<br />
from the start but also stabilized after 140 days (Gao et al., 2004a). Nagaoka <strong>and</strong><br />
Nemoto (2005) observed an increase in MLSS concentration from 4 to 14 g/L over<br />
100 days along with a steady increase in EPS (from 50 to 250 mgTOC/L). <strong>The</strong>re<br />
therefore appears to be no distinct pattern regarding foulant species generation <strong>and</strong><br />
start-up, other than a general trend <strong>of</strong> more stable foulant levels at longer SRTs.<br />
<strong>The</strong> generation <strong>of</strong> foulants arising from changes in salinity have been studied<br />
by Reid (2006). According to established literature on the ASP extending back to<br />
the 1960s (Ludzack <strong>and</strong> Noran, 1965; Tokuz <strong>and</strong> Eckenfelder, 1979), changes in<br />
salinity have a greater impact on biotreatment efficacy, as manifested in the outlet