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Index Terms Links crystal growth techniques, numerical simulations of 244 245 246 247 248 249 crystal imperfections, effect of 250 251 crystalline silicon 21 27 28 173 230 bulk properties 257 contacting structures 260 contacts 257 258 progress and challenges 23 24 25 26 27 surfaces 256 257 258 259 wafer material for 245 crystalline silicon Cz module 35 crystalline silicon noncontacted surfaces 258 259 crystalline silicon photovoltaic modules 291 292 293 294 295 296 297 297 297 297 297 297 948 949 955 cell matrix 291 292 electrical characteristics 295 296 297 fabrication spread 297 field performance 301 302 lamination and curing 293 layers of the module 292 293 lifetime 301 local shading and hot spot formation 297 298 299 mismatch losses 297 optical properties 300 postlamination steps 294 qualification tests 301 302 special modules 294 295 thermal characteristics 295 296 297 with back contact cells 295 crystalline silicon solar cells 255-291 948 back contact print and dry 275 back surface 266 back surface passivation 281 cell structure 259 260 cofiring of metal contacts 275 front contact print and dry 275 275 front surface 263 264 265 266 manufacturing process 271 272 273 274 275 276 materials and processing 277 278 279 280 performance comparison 270 process flow 271 272 273 274 275 276 size effects 266 267 268 substrate 260 261 262 263 substrate thickness 263 testing and sorting 275 throughput and yield 279 280 variations to basic process 280 281 282 283 This page has been reformatted by Knovel to provide easier navigation
Index Terms Links crystalline silicon technology 40 crystalline silicon wafer PV technology 28 crystallization 193 194 216 217 219 223 from aluminum melt 194 from silicon-melt 194 heat flow in 247 thermal modeling of 245 246 247 Cu 2 S/CdS thin-film solar cells 568 Cu-In-Se system 571 572 CuIn 1−x Ga x Se 2 , complex refractive index 575 Cu(InGa)Se 2 21 27 29 31 35 Cu(InGa)Se 2 solar cells 567-616 absorption of light with different wavelengths 595 alternative buffer layers 588 589 590 back contact 580 buffer layers 591 592 chemical bath deposition (CBD) 585 586 coevaporation 580 581 582 583 commercial development 570 composition 571 572 573 critical materials with respect to primary supply 608 current loss 594 deposition methods 578 579 580 581 582 583 device completion 584 587 588 device operation 592 593 594 595 596 597 598 599 600 601 602 efficiency 590 593 electrical properties 574 575 576 environmental concerns 608 609 equipment 602 603 604 evolution of device record efficiencies 605 future outlook 609 610 611 grain boundaries 576 577 interface effects 586 587 junction and device formation 584 585 586 587 588 589 590 591 592 lack of comprehensive scientific base 570 light-generated current 593 manufacturing issues 602 603 604 605 606 607 608 609 material properties 570 571 572 573 574 575 576 577 578 module fabrication 604 module performance 604 606 607 optical properties 574 outdoor testing results 606 This page has been reformatted by Knovel to provide easier navigation
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Handbook of Photovoltaic Science an
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We dedicate this book to all those
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xxiv LIST OF CONTRIBUTORS Phone: +1
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xxvi LIST OF CONTRIBUTORS 28040 Mad
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Contents List of Contributors xxiii
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CONTENTS ix 4.3.1 The Balance Equat
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CONTENTS xi 7.4 Manufacturing Proce
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CONTENTS xiii 9.8 Future-generation
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CONTENTS xv 12.1.2 Designs for Amor
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CONTENTS xvii 14.3.3 CdS/CdTe Inter
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CONTENTS xix 18.2.2 Batteries with
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CONTENTS xxi 22.2 PV in Architectur
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1 Status, Trends, Challenges and th
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WHAT IS PHOTOVOLTAICS? 3 1.2 WHAT I
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SIX MYTHS OF PHOTOVOLTAICS 5 Sunlig
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SIX MYTHS OF PHOTOVOLTAICS 7 of 10
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SIX MYTHS OF PHOTOVOLTAICS 9 2500 W
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HISTORY OF PHOTOVOLTAICS 11 the maj
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HISTORY OF PHOTOVOLTAICS 13 the USA
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PV COSTS, MARKETS AND FORECASTS 15
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PV COSTS, MARKETS AND FORECASTS 17
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GOALS OF PV RESEARCH AND MANUFACTUR
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GLOBAL TRENDS IN PERFORMANCE AND AP
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CRYSTALLINE SILICON PROGRESS AND CH
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CRYSTALLINE SILICON PROGRESS AND CH
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THIN FILM PROGRESS AND CHALLENGES 2
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THIN FILM PROGRESS AND CHALLENGES 2
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CONCENTRATION PV SYSTEMS 31 reality
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BALANCE OF SYSTEMS 33 Percentage of
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BALANCE OF SYSTEMS 35 Total capital
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FUTURE OF EMERGING PV TECHNOLOGIES
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CONCLUSIONS 39 Yet, in all these al
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REFERENCES 41 the other hand, hybri
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REFERENCES 43 69. Mickelson R, Chen
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46 MOTIVATION FOR PV APPLICATION AN
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62 THE PHYSICS OF THE SOLAR CELL Su
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64 THE PHYSICS OF THE SOLAR CELL 3.
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66 THE PHYSICS OF THE SOLAR CELL E
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72 THE PHYSICS OF THE SOLAR CELL an
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74 THE PHYSICS OF THE SOLAR CELL pr
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76 THE PHYSICS OF THE SOLAR CELL No
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80 THE PHYSICS OF THE SOLAR CELL El
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82 THE PHYSICS OF THE SOLAR CELL wh
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84 THE PHYSICS OF THE SOLAR CELL n
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86 THE PHYSICS OF THE SOLAR CELL Th
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88 THE PHYSICS OF THE SOLAR CELL Th
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94 THE PHYSICS OF THE SOLAR CELL Ta
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96 THE PHYSICS OF THE SOLAR CELL cu
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100 THE PHYSICS OF THE SOLAR CELL 5
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102 THE PHYSICS OF THE SOLAR CELL I
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106 THE PHYSICS OF THE SOLAR CELL T
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108 THE PHYSICS OF THE SOLAR CELL S
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114 THEORETICAL LIMITS OF PHOTOVOLT
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5 Solar Grade Silicon Feedstock Bru
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SILICON 155 faces of silicon are (1
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SILICON 157 powder in the presence
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SILICON 159 5.2.4.1.2 Wrought alloy
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PRODUCTION OF METALLURGICAL GRADE S
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PRODUCTION OF SEMICONDUCTOR GRADE S
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CURRENT SILICON FEEDSTOCK TO SOLAR
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CURRENT SILICON FEEDSTOCK TO SOLAR
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REQUIREMENTS OF SILICON FOR CRYSTAL
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ROUTES TO SOLAR GRADE SILICON 193 c
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ROUTES TO SOLAR GRADE SILICON 195 c
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ROUTES TO SOLAR GRADE SILICON 197 d
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ROUTES TO SOLAR GRADE SILICON 199 d
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CONCLUSIONS 201 2. Another German c
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REFERENCES 203 34. Fischler S, J. A
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6 Bulk Crystal Growth and Wafering
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BULK MONOCRYSTALLINE MATERIAL 207 b
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BULK MONOCRYSTALLINE MATERIAL 209 (
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BULK MONOCRYSTALLINE MATERIAL 211 O
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BULK MONOCRYSTALLINE MATERIAL 213 8
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BULK MULTICRYSTALLINE SILICON 215 I
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BULK MULTICRYSTALLINE SILICON 217 1
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BULK MULTICRYSTALLINE SILICON 219 b
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BULK MULTICRYSTALLINE SILICON 221 L
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WAFERING 223 This in turn verifies
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WAFERING 225 suspension of hard gri
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WAFERING 227 tips, they can exert v
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WAFERING 229 6.4.3 Wafer Quality an
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SILICON RIBBON AND FOIL PRODUCTION
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NUMERICAL SIMULATIONS OF CRYSTAL GR
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CONCLUSIONS 251 the supercooling de
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REFERENCES 253 28. Sahoo R et al.,
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7 Crystalline Silicon Solar Cells a
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CRYSTALLINE SILICON AS A PHOTOVOLTA
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CRYSTALLINE SILICON SOLAR CELLS 259
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MANUFACTURING PROCESS 271 The most
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MANUFACTURING PROCESS 273 3. Textur
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MANUFACTURING PROCESS 275 materials
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MANUFACTURING PROCESS 277 nearly 50
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MANUFACTURING PROCESS 279 Figure 7.
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VARIATIONS TO THE BASIC PROCESS 281
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MULTICRYSTALLINE CELLS 283 of defec
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MULTICRYSTALLINE CELLS 285 better s
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MULTICRYSTALLINE CELLS 287 Figure 7
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OTHER INDUSTRIAL APPROACHES 289 TCO
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CRYSTALLINE SILICON PHOTOVOLTAIC MO
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CRYSTALLINE SILICON PHOTOVOLTAIC MO
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ELECTRICAL AND OPTICAL PERFORMANCE
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FIELD PERFORMANCE OF MODULES 301 7.
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REFERENCES 303 REFERENCES 1. Luque
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REFERENCES 305 75. Lenkeit B et al.
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8 Thin-film Silicon Solar Cells Bhu
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INTRODUCTION 309 Open circuit volta
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A REVIEW OF CURRENT THIN-FILM SI CE
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CVD Excimer laser crystallization U
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n-type silicon (0.2 µm) p-type sil
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DESIGN CONCEPTS OF TF-SI SOLAR CELL
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CONCLUSION 353 Introduction of H af
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REFERENCES 355 17. Kamins T, Ed, Po
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REFERENCES 357 98. Symko M, Sopori
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360 HIGH-EFFICIENCY III-V MULTIJUNC
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10 Space Solar Cells and Arrays She
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THE HISTORY OF SPACE SOLAR CELLS 41
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THE CHALLENGE FOR SPACE SOLAR CELLS
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SILICON SOLAR CELLS 425 Figure 10.7
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III-V SOLAR CELLS 427 n+-GaAs n-AlI
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III-V SOLAR CELLS 429 missions with
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SPACE SOLAR ARRAYS 431 supported af
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SPACE SOLAR ARRAYS 433 JPL-25888AC
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SPACE SOLAR ARRAYS 435 Figure 10.13
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SPACE SOLAR ARRAYS 437 Figure 10.15
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SPACE SOLAR ARRAYS 439 0.31 Astrono
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FUTURE CELL AND ARRAY POSSIBILITIES
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FUTURE CELL AND ARRAY POSSIBILITIES
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POWER SYSTEM FIGURES OF MERIT 445 A
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REFERENCES 447 8. Statler R, Curtin
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11 Photovoltaic Concentrators Richa
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INTRODUCTION 451 markets most often
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BASIC TYPES OF CONCENTRATORS 453 ha
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BASIC TYPES OF CONCENTRATORS 455 is
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BASIC TYPES OF CONCENTRATORS 457 sk
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BASIC TYPES OF CONCENTRATORS 459 Ho
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HISTORICAL OVERVIEW 461 thereafter.
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HISTORICAL OVERVIEW 463 Figure 11.6
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HISTORICAL OVERVIEW 465 production
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HISTORICAL OVERVIEW 467 Figure 11.1
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HISTORICAL OVERVIEW 469 n + bussbar
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HISTORICAL OVERVIEW 471 array [33].
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HISTORICAL OVERVIEW 473 Solar radia
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OPTICS OF CONCENTRATORS 475 q max,
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OPTICS OF CONCENTRATORS 477 If r 1
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OPTICS OF CONCENTRATORS 479 r i Med
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OPTICS OF CONCENTRATORS 481 When θ
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OPTICS OF CONCENTRATORS 483 filled
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OPTICS OF CONCENTRATORS 485 q i q i
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OPTICS OF CONCENTRATORS 487 For lar
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OPTICS OF CONCENTRATORS 489 on a co
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OPTICS OF CONCENTRATORS 491 gleaned
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OPTICS OF CONCENTRATORS 493 Solar c
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CURRENT CONCENTRATOR ACTIVITIES 495
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REFERENCES 501 11. Boes E, “Photo
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REFERENCES 503 60. Uematsu T et al.
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506 AMORPHOUS SILICON-BASED SOLAR C
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13 Cu(InGa)Se 2 Solar Cells William
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INTRODUCTION 569 CdS. The latter en
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MATERIAL PROPERTIES 571 Even though
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MATERIAL PROPERTIES 573 800 d 785 T
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MATERIAL PROPERTIES 575 3.2 x = 0.2
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MATERIAL PROPERTIES 577 1µm Figure
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DEPOSITION METHODS 579 though other
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DEPOSITION METHODS 581 much higher
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DEPOSITION METHODS 583 in the tempe
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JUNCTION AND DEVICE FORMATION 585 f
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JUNCTION AND DEVICE FORMATION 587 0
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JUNCTION AND DEVICE FORMATION 589 T
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JUNCTION AND DEVICE FORMATION 591 d
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DEVICE OPERATION 593 the voltage. F
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DEVICE OPERATION 595 1.0 0.8 500 80
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DEVICE OPERATION 597 1.4 V OC [Volt
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DEVICE OPERATION 599 13.5.3 The Cu(
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DEVICE OPERATION 601 Table 13.5 Hig
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MANUFACTURING ISSUES 603 can well f
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MANUFACTURING ISSUES 605 P1 P1 Mo G
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MANUFACTURING ISSUES 607 Finally, f
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THE Cu(InGa)Se 2 OUTLOOK 609 active
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REFERENCES 611 With all these chall
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REFERENCES 613 81. Stolt L, Hedstr
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REFERENCES 615 168. Fahrenbruch A,
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14 Cadmium Telluride Solar Cells Br
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INTRODUCTION 619 In contrast to p/n
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CdTe PROPERTIES AND THIN-FILM FABRI
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CdTe THIN-FILM SOLAR CELLS 631 orie
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CdTe THIN-FILM SOLAR CELLS 633 14.3
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CdTe THIN-FILM SOLAR CELLS 635 CdTe
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CdTe THIN-FILM SOLAR CELLS 639 800
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CdTe THIN-FILM SOLAR CELLS 641 10
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CdTe THIN-FILM SOLAR CELLS 645 forw
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CdTe THIN-FILM SOLAR CELLS 647 30 R
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CdTe THIN-FILM SOLAR CELLS 649 The
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CdTe MODULES 651 14.4 CdTe MODULES
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THE FUTURE OF CdTe-BASED SOLAR CELL
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THE FUTURE OF CdTe-BASED SOLAR CELL
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REFERENCES 657 This chapter has sho
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REFERENCES 659 60. Wei S, Mtg. Reco
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REFERENCES 661 152. McCandless B, Q
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15 Dye-sensitized Solar Cells Kohji
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INTRODUCTION TO DYE-SENSITIZED SOLA
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DSSC FABRICATION (η = 8%) 679 alko
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DSSC FABRICATION (η = 8%) 681 15.2
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NEW DEVELOPMENTS 683 of highly effi
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NEW DEVELOPMENTS 685 HOOC COOH HOOC
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NEW DEVELOPMENTS 687 photosensitize
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NEW DEVELOPMENTS 689 of these ionic
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APPROACH TO COMMERCIALIZATION 691 1
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Institute and reference Table 15.3
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SUMMARY AND PROSPECTS 695 Chemicals
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REFERENCES 697 4. Dare-Edwards M et
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REFERENCES 699 96. Tennakone K, Kum
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16 Measurement and Characterization
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RATING PV PERFORMANCE 703 Spectral
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λ [nm] Table 16.3 AM0 standard sol
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171.5 7.01E − 1 372.5 1074 573.5
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228.5 52.940 429.5 1501 630.7 1682
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288.5 328.400 489.5 1994 689.1 1506
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RATING PV PERFORMANCE 713 The extra
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RATING PV PERFORMANCE 715 of about
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RATING PV PERFORMANCE 717 Energy [W
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RATING PV PERFORMANCE 719 16.2.4 Tr
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CURRENT VERSUS VOLTAGE MEASUREMENTS
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SPECTRAL RESPONSIVITY MEASUREMENTS
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MODULE QUALIFICATION AND CERTIFICAT
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REFERENCES 747 REFERENCES 1. Emery
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REFERENCES 749 62. Standard IEC 608
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REFERENCES 751 130. Dondero R, Zirk
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17 Photovoltaic Systems Klaus Preis
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PV POWER SYSTEM CONFIGURATION AND A
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COMPONENTS FOR PV SYSTEMS 785 NASA
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COMPONENTS FOR PV SYSTEMS 787 volta
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COMPONENTS FOR PV SYSTEMS 789 well
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COMPONENTS FOR PV SYSTEMS 791 A sig
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COMPONENTS FOR PV SYSTEMS 793 In st
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FUTURE DEVELOPMENTS IN PHOTOVOLTAIC
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REFERENCES 797 CL Controllable load
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18 Electrochemical Storage for Phot
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GENERAL CONCEPT OF ELECTROCHEMICAL
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TYPICAL OPERATION CONDITIONS OF BAT
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TYPICAL OPERATION CONDITIONS OF BAT
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SECONDARY ELECTROCHEMICAL ACCUMULAT
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Table 18.4 Overview of the technica
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BATTERY SYSTEMS WITH EXTERNAL STORA
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INVESTMENT AND LIFETIME COST CONSID
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CONCLUSION 859 This example is just
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REFERENCES 861 10. Ruddell A et al.
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19 Power Conditioning for Photovolt
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CONTROLLERS AND MONITORING SYSTEMS
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INVERTERS 881 19.2 INVERTERS 19.2.1
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INVERTERS 883 Current [A] MPP Power
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INVERTERS 885 S1 S3 DC source AC ou
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INVERTERS 887 V PV V load t 0 t 1 t
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INVERTERS 889 The resulting voltage
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INVERTERS 891 12 V 24 V 48 V 96 V 1
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INVERTERS 893 U DC voltage level U
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INVERTERS 895 100 55 Hz 50 Hz Frequ
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INVERTERS 897 S1 L C 1 C 2 AC outpu
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INVERTERS 899 Time delay Seconds Mi
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INVERTERS 901 Separated part of the
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REFERENCES 903 5. Gonzalez G, Hill
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906 ENERGY COLLECTED AND DELIVERED
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972 ECONOMIC ANALYSIS OF PV SYSTEMS
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1000 ECONOMIC ANALYSIS OF PV SYSTEM
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1002 ECONOMIC ANALYSIS OF PV SYSTEM
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22 PV in Architecture Tjerk H. Reij
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INTRODUCTION 1007 Figure 22.2 Integ
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PV IN ARCHITECTURE 1009 Figure 22.4
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PV IN ARCHITECTURE 1013 Heat load a
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PV IN ARCHITECTURE 1015 • aesthet
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BIPV BASICS 1027 22.3.1.2 Categorie
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BIPV BASICS 1029 Figure 22.34 Alute
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BIPV BASICS 1031 Figure 22.38 Solgr
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BIPV BASICS 1033 Figure 22.42 Canop
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BIPV BASICS 1035 cooling as possibl
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STEPS IN THE DESIGN PROCESS WITH PV
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STEPS IN THE DESIGN PROCESS WITH PV
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REFERENCES 1041 REFERENCES 1. Reije
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23 Photovoltaics and Development Jo
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ELECTRICITY AND DEVELOPMENT 1045 pe
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BREAKING THE CHAINS OF UNDERDEVELOP
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THE PV ALTERNATIVE 1049 was too exp
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THE PV ALTERNATIVE 1051 Basic light
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THE PV ALTERNATIVE 1053 (for a deta
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THE PV ALTERNATIVE 1055 issued by t
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THE PV ALTERNATIVE 1057 Needless to
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THE PV ALTERNATIVE 1059 exports bal
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FOUR EXAMPLES OF PV RURAL ELECTRIFI
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REFERENCES 1069 standard of living
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REFERENCES 1071 36. Martinot E et a
Page 1101 and 1102: 1074 FINANCING PV GROWTH 1995 : The
Page 1103 and 1104: 1076 FINANCING PV GROWTH 24.2.3 Cap
Page 1105 and 1106: 1078 FINANCING PV GROWTH can range
Page 1107 and 1108: 1080 FINANCING PV GROWTH 24.4.2 Typ
Page 1109 and 1110: 1082 FINANCING PV GROWTH 24.4.5 Exa
Page 1111 and 1112: 1084 FINANCING PV GROWTH Such PV sy
Page 1113 and 1114: 1086 FINANCING PV GROWTH approved a
Page 1115 and 1116: 1088 FINANCING PV GROWTH Ghana: ren
Page 1117 and 1118: 1090 FINANCING PV GROWTH Table 24.3
Page 1119 and 1120: 1092 FINANCING PV GROWTH with succe
Page 1121 and 1122: 1094 FINANCING PV GROWTH 24.8.2 Dir
Page 1123 and 1124: 1096 FINANCING PV GROWTH using a 40
Page 1125 and 1126: 1098 FINANCING PV GROWTH Current do
Page 1127 and 1128: 1100 FINANCING PV GROWTH 3503 RE Ut
Page 1129 and 1130: 1102 FINANCING PV GROWTH was capita
Page 1131 and 1132: 1104 FINANCING PV GROWTH Policy and
Page 1133 and 1134: 1106 FINANCING PV GROWTH E-mail: We
Page 1135 and 1136: 1108 FINANCING PV GROWTH Triodos Ba
Page 1137 and 1138: 1110 FINANCING PV GROWTH Contact: G
Page 1139 and 1140: 1112 FINANCING PV GROWTH Phone: 94
Page 1141 and 1142: 1114 FINANCING PV GROWTH Fax: 91 11
Page 1143 and 1144: Index Index Terms Links A a-Si see
Page 1145 and 1146: Index Terms Links III-V multijuncti
Page 1147 and 1148: Index Terms Links module temperatur
Page 1149 and 1150: Index Terms Links CdTe modules 651
Page 1151: Index Terms Links early demonstrati
Page 1155 and 1156: Index Terms Links daily irradiation
Page 1157 and 1158: Index Terms Links module fabricatio
Page 1159 and 1160: Index Terms Links electricity produ
Page 1161 and 1162: Index Terms Links extensive variabl
Page 1163 and 1164: Index Terms Links lattice matching
Page 1165 and 1166: Index Terms Links heat load and day
Page 1167 and 1168: Index Terms Links intensive variabl
Page 1169 and 1170: Index Terms Links chemistry 827 828
Page 1171 and 1172: Index Terms Links Meteosat weather
Page 1173 and 1174: Index Terms Links thin-film silicon
Page 1175 and 1176: Index Terms Links energy collection
Page 1177 and 1178: Index Terms Links powerguard flat-r
Page 1179 and 1180: Index Terms Links rooftop PV genera
Page 1181 and 1182: Index Terms Links Siemens Solar Bor
Page 1183 and 1184: Index Terms Links Sofrel flat-roof
Page 1185 and 1186: Index Terms Links Solar Terrestrial
Page 1187 and 1188: Index Terms Links SunPower Corporat
Page 1189 and 1190: Index Terms Links surface texture 3
Page 1191: Index Terms Links waferin 223 224 2
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