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INTRODUCTION 63<br />

2500<br />

5762 K black body<br />

2000<br />

AM0<br />

AM1.5g<br />

Incident power<br />

[W/cm 2 /µm]<br />

1500<br />

1000<br />

500<br />

0<br />

0.0<br />

0.5 1.0<br />

Wavelength<br />

[µm]<br />

1.5 2.0<br />

Figure 3.2 The radiation spectrum for a black body at 5762 K, an AM0 spectrum, and an AM1.5<br />

global spectrum<br />

cell. The Air Mass number is therefore further defined by whether or not the measured<br />

spectrum includes the diffuse component. An AM1.5g (global) spectrum includes the diffuse<br />

component, while an AM1.5d (direct) does not. Black body (T = 5762 K), AM0, and<br />

AM1.5g radiation spectrums are shown in Figure 3.2. The Air Mass and solar radiation<br />

are described in more detail in Chapters 16 and 20.<br />

The physical principles underlying the operation of solar cells are the subject of<br />

this chapter. First, a brief review of the fundamental properties of semiconductors is<br />

given that includes an overview of semiconductor band structure and carrier generation,<br />

recombination, and transport. Next, the electrostatic properties of the pn-junction diode are<br />

reviewed, followed by a description of the basic operating characteristics of the solar cell,<br />

including the derivation (based on the solution of the minority-carrier diffusion equation)<br />

of an expression for the current–voltage characteristic of an idealized solar cell. This<br />

is used to define the basic solar cell figures of merit, namely, the open-circuit voltage,<br />

V OC ; the short-circuit current, I SC ;thefillfactor,FF; the conversion efficiency, η; andthe<br />

collection efficiency, η C . Much of the discussion here centers on how carrier recombination<br />

is the primary factor controlling solar cell performance. Finally, some additional topics<br />

relevant to solar cell operation, design, and analysis are presented. These include the<br />

relationship between band gap and efficiency, the solar cell spectral response, parasitic<br />

resistive effects, temperature effects, a brief introduction to some modern cell design<br />

concepts, and a short overview of detailed numerical modeling of solar cells.

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