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MULTIPLE-JUNCTION SOLAR CELLS 545 0 −5 Current density [mA/cm 2 ] −10 −15 E G (eV) 1.84 1.65 1.50 1.37 0.0 0.2 0.4 0.6 0.8 1.0 Voltage [V] Figure 12.23 Performance of a-Si and a-SiGe nip solar cells with different Ge concentrations in the i-layer; the i-layer band gaps are indicated in the legend. The fill factors for these cells are 0.70, 0.62, 0.55, and 0.43 for the cells with i-layer band gaps of 1.84, 1.65, 1.50, and 1.37 eV, respectively [149] Quantum efficiency 1.0 0.8 0.6 0.4 0.2 Photon energy [eV] 3.5 3 2.5 2 1.5 Band gap (eV) (a) 1.84 (b) 1.65 (c) 1.50 (d) 1.37 (e) 1.50 (BR) (f) µc-Si 0.0 400 500 600 700 800 900 1000 Wavelength l [nm] Figure 12.24 Quantum efficiency (QE) spectra for a series of a-Si- and a-SiGe-based pin single-junction solar cells. Shown in the figure are QE curves for single junction solar cells with (a) 1.84 eV a-Si i-layer, (b) 1.65 eV a-SiGe i-layer, (c) 1.50 eV a-SiGe i-layer, (d) 1.37 eV a-SiGe i-layer, (e) 1.50 eV a-SiGe i-layer, with the device deposited on a back-reflector (BR), (f) µc-Si i-layer. Curve (f) is included here for a later discussion in Section 12.5.4. Curves (a) through (e) are from [149] and curve (f) is from [150]
546 AMORPHOUS SILICON–BASED SOLAR CELLS When the Ge content is increased such that the band gap of a-SiGe is reduced below 1.4 eV (see the J–V curve for the 1.37-eV cell in Figure 12.23), the FF deteriorates rapidly. In this case, the short-circuit current density does not increase compared to the 1.50-eV cell even though more photons are absorbed. This lack of increase in J SC with further decrease in the band gap occurs because the fraction of photocarriers that recombine has become more significant than the increase in the rate of photocarrier generation. Similar to the deposition of a-Si, a-SiGe films and devices made with high hydrogen dilution show improved quality and light stability [151]. Optoelectronic properties of narrow band gap a-SiGe material are nonetheless inferior to those of a-Si. 12.5.2.1 Band gap grading To enhance the fill factor of cells made using a-SiGe, band gap grading is used to enhance the collection of holes [152, 153]. In such a design, an asymmetric “V”-shaped band gap profile is created by adjusting the Ge content across the i-layer. Wider band gap material lies closest to the n- andp-layers. The plane of narrowest band gap lies closer to the p-layer (through which the photons enter into the device). Such a grading scheme allows more light to be absorbed near the p-layer so that “slower” holes do not have to travel far to get collected (see Figure 12.10). Also, the tilting of the valence band assists holes generated in the middle or near the n-side of the i-layer to move toward the p-layer. With appropriate hydrogen dilution during growth and band gap grading, a-SiGe cells can be made to generate up to 24.4 mA/cm 2 (27 mA/cm 2 as the bottom cell in a triple cell) when a light enhancing back reflector is used [154]. 12.5.2.2 a-SiC alloys The band gap of a-SiC can be adjusted between 1.7 and 2.2 eV, depending mainly on the C concentration [155]. After extensive research, most workers decided that a-SiC is not suitable for use as the i-layer of the uppermost cell in a multijunction structure. After light soaking, a-SiC material that has an appreciable band gap increase over a-Si is fairly defective and must be used in very thin layers; these layers do not absorb enough sunlight to be optimal. The wide band gap material presently used in triple-junction cells is a-Si with a relatively higher concentration of H (achieved by using lower substrate temperature and H dilution) [8]. 12.5.3 a-Si/a-SiGe Tandem and a-Si/a-SiGe/a-SiGe Triple-junction Solar Cells Several types of multijunction solar cells have been used in a-Si photovoltaics. Dualjunction a-Si/a-Si (same band gap tandem) solar cells have lower material cost than tandem cells using a-SiGe, but have lower efficiencies than more advanced structures [156]. Dual-junction a-Si/a-SiGe cell and triple-junction a-Si/a-SiGe/a-SiGe cells, which use a spectrum-splitting approach to collect the sunlight, achieve higher conversion efficiencies. Some additional details and references may be found later in Table 12.4. Among these, a-Si(1.8 eV)/a-SiGe(1.6 eV)/a-SiGe(1.4 eV) triple-junction solar cells have been used to obtain the most efficient a-Si-based cells today [8]. Figure 12.25 shows the structure of
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Handbook of Photovoltaic Science an
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We dedicate this book to all those
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xxiv LIST OF CONTRIBUTORS Phone: +1
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xxvi LIST OF CONTRIBUTORS 28040 Mad
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Contents List of Contributors xxiii
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CONTENTS ix 4.3.1 The Balance Equat
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CONTENTS xi 7.4 Manufacturing Proce
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CONTENTS xiii 9.8 Future-generation
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CONTENTS xv 12.1.2 Designs for Amor
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CONTENTS xvii 14.3.3 CdS/CdTe Inter
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CONTENTS xix 18.2.2 Batteries with
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CONTENTS xxi 22.2 PV in Architectur
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1 Status, Trends, Challenges and th
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WHAT IS PHOTOVOLTAICS? 3 1.2 WHAT I
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SIX MYTHS OF PHOTOVOLTAICS 5 Sunlig
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SIX MYTHS OF PHOTOVOLTAICS 7 of 10
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SIX MYTHS OF PHOTOVOLTAICS 9 2500 W
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HISTORY OF PHOTOVOLTAICS 11 the maj
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HISTORY OF PHOTOVOLTAICS 13 the USA
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PV COSTS, MARKETS AND FORECASTS 15
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PV COSTS, MARKETS AND FORECASTS 17
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GOALS OF PV RESEARCH AND MANUFACTUR
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GLOBAL TRENDS IN PERFORMANCE AND AP
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CRYSTALLINE SILICON PROGRESS AND CH
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CRYSTALLINE SILICON PROGRESS AND CH
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THIN FILM PROGRESS AND CHALLENGES 2
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THIN FILM PROGRESS AND CHALLENGES 2
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CONCENTRATION PV SYSTEMS 31 reality
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BALANCE OF SYSTEMS 33 Percentage of
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BALANCE OF SYSTEMS 35 Total capital
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FUTURE OF EMERGING PV TECHNOLOGIES
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CONCLUSIONS 39 Yet, in all these al
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REFERENCES 41 the other hand, hybri
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REFERENCES 43 69. Mickelson R, Chen
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46 MOTIVATION FOR PV APPLICATION AN
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62 THE PHYSICS OF THE SOLAR CELL Su
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64 THE PHYSICS OF THE SOLAR CELL 3.
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66 THE PHYSICS OF THE SOLAR CELL E
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72 THE PHYSICS OF THE SOLAR CELL an
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74 THE PHYSICS OF THE SOLAR CELL pr
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76 THE PHYSICS OF THE SOLAR CELL No
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80 THE PHYSICS OF THE SOLAR CELL El
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82 THE PHYSICS OF THE SOLAR CELL wh
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84 THE PHYSICS OF THE SOLAR CELL n
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86 THE PHYSICS OF THE SOLAR CELL Th
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88 THE PHYSICS OF THE SOLAR CELL Th
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94 THE PHYSICS OF THE SOLAR CELL Ta
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96 THE PHYSICS OF THE SOLAR CELL cu
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100 THE PHYSICS OF THE SOLAR CELL 5
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102 THE PHYSICS OF THE SOLAR CELL I
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106 THE PHYSICS OF THE SOLAR CELL T
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108 THE PHYSICS OF THE SOLAR CELL S
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114 THEORETICAL LIMITS OF PHOTOVOLT
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5 Solar Grade Silicon Feedstock Bru
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SILICON 155 faces of silicon are (1
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SILICON 157 powder in the presence
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SILICON 159 5.2.4.1.2 Wrought alloy
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PRODUCTION OF METALLURGICAL GRADE S
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PRODUCTION OF SEMICONDUCTOR GRADE S
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CURRENT SILICON FEEDSTOCK TO SOLAR
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CURRENT SILICON FEEDSTOCK TO SOLAR
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REQUIREMENTS OF SILICON FOR CRYSTAL
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ROUTES TO SOLAR GRADE SILICON 193 c
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ROUTES TO SOLAR GRADE SILICON 195 c
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ROUTES TO SOLAR GRADE SILICON 197 d
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ROUTES TO SOLAR GRADE SILICON 199 d
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CONCLUSIONS 201 2. Another German c
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REFERENCES 203 34. Fischler S, J. A
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6 Bulk Crystal Growth and Wafering
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BULK MONOCRYSTALLINE MATERIAL 207 b
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BULK MONOCRYSTALLINE MATERIAL 209 (
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BULK MONOCRYSTALLINE MATERIAL 211 O
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BULK MONOCRYSTALLINE MATERIAL 213 8
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BULK MULTICRYSTALLINE SILICON 215 I
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BULK MULTICRYSTALLINE SILICON 217 1
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BULK MULTICRYSTALLINE SILICON 219 b
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BULK MULTICRYSTALLINE SILICON 221 L
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WAFERING 223 This in turn verifies
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WAFERING 225 suspension of hard gri
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WAFERING 227 tips, they can exert v
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WAFERING 229 6.4.3 Wafer Quality an
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SILICON RIBBON AND FOIL PRODUCTION
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NUMERICAL SIMULATIONS OF CRYSTAL GR
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CONCLUSIONS 251 the supercooling de
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REFERENCES 253 28. Sahoo R et al.,
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7 Crystalline Silicon Solar Cells a
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CRYSTALLINE SILICON AS A PHOTOVOLTA
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CRYSTALLINE SILICON SOLAR CELLS 259
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MANUFACTURING PROCESS 271 The most
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MANUFACTURING PROCESS 273 3. Textur
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MANUFACTURING PROCESS 275 materials
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MANUFACTURING PROCESS 277 nearly 50
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MANUFACTURING PROCESS 279 Figure 7.
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VARIATIONS TO THE BASIC PROCESS 281
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MULTICRYSTALLINE CELLS 283 of defec
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MULTICRYSTALLINE CELLS 285 better s
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MULTICRYSTALLINE CELLS 287 Figure 7
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OTHER INDUSTRIAL APPROACHES 289 TCO
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CRYSTALLINE SILICON PHOTOVOLTAIC MO
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CRYSTALLINE SILICON PHOTOVOLTAIC MO
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ELECTRICAL AND OPTICAL PERFORMANCE
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FIELD PERFORMANCE OF MODULES 301 7.
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REFERENCES 303 REFERENCES 1. Luque
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REFERENCES 305 75. Lenkeit B et al.
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8 Thin-film Silicon Solar Cells Bhu
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INTRODUCTION 309 Open circuit volta
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A REVIEW OF CURRENT THIN-FILM SI CE
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CVD Excimer laser crystallization U
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n-type silicon (0.2 µm) p-type sil
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DESIGN CONCEPTS OF TF-SI SOLAR CELL
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CONCLUSION 353 Introduction of H af
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REFERENCES 355 17. Kamins T, Ed, Po
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REFERENCES 357 98. Symko M, Sopori
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360 HIGH-EFFICIENCY III-V MULTIJUNC
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10 Space Solar Cells and Arrays She
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THE HISTORY OF SPACE SOLAR CELLS 41
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THE CHALLENGE FOR SPACE SOLAR CELLS
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SILICON SOLAR CELLS 425 Figure 10.7
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III-V SOLAR CELLS 427 n+-GaAs n-AlI
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III-V SOLAR CELLS 429 missions with
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SPACE SOLAR ARRAYS 431 supported af
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SPACE SOLAR ARRAYS 433 JPL-25888AC
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SPACE SOLAR ARRAYS 435 Figure 10.13
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SPACE SOLAR ARRAYS 437 Figure 10.15
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SPACE SOLAR ARRAYS 439 0.31 Astrono
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FUTURE CELL AND ARRAY POSSIBILITIES
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FUTURE CELL AND ARRAY POSSIBILITIES
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POWER SYSTEM FIGURES OF MERIT 445 A
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REFERENCES 447 8. Statler R, Curtin
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11 Photovoltaic Concentrators Richa
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INTRODUCTION 451 markets most often
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BASIC TYPES OF CONCENTRATORS 453 ha
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BASIC TYPES OF CONCENTRATORS 455 is
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BASIC TYPES OF CONCENTRATORS 457 sk
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BASIC TYPES OF CONCENTRATORS 459 Ho
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HISTORICAL OVERVIEW 461 thereafter.
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HISTORICAL OVERVIEW 463 Figure 11.6
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HISTORICAL OVERVIEW 465 production
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HISTORICAL OVERVIEW 467 Figure 11.1
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HISTORICAL OVERVIEW 469 n + bussbar
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HISTORICAL OVERVIEW 471 array [33].
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HISTORICAL OVERVIEW 473 Solar radia
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OPTICS OF CONCENTRATORS 475 q max,
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OPTICS OF CONCENTRATORS 477 If r 1
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OPTICS OF CONCENTRATORS 479 r i Med
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OPTICS OF CONCENTRATORS 481 When θ
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OPTICS OF CONCENTRATORS 483 filled
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OPTICS OF CONCENTRATORS 485 q i q i
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OPTICS OF CONCENTRATORS 487 For lar
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OPTICS OF CONCENTRATORS 489 on a co
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OPTICS OF CONCENTRATORS 491 gleaned
Page 515 and 516: OPTICS OF CONCENTRATORS 493 Solar c
Page 517 and 518: CURRENT CONCENTRATOR ACTIVITIES 495
Page 523 and 524: REFERENCES 501 11. Boes E, “Photo
Page 525 and 526: REFERENCES 503 60. Uematsu T et al.
Page 527 and 528: 506 AMORPHOUS SILICON-BASED SOLAR C
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Page 589 and 590: INTRODUCTION 569 CdS. The latter en
Page 591 and 592: MATERIAL PROPERTIES 571 Even though
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Page 613 and 614: DEVICE OPERATION 593 the voltage. F
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DEVICE OPERATION 597 1.4 V OC [Volt
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DEVICE OPERATION 599 13.5.3 The Cu(
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DEVICE OPERATION 601 Table 13.5 Hig
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MANUFACTURING ISSUES 603 can well f
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MANUFACTURING ISSUES 605 P1 P1 Mo G
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MANUFACTURING ISSUES 607 Finally, f
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THE Cu(InGa)Se 2 OUTLOOK 609 active
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REFERENCES 611 With all these chall
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REFERENCES 613 81. Stolt L, Hedstr
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REFERENCES 615 168. Fahrenbruch A,
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14 Cadmium Telluride Solar Cells Br
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INTRODUCTION 619 In contrast to p/n
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CdTe PROPERTIES AND THIN-FILM FABRI
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CdTe THIN-FILM SOLAR CELLS 631 orie
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CdTe THIN-FILM SOLAR CELLS 633 14.3
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CdTe THIN-FILM SOLAR CELLS 635 CdTe
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CdTe THIN-FILM SOLAR CELLS 639 800
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CdTe THIN-FILM SOLAR CELLS 641 10
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CdTe THIN-FILM SOLAR CELLS 645 forw
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CdTe THIN-FILM SOLAR CELLS 647 30 R
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CdTe THIN-FILM SOLAR CELLS 649 The
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CdTe MODULES 651 14.4 CdTe MODULES
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THE FUTURE OF CdTe-BASED SOLAR CELL
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THE FUTURE OF CdTe-BASED SOLAR CELL
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REFERENCES 657 This chapter has sho
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REFERENCES 659 60. Wei S, Mtg. Reco
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REFERENCES 661 152. McCandless B, Q
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15 Dye-sensitized Solar Cells Kohji
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INTRODUCTION TO DYE-SENSITIZED SOLA
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DSSC FABRICATION (η = 8%) 679 alko
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DSSC FABRICATION (η = 8%) 681 15.2
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NEW DEVELOPMENTS 683 of highly effi
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NEW DEVELOPMENTS 685 HOOC COOH HOOC
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NEW DEVELOPMENTS 687 photosensitize
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NEW DEVELOPMENTS 689 of these ionic
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APPROACH TO COMMERCIALIZATION 691 1
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Institute and reference Table 15.3
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SUMMARY AND PROSPECTS 695 Chemicals
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REFERENCES 697 4. Dare-Edwards M et
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REFERENCES 699 96. Tennakone K, Kum
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16 Measurement and Characterization
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RATING PV PERFORMANCE 703 Spectral
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λ [nm] Table 16.3 AM0 standard sol
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171.5 7.01E − 1 372.5 1074 573.5
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228.5 52.940 429.5 1501 630.7 1682
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288.5 328.400 489.5 1994 689.1 1506
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RATING PV PERFORMANCE 713 The extra
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RATING PV PERFORMANCE 715 of about
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RATING PV PERFORMANCE 717 Energy [W
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RATING PV PERFORMANCE 719 16.2.4 Tr
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CURRENT VERSUS VOLTAGE MEASUREMENTS
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SPECTRAL RESPONSIVITY MEASUREMENTS
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MODULE QUALIFICATION AND CERTIFICAT
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REFERENCES 747 REFERENCES 1. Emery
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REFERENCES 749 62. Standard IEC 608
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REFERENCES 751 130. Dondero R, Zirk
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17 Photovoltaic Systems Klaus Preis
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PV POWER SYSTEM CONFIGURATION AND A
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COMPONENTS FOR PV SYSTEMS 785 NASA
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COMPONENTS FOR PV SYSTEMS 787 volta
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COMPONENTS FOR PV SYSTEMS 789 well
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COMPONENTS FOR PV SYSTEMS 791 A sig
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COMPONENTS FOR PV SYSTEMS 793 In st
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FUTURE DEVELOPMENTS IN PHOTOVOLTAIC
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REFERENCES 797 CL Controllable load
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18 Electrochemical Storage for Phot
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GENERAL CONCEPT OF ELECTROCHEMICAL
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TYPICAL OPERATION CONDITIONS OF BAT
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TYPICAL OPERATION CONDITIONS OF BAT
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SECONDARY ELECTROCHEMICAL ACCUMULAT
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Table 18.4 Overview of the technica
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BATTERY SYSTEMS WITH EXTERNAL STORA
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INVESTMENT AND LIFETIME COST CONSID
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CONCLUSION 859 This example is just
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REFERENCES 861 10. Ruddell A et al.
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19 Power Conditioning for Photovolt
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CONTROLLERS AND MONITORING SYSTEMS
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INVERTERS 881 19.2 INVERTERS 19.2.1
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INVERTERS 883 Current [A] MPP Power
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INVERTERS 885 S1 S3 DC source AC ou
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INVERTERS 887 V PV V load t 0 t 1 t
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INVERTERS 889 The resulting voltage
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INVERTERS 891 12 V 24 V 48 V 96 V 1
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INVERTERS 893 U DC voltage level U
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INVERTERS 895 100 55 Hz 50 Hz Frequ
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INVERTERS 897 S1 L C 1 C 2 AC outpu
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INVERTERS 899 Time delay Seconds Mi
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INVERTERS 901 Separated part of the
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REFERENCES 903 5. Gonzalez G, Hill
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906 ENERGY COLLECTED AND DELIVERED
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972 ECONOMIC ANALYSIS OF PV SYSTEMS
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1000 ECONOMIC ANALYSIS OF PV SYSTEM
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1002 ECONOMIC ANALYSIS OF PV SYSTEM
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22 PV in Architecture Tjerk H. Reij
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INTRODUCTION 1007 Figure 22.2 Integ
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PV IN ARCHITECTURE 1009 Figure 22.4
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PV IN ARCHITECTURE 1013 Heat load a
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PV IN ARCHITECTURE 1015 • aesthet
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BIPV BASICS 1027 22.3.1.2 Categorie
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BIPV BASICS 1029 Figure 22.34 Alute
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BIPV BASICS 1031 Figure 22.38 Solgr
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BIPV BASICS 1033 Figure 22.42 Canop
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BIPV BASICS 1035 cooling as possibl
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STEPS IN THE DESIGN PROCESS WITH PV
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STEPS IN THE DESIGN PROCESS WITH PV
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REFERENCES 1041 REFERENCES 1. Reije
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23 Photovoltaics and Development Jo
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ELECTRICITY AND DEVELOPMENT 1045 pe
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BREAKING THE CHAINS OF UNDERDEVELOP
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THE PV ALTERNATIVE 1049 was too exp
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THE PV ALTERNATIVE 1051 Basic light
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THE PV ALTERNATIVE 1053 (for a deta
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THE PV ALTERNATIVE 1055 issued by t
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THE PV ALTERNATIVE 1057 Needless to
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THE PV ALTERNATIVE 1059 exports bal
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FOUR EXAMPLES OF PV RURAL ELECTRIFI
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REFERENCES 1069 standard of living
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REFERENCES 1071 36. Martinot E et a
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1074 FINANCING PV GROWTH 1995 : The
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1076 FINANCING PV GROWTH 24.2.3 Cap
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1078 FINANCING PV GROWTH can range
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1080 FINANCING PV GROWTH 24.4.2 Typ
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1082 FINANCING PV GROWTH 24.4.5 Exa
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1084 FINANCING PV GROWTH Such PV sy
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1086 FINANCING PV GROWTH approved a
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1088 FINANCING PV GROWTH Ghana: ren
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1090 FINANCING PV GROWTH Table 24.3
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1092 FINANCING PV GROWTH with succe
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1094 FINANCING PV GROWTH 24.8.2 Dir
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1096 FINANCING PV GROWTH using a 40
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1098 FINANCING PV GROWTH Current do
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1100 FINANCING PV GROWTH 3503 RE Ut
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1102 FINANCING PV GROWTH was capita
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1104 FINANCING PV GROWTH Policy and
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1106 FINANCING PV GROWTH E-mail: We
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1108 FINANCING PV GROWTH Triodos Ba
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1110 FINANCING PV GROWTH Contact: G
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1112 FINANCING PV GROWTH Phone: 94
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1114 FINANCING PV GROWTH Fax: 91 11
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Index Index Terms Links A a-Si see
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Index Terms Links III-V multijuncti
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Index Terms Links module temperatur
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Index Terms Links CdTe modules 651
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Index Terms Links early demonstrati
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Index Terms Links crystalline silic
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Index Terms Links daily irradiation
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Index Terms Links module fabricatio
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Index Terms Links electricity produ
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Index Terms Links extensive variabl
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Index Terms Links lattice matching
Page 1165 and 1166:
Index Terms Links heat load and day
Page 1167 and 1168:
Index Terms Links intensive variabl
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Index Terms Links chemistry 827 828
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Index Terms Links Meteosat weather
Page 1173 and 1174:
Index Terms Links thin-film silicon
Page 1175 and 1176:
Index Terms Links energy collection
Page 1177 and 1178:
Index Terms Links powerguard flat-r
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Index Terms Links rooftop PV genera
Page 1181 and 1182:
Index Terms Links Siemens Solar Bor
Page 1183 and 1184:
Index Terms Links Sofrel flat-roof
Page 1185 and 1186:
Index Terms Links Solar Terrestrial
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Index Terms Links SunPower Corporat
Page 1189 and 1190:
Index Terms Links surface texture 3
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Index Terms Links waferin 223 224 2
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