Narcissus and Daffodil

Table 6.3 Continued
Alkaloid* Formula MW Spectroscopic data References
51 haemanthidine C17H19NO5 317 UV
IR, MS
1
H NMR
13
C NMR
CD
52 6-epihaemanthidine C17H19NO5 317 UV
IR, MS
1
H NMR
13
C NMR
CD
30 hippeastrine C17H17NO5 315 UV
IR, MS, 1 H NMR,
13
C NMR
CD
23 homolycorine C18H21NO4 315 UV, IR, MS,
1
H NMR
13
C NMR
CD
24 8-O-demethylhomolycorine
37 8-O-demethylhomolycorine-
N-oxide
25 8-O-demethyl-8-Oacetylhomolycorine
26 9-O-demethylhomolycorine
29 9-O-demethyl-
2α-hydroxyhomolycorine
C 17H 19NO 4 301 UV, IR, 1 H NMR,
13 C NMR
MS
CD
X-Ray
C 17 H 19 NO 5 317 UV, IR, MS,
1 H NMR, 13 C NMR
C 19H 21NO 5 343 IR, MS, 1 H NMR,
13 C NMR
C 17H 19NO 4 301 UV, IR, MS,
1 H NMR, 13 C NMR
C 17 H 19 NO 5 317 IR, MS, 1 H NMR,
13 C NMR
67 ismine C 15H 15NO 3 257 UV, IR, MS,
1 H NMR
1 H NMR, 13 C NMR
X-Ray
Irie et al., 1959
Trimiño et al., 1989
Pabuççuoglu et al., 1989
Antoun et al., 1993
Wagner et al., 1996
Irie et al., 1959
Trimiño et al., 1989
Pabuççuoglu et al., 1989
Antoun et al., 1993
Wagner et al., 1996
Irie et al., 1959
Almanza et al., 1996
Wagner et al., 1996
Bastida et al., 1987a
Jeffs et al., 1985
Wagner et al., 1996
Latvala et al., 1995b
Bastida et al., 1988c
Wagner et al., 1996
Latvala et al., 1995a
Suau et al., 1990a
Bastida et al., 1992a
Bastida et al., 1987a
Bastida et al., 1990b
Suau et al., 1990b
Viladomat et al., 1997
Viladomat et al., 1998
9 jonquilline C18H17NO5 327 UV, IR Döpke and Dalmer, 1965a
77 lycoramine C17H23NO3 289 IR, MS, 1 H NMR,
13
C NMR
Li et al., 1987
13
C NMR
Kobayashi et al., 1991
13
C NMR
Youssef and Frahm, 1998
78 norlycoramine C16H21NO3 275 IR, MS, 1 H NMR Kihara et al., 1987
79 epinorlycoramine C16H21NO3 275 IR, MS, 1 H NMR,
13
C NMR
Bastida et al., 1993
31 lycorenine C18H23NO4 317 UV
MS
Kitagawa et al., 1955
Ibuka et al., 1966
1 13
H NMR, C NMR Codina et al., 1992a
X-Ray
Clardy et al., 1972