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BAKER HUGHES - Drilling Fluids Reference Manual

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TABLE OF CONTENTS<br />

Figure 13 - 4<br />

Gas Hydrates in Seawater<br />

(Phase Diagram)<br />

Depth (km)<br />

0<br />

0.3<br />

1<br />

2<br />

3<br />

4<br />

Methane Hydrate &<br />

Sea Water - Stable<br />

Methane Gas<br />

& Sea W ater<br />

- Stable<br />

0 10 20 30<br />

Temperature °C<br />

Gas Hydrate Stability Curve<br />

To the left is a curve representing the stability<br />

of gas hydrates in sea water. Pressure and<br />

temperature are two of the major factors<br />

controlling where the hydrate (solid) or<br />

methane gas will be stable. Whether or not gas<br />

hydrate actually forms depends on the amount<br />

of gas available.<br />

IN-SITU HYDRATES<br />

In-situ hydrates can exist at various depths below the seabed and may be encountered while drilling in<br />

deepwater virtually anywhere in the world where there are sufficiently high pressures to favor hydrate<br />

formation. Gas may exist below the in-situ hydrates.<br />

Associated Problems<br />

1. Maintaining competency of in-situ hydrates while drilling and cementing<br />

2. Maintaining static well conditions while drilling and cementing in gas/water<br />

3. Obtaining a competent cement job in a gas environment<br />

Problem Resolution: It may be possible to drill the in-situ hydrate section without incurring hydrate<br />

dissociation. Dissociation of the hydrates will lead to an enlarged hole section which will negatively<br />

impact both the cement bond/hydraulic seal and lateral casing support. To maintain the in-situ<br />

hydrates in a competent state, special attention needs to be paid to the annular temperature during<br />

drilling, cementing and cement transitional period.<br />

<strong>Drilling</strong><br />

• Simulations can be performed to predict fluid circulating temperatures inside the drill pipe<br />

and in the annulus.<br />

• If annular temperature does not exceed the hydrate equilibrium temperature, nothing more is<br />

necessary.<br />

• If annular temperature exceeds the hydrate equilibrium temperature, several options should<br />

be explored:<br />

• Increasing the mud weight, thus pressure in the annulus, if fracture pressure will allow<br />

• Utilize lecithin to retard the rate of dissociation<br />

• Reduce the target depth of the surface casing, so as to reduce the annular temperature<br />

<strong>BAKER</strong> <strong>HUGHES</strong> DRILLING FLUIDS<br />

REFERENCE MANUAL<br />

REVISION 2006 13-13

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