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1996 Electronics Industry Environmental Roadmap - Civil and ...

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Emerging Technologies<br />

of-use chemical generation, water recycling, process material minimization, <strong>and</strong> chemical<br />

reprocessing.<br />

The IPC roadmap identifies a specific agenda of material <strong>and</strong> chemical replacement,<br />

including brominated materials, solder replacements, ODS <strong>and</strong> VOC elimination in<br />

cleaning, <strong>and</strong> the development of aqueous solder masks. The IPC roadmap also<br />

emphasizes the importance of solvent recovery <strong>and</strong> closed loop techniques <strong>and</strong> additive<br />

processes <strong>and</strong> direct plating [36].<br />

The SIA roadmap also calls for hazardous chemical use reductions, reducing use <strong>and</strong><br />

waste-at-the-point-of-use through process efficiency, reuse, substitution, <strong>and</strong> additive<br />

technologies [31]. This includes total phase-outs of ozone-depleting substances <strong>and</strong><br />

ethylene glycol ethers. Establishment of specific emission reduction goals is<br />

recommended, including efforts to use control technologies for emissions reductions until<br />

source reductions take effect. The roadmap also recommends efforts to reduce natural<br />

resources required to produce wafers <strong>and</strong> devices, with specific emphasis on water <strong>and</strong><br />

energy.<br />

Other challenges also remain, <strong>and</strong> are reflected in the recommendations of the individual<br />

roadmaps. For example:<br />

– Alternatives should be found to lead-based solders, including lead-free solders <strong>and</strong><br />

conductive adhesives.<br />

– New coatings or chemical formulations, used to improve processes or to enhance performance,<br />

are beginning to emerge <strong>and</strong> require environmental characterization. In IC<br />

manufacturing, for example, increased aspect ratios in lithography may require chemically<br />

amplified resists to maintain the requirements of process latitude, etch<br />

resistance, implant blocking, <strong>and</strong> mechanical stability [31]. In the fabrication of<br />

substrates <strong>and</strong> displays, diamond coatings have received considerable attention due to<br />

the manufacturability <strong>and</strong> performance benefits they promise. Effective<br />

environmental characterization methods must be applied early in the development<br />

process in order to avoid problems in later stages of production.<br />

– Emission abatement, processing optimization, <strong>and</strong> replacement chemicals for atmospherically<br />

long-lived process gases, such as perfluoro compounds.<br />

– Alternative chemicals <strong>and</strong> safer delivery methods for silane, dopants, <strong>and</strong> hazardous<br />

solvents <strong>and</strong> degreasers.<br />

– Evaluation of OEM/government specifications to ensure support for reduction or<br />

elimination of targeted chemicals.<br />

– Recycling or end-of-life management for cupric chloride <strong>and</strong> ammoniacal etchants,<br />

the largest single waste stream for most PWB manufacturers [36].<br />

Processes: The SIA roadmap notes that “There will not be radical changes in the process<br />

technology used to manufacture semiconductors throughout this decade. Rather, there<br />

will be expansion <strong>and</strong> refinement of current processes.” [31].<br />

Adapting to the rapid evolution of technology will require its own set of technology advancements<br />

to ensure that processes <strong>and</strong> materials are suited to the technologies that they<br />

must address. NEMI succinctly states the goal: “Cost-effectiveness implies high levels<br />

109

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