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Introduction to Nanotechnology

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5.5. APPLICATIONS OF CARBON NANOTUBES 125<br />

counterparts. For example, multi-walled nanotubes of 200 nm diameter have a tensile<br />

strength of 0.007 TPa (i.e., 7 GPa) and a modulus of 0.6 TPa.<br />

5.5. APPLICATIONS OF CARBON NANOTUBES<br />

The unusual properties of carbon nanotubes make possible many applications<br />

ranging from battery electrodes, <strong>to</strong> electronic devices, <strong>to</strong> reinforcing fibers, which<br />

make stronger composites. In this section we describe some of the potential ap-<br />

plications that researchers are now working on. However, for the application poten-<br />

tial <strong>to</strong> be realized, methods for large-scale production of single-walled carbon<br />

nanotubes will have <strong>to</strong> be developed. The present synthesis methods provide only<br />

small yields, and make the cost of the tubes about $1500 per gram ($680,000 per<br />

pound). On the other hand, large-scale production methods based on chemical<br />

deposition have been developed for multiwalled tubes, which are presently available<br />

for $60 per pound, and as demand increases, this price is expected <strong>to</strong> drop sig-<br />

nificantly. The methods used <strong>to</strong> scale up the multiwalled tubes should provide the<br />

basis for scaling up synthesis of single-walled nanotubes. Because of the enormous<br />

application potential, it might be reasonable <strong>to</strong> hope that large-scale synthesis<br />

methods will be developed, resulting in a decrease in the cost <strong>to</strong> the order of $10<br />

per pound.<br />

5.5.1. Field Emission and Shielding<br />

When a small electric field is applied parallel <strong>to</strong> the axis of a nanotube, electrons are<br />

emitted at a very high rate from the ends of the tube. This is calledjeld emission.<br />

This effect can easily be observed by applying a small voltage between two parallel<br />

metal electrodes, and spreading a composite paste of nanotubes on one electrode. A<br />

sufficient number of tubes will be perpendicular <strong>to</strong> the electrode so that electron<br />

emission can be observed. One application of this effect is the development of flat<br />

panel displays. Television and computer moni<strong>to</strong>rs use a controlled electron gun <strong>to</strong><br />

impinge electrons on the phosphors of the screen, which then emit light of the<br />

appropriate colors. Samsung in Korea is developing a flat-panel display using the<br />

electron emission of carbon nanotubes. A thin film of nanotubes is placed over<br />

control electronics with a phosphor-coated glass plate on <strong>to</strong>p. A Japanese company<br />

is using this electron emission effect <strong>to</strong> make vacuum tube lamps that are as bright as<br />

conventional light bulbs, and longer-lived and more efficient. Other researchers are<br />

using the effect <strong>to</strong> develop a way <strong>to</strong> generate microwaves.<br />

The high electrical conductivity of carbon nanotubes means that they will be poor<br />

transmitters of electromagnetic energy. A plastic composite of carbon nanotubes<br />

could provide lightweight shielding material for electromagnetic radiation. This is a<br />

matter of much concern <strong>to</strong> the military, which is developing a highly digitized<br />

battlefield for command, control, and communication. The computers and electronic<br />

devices that are a part of this system need <strong>to</strong> be protected from weapons that emit<br />

electromagnetic pulses.

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