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Introduction to Nanotechnology

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9.2. PREPARATION OF QUANTUM NANOSTRUCTURES 227<br />

BULK WELL WIRE DOT<br />

Figure 9.1. Progressive generation of rectangular nanostructures.<br />

BULK WELL WIRE DOT<br />

Figure 9.2. Progressive generation of curvilinear nanostructures.<br />

altered by these changes. Jacak et al. (1998) have surveyed the field of quantum<br />

nanostructures.<br />

9.2. PREPARATION OF QUANTUM NANOSTRUCTURES<br />

One approach <strong>to</strong> the preparation of a nanostructure, called the bot<strong>to</strong>m-up approach,<br />

is <strong>to</strong> collect, consolidate, and fashion individual a<strong>to</strong>ms and molecules in<strong>to</strong> the<br />

structure. This is camed out by a sequence of chemical reactions controlled by<br />

catalysts. It is a process that is widespread in biology where, for example, catalysts<br />

called enzymes assemble amino acids <strong>to</strong> construct living tissue that forms and<br />

supports the organs of the body. The next chapter explains how nature brings about<br />

this variety of self-assembly.<br />

The opposite approach <strong>to</strong> the preparation of nanostructures is called the <strong>to</strong>p-down<br />

method, which starts with a large-scale object or pattern and gradually reduces its<br />

dimension or dimensions. This can be accomplished by a technique called Zitho-<br />

gruphy which shines radiation through a template on <strong>to</strong> a surface coated with a<br />

radiation-sensitive resist; the resist is then removed and the surface is chemically<br />

treated <strong>to</strong> produce the nanostructure. A typical resist material is the polymer<br />

polymethyl methacrylate [C5O2H8In with a molecular weight in the range from

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