Introduction to Nanotechnology

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6.2. NANOSTRUCTURED CRYSTALS 155 Figure 6.23. Possible body-centered structure 01 a lattice made 01 AIr3 nanoparticles and pozasslum (large circles). [Adapted lrom S. N. Khanna and P. Jena. Fhys. Rev. 51, 13705 (1 995) 1 Figure 6.24. Schemalie or cluster assemblies in zeolite pores. (With permission from S. G. Rornanov et al., in Handbook d Nanoslructured Malerials and Namrechnology. 51. S. Naha. ed., Academic Press. San Diego. 2000. Vol. 4, Chaprer 4, p. 236.)
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INTRODUCTION TO NANOTECHNOLOGY Char
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CONTENTS Preface xi 1 Introduction
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5.2 Carbon Molecules 103 5.2.1 Natu
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9.4 Excitons 244 9.5 Single-Electro
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PREFACE In recent years nanotechnol
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INTRODUCTION The prefix nano in the
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INTRODUCTION 3 he recognized the ex
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1000 (I) a 900 4 800 a 900 I 6 700
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INTRODUCTION 7 developed before the
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2.1. STRUCTURE 9 mechanics, the res
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X T 2.1. STRUCTURE 11 Figure 2.4. C
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2.1. STRUCTURE 13 Figure 2.6. Thirt
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Sodium Nanoparticle Na, Magic Numbe
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2.1. STRUCTURE 17 of the large anio
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2.1. STRUCTURE 19 other, and high-f
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2.2. ENERGY BANDS 21 Conduction Ban
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2.2. ENERGY BANDS 23 Figure 2.13. S
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2.2. ENERGYBANDS 25 band at point T
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A X ' Wavevector A Si c z 2.2. ENER
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2.2. ENERGY BANDS 29 bands of Figs.
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2.3. LOCALIZED PARTICLES 31 add ele
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1 meV 10 meV 100 meV FJ E W 1 eV 10
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3 METHODS OF MEASURING PROPERTIES 3
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3.2. STRUCTURE 37 Table 3.1. Crysta
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3.2. STRUCTURE 39 Figure 3.2. Two-d
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3.2. STRUCTURE 41 The widths of the
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44 METHODS OF MEASURING PROPERTIES
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3.3. MICROSCOPY 51 types of transit
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3.3. MICROSCOPY 53 Actual diverging
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Tunneling current Tunneling current
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3.3. MrCAOSCOPY 57 and the latter m
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3.4. SPECTROSCOPY 59 From Eq. (3.8)
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1 Average Panicle FWHM Size (nm) in
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CdSe colloidal NCs a = 1.2 nrn 3.4.
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El X-RAY TUBE 8000 - A 6000 - 4000
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2 N I w 3.0 2.5 2.0 1.5 1 .o 0.5 3.
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i 3.4. SPECTROSCOPY 69 NMR involves
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T=220K - 2G H FURTHER READING 71 Fi
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NUMBER OF ATOMS RADIUS (nm) 1 10 1
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I L 7 3 5 7 9 11 13 15 17 NUMBER OF
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JELLIUM MODEL OF CLUSTERS ATOMS CLU
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1.02 { 1.01 - 1 - 0.99 - 4.2. METAL
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4.2. METAL NANOCLUSTERS 81 Figure 4
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4.2. METAL NANOCLUSTERS 83 Figure 4
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-0 100 200 300 400 500 600 MASSICHA
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a 42. METAL NANOCLUSTERS 87 Figure
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. . . .. . - . D 111111111111111111
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3 4 2.5 0 cn g 2 0 z d 1.5 t a 9 1
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4.3. SEMICONDUCTING NANOPARTICLES 9
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4.4. RARE GAS AND MOLECULAR CLUSTER
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4.5. METHODS OF SYNTHESIS 97 d Figu
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4.5. METHODS OF SYNTHESIS 99 isopro
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PULSED LASER BEAM 1 1 1 1 1 I ROTAT
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5.1. INTRODUCTION CARBON NANOSTRUCT
Page 116 and 117: 5.2. CARBON MOLECULES 105 methane d
Page 118 and 119: 5.3. CARBON CLUSTERS 107 -0 20 40 6
Page 120 and 121: PHOTON ENERGY (electron volts) 5.3.
Page 122 and 123: Figure 5.6. Structure of the CEO fu
Page 124 and 125: 1 30 0 14.1 14.2 14.3 14.4 14.5 LAT
Page 126 and 127: (c) 5.4. CARBON NANOTUBES 115 Figur
Page 128 and 129: 5.4. CARBON NANOTUBES 1 17 The mech
Page 130 and 131: 5.4. CARBON NANOTUBES 11 9 investig
Page 132 and 133: 5.4. CARBON NANOTUBES 121 energy gr
Page 134 and 135: 5.4. CARBON NANOTUBES 123 stretch c
Page 136 and 137: 5.5. APPLICATIONS OF CARBON NANOTUB
Page 140 and 141: - v) 450 : 400 3 350 1 300 : 5 250
Page 144 and 145: BULK NANOSTRUCTURED MATERIALS In th
Page 146 and 147: h 8 0 6.1. SOLID DISORDERED NANOSTR
Page 148 and 149: 6.1. SOLID DISORDERED NANOSTRUCTURE
Page 164 and 165: 6.2. NANOSTRUCTURED CRYSTALS 153 qu
Page 168 and 169: 6.2.4. Crystals of Metal Nanopartic
Page 170 and 171: 6.2. NANOSTRUCTURED CRYSTALS 159 re
Page 172 and 173: 6.2. NANOSTRUCTURED CRYSTALS 161 Fi
Page 174 and 175: 6.2. NANOSTRUCTURED CRYSTALS 163 se
Page 176 and 177: 7.1. BASICS OF FERROMAGNETISM 7 NAN
Page 178 and 179: 7.1. BASICS OF FERROMAGNETISM 167 a
Page 180 and 181: INITIAL CONFIGURATION ,i:k DOMAIN R
Page 182 and 183: 7.2. EFFECT OF BULK NANOSTRUCTURING
Page 184 and 185: - - m Lo v a? 7.3. DYNAMICS OF NANO
Page 186 and 187: 7.3. DYNAMICS OF NANOMAGNETS 175 Fi
Page 188: 16 w U 3 10 2 U w i 6 , , , , ,,, ,
Page 191 and 192: 180 NANOSTRUCTURED FERROMAGNETISM 0
Page 193 and 194: 182 NANOSTRUCTURED FERROMAGNETISM N
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Page 203 and 204: 192 NANOSTRUCTURED FERROMAGNETISM d
Page 205 and 206: 8 OPTICAL AND VIBRATIONAL SPECTROSC
Page 207 and 208: 196 OPTICAL AND VIBRATIONAL SPECTRO
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206 OPTICAL AND VIBRATIONAL SPECTRO
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QUANTUM WELLS, WIRES, AND DOTS 9.1.
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f37 228 QUANTUM WELLS, WIRES, AND D
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230 QUANTUM WELLS. WIRES, AND DOTS
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232 QUANTUM WELLS, WIRES, AND DOTS
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258 SELF-ASSEMBLY AND CATALYSIS err
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260 SELF-ASSEMBLY AND CATALYSIS the
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262 SELF-ASSEMBLY AND CATALYSIS Fig
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264 SELF-ASSEMBLY AND CATALYSIS pas
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266 SELF-ASSEMBLY AND CATALYSIS 351
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268 SELF-ASSEMBLY AND CATALYSIS sam
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270 SELF-ASSEMBLY AND CATALYSIS I I
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272 SELF-ASSEMBLY AND CATALYSIS 20
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278 SELF-ASSEMBLY AND CATALYSIS /O\
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280 SELF-ASSEMBLY AND CATALYSIS so,
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282 ORGANIC COMPOUNDS AND POLYMERS
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12 BIOLOGICAL MATERIALS 12.1. INTRO
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31 2 BIOLOGICAL MATERIALS Another c
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12.2. BIOLOGICAL BUILDING BLOCKS 31
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NAME Glycine Alanine Valine Threoni
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Attachment point for next desoxyrib
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12.3. NUCLEIC ACIDS 321 Figure 12.1
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12.3. NUCLEIC ACIDS 323 alphabet th
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12.4. BIOLOGICAL NANOSTRUCTURES 325
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water water water 0 Air oil 12.4. B
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12.4. BIOLOGICAL NANOSTRUCTURES 329
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1 L+~-&Iq#J FURTHER READING 331 + +
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13.1. MICROELECTROMECHANICAL SYSTEM
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13.2. NANOELECTROMECHANICAL SYSTEMS
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13.2. NANOELECTROMEGHANICAL SYSTEMS
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13.2. NANOELECTROMECHAsrlICAL SYSTE
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CANTILEVER \ \ \ \ 13.3. MOLECULAR
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13.3. MOLECULAR AND SUPRAMOLECULAR
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Gold electrode 13.3. MOLECULAR AND
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FURTHER READING 355 D. Ruger and F!
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358 FORMULAS FOR DIMENSIONALITY Tab
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0 Q) 0 Table A.3. Number of electro
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362 TABULATIONS OF SEMICONDUCTING M
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abalone mollusk, 1 absorption coeff
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one, 324 bongo drum, 2 Bose-Einstei
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explosion, 93 force, 244 interactio
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sublattice, 15 unit cell figure, 12
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hydroxyproline, 324, 325 hyperfoldi
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effective, see effective mass mean
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nuclear fusion, 94 deuterium cluste
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Re (rhenium) nanoparticle magnetic
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thermal conductivity of semiconduct
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Introduction to Nanotechnology

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