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Convened under the auspicious of esteemed endorsers - ISTA

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*Email: ikedaj@jmmc.jpHigh purity alumina (Alumina) and 3 mol% yttria stabilized tetragonal zirconia polycrystalline(3Y-TZP) have been used for hip and knee joint pros<strong>the</strong>ses because <strong>of</strong> <strong>the</strong>ir excellent wearproperty and biocompatibility. Especially, Ceramic-on-ceramic bearing has been applicableeven to younger patients. Recently, various alumina and zirconia composites were developedand proposed as alternatives to Alumina and 3Y-TZP. It was reported that alumina and zirconiacomposites have superior mechanical properties compared with Alumina. However, it was alsoreported that changes in crystal structure <strong>of</strong> zirconia phase in some alumina and zirconiacomposites including commercially available zirconia toughened alumina (ZTA) <strong>under</strong>hydro<strong>the</strong>rmal environment such as human body occurred. Consequently, it is necessary forlonger reliability to improve not only mechanical properties but phase stability <strong>of</strong> zirconia phaseconcurrently. In our previous study, it was confirmed that newly-developed ZTA(BIOCERAM ® AZ209) had good mechanical properties compared with Alumna. However, <strong>the</strong>relationship among mechanical and wear properties, phase stability and microstructure <strong>of</strong>BIOCERAM ® AZ209 is still unclear. In this study, we evaluated <strong>the</strong>se characteristics <strong>of</strong>BIOCERAM ® AZ209 with different microstructures.BIOCERAM ® AZ209 powder, which composed <strong>of</strong> Al 2 O 3 (79 wt %), ZrO 2 (19 wt %) and o<strong>the</strong>roxides (2 wt %), were pressed into <strong>the</strong> solid form. Green bodies were sintered at varioustemperatures in air and <strong>the</strong>n HIP (hot isotopic press) treatment was subjected. The densespecimens with over 99.9% <strong>of</strong> <strong>the</strong>oretical density were turned to prescribed shapes and fivekinds specimens with several grain sizes and crystal structures were prepared. Microstructures<strong>of</strong> sintered bodies were checked by scanning electron microscope (SEM) and X-raydiffractometer. Mechanical properties were evaluated according to ISO standards. Besides,phase stability <strong>under</strong> hydro<strong>the</strong>rmal environment and specific wear rate in ceramic-on-ceramiccombination were evaluated. Alumina manufactured by Japan Medical Materials Corporationwas used as comparative material <strong>of</strong> each evaluation.In SEM observation, homogeneously dispersion <strong>of</strong> zirconia grains in alumina matrix and noagglomeration <strong>of</strong> zirconia grains were observed. From <strong>the</strong> result <strong>of</strong> X-ray diffraction,monoclinic fraction <strong>of</strong> zirconia phase was calculated by Garvie and Nicholson equation.Increases in both grain size and monoclinic fraction with increasing sintering temperature wereobserved. Besides, with increasing sintering temperature, fracture strength was declined fromabout 1300 to < 500 MPa and fracture toughness was increased from 3.8 to 5.0 MPa·m 1/2 . Bothgrain size and stress induced phase transformation affected <strong>the</strong> fracture strength <strong>of</strong>BIOCERAM ® AZ209, and <strong>the</strong> effect was larger in <strong>the</strong> former than in <strong>the</strong> latter. In allspecimens, no significant change in crystal structure in saturated vapor at 134 °C was observed.It was confirmed that zirconia phase <strong>of</strong> BIOCERAM ® AZ209 was stable as well as Alumina<strong>under</strong> hydro<strong>the</strong>rmal environment. It was possible to support mechanical properties and phasestability at <strong>the</strong> same time. The relationship between wear property with squeaking <strong>under</strong> highload condition and mechanical properties will also be discussed in terms <strong>of</strong> microstructure <strong>of</strong>BIOCERAM ® AZ209.file:///E|/<strong>ISTA</strong>2010-Abstracts.htm[12/7/2011 3:15:47 PM]

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