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Food additives data book - wordpres

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Alginates are composed of blocks of polymannuronic acid, polyguluronic acid and mixed regions.<br />

Ribbon-like structures are formed in solution and alginates with a high percentage of guluronic blocks<br />

can be cross-linked (gelled) by divalent ions (e.g. calcium)<br />

SYNERGISTS: Divalent ion, pectins<br />

ANTAGONISTS: None known<br />

FOOD SAFETY ISSUES: LD 50 (intravenous, rat) 1,000 mg/kg; ADI 0–50 mg/kg<br />

The powder is combustible and emits toxic fumes when heated<br />

LEGISLATION: Usage level: Limitation 0.4% (confections); 0.5% (fats/oils); 0.5% (gelatins/puddings); 0.4%<br />

(gravies/sauces); 0.5% (sweet sauces); 0.1% (other foods)<br />

USA: UK and EUROPE: AUSTRALIA/PACIFIC RIM:<br />

FDA 21CFR § 173.310, 184.1133, UK: approved; Japan: approved<br />

GRAS, USDA 9CFR 318.7 Europe: listed<br />

REFERENCES: Ash, M., and Ash, I. (1996) <strong>Food</strong> Additives. Gower Publishing Co., Brookfield, VT.<br />

Clare, K. (1993) Algin. In: Whistler R. L. and J. N. BeMiller (Eds.), Industrial Gums:<br />

Polysaccharides and Derivatives. 3rd Edition, pp. 105–143.<br />

ANY OTHER RELEVANT INFORMATION: Alginates are natural polysaccharides which are extracted from brown seaweeds (Phaeophyceae).<br />

Macrocystis pyrifera, Laminera hyperborea, Laminaria digitata, Laminaria japonica, Ascophyllum<br />

nodosum, Ecklonia maxima and Lessonia nigrescens are the most important commercial sources of<br />

alginates. Structurally distinct bacterial alginates can be obtained from Pseudomonas species and<br />

Azotobacter species. Although algin, alginic acid, ammonium alginate, calcium alginate, potassium<br />

alginate and sodium alginate are essentially different states of the same type of compound, for<br />

legislative purposes they are listed separately<br />

Ammonium alginate 667

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