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Food additives data book - wordpres

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TECHNOLOGY OF USE IN FOODS: Carrageenans should be dispersed in cold water and heated for 10 minutes at 80°C to hydrate the<br />

polysaccharide. A high shear mixer will aid dispersion, although prolonged shear of high molecularweight<br />

polymers will reduce the viscosity.<br />

Commercially available grades of carrageenan are complex mixtures of a wide range of carrageenans<br />

(kappa, iota, lambda, etc.) with different molecular weights, a range of different cations (chiefly<br />

potassium, sodium and calcium) and other constituents (e.g. polysorbate 80, celluloses in semi-refined<br />

carrageenans). Consequently the functional properties of carrageenan extracts are extremely diverse.<br />

Extracts with a high concentration of lambda-carrageenans do not gel at all but can be useful<br />

thickeners. Lambda-carrageenans can interact with proteins below the protein isoelectric point, and this<br />

interaction has been used to improve the stability of protein products<br />

SYNERGISTS: Proteins; chitosan<br />

ANTAGONISTS: Any positive or negatively charged molecule is a potential antagonist<br />

FOOD SAFETY ISSUES: Suspected carcinogen. May induce colonic ulcers. The powder is combustible<br />

LEGISLATION: USA: UK and EUROPE: AUSTRALIA/PACIFIC RIM:<br />

FDA 21CFR § 172.620, UK: approved. Japan: approved for use as a<br />

172.623, 172.626, Europe: listed. Carrageenans extracted natural thickener and stabiliser<br />

182.7255. GRAS. USDA using traditional aqueous extraction<br />

9CFR § 318.7. ADI = methods are labelled E407.<br />

75 mg/kg Carrageenans (PES, PNC, ARC)<br />

extracted using an alternative<br />

commercial method are labelled<br />

E407a<br />

REFERENCES: Ash, M., and Ash, I. (1996) <strong>Food</strong> Additives. Gower Publishing Co., Brookfield, VT.<br />

Craighie, J. S., and Leigh, C. (1978) Carrageenans and Agars. In: Hand<strong>book</strong> of Physiological and<br />

Biochemical Methods. Cambridge University Press, p. 114.<br />

Shepherd, R. (1996) Extraction, purification and characterization of novel carrageenans with<br />

potential applications in dairy products. NZBA.<br />

Therkelsen, G. H. (1993) Carrageenan. In: Whistler, R. L., and J. N. BeMiller (Eds.), Industrial<br />

Gums: Polysaccharides and Derivatives. 3rd edition, pp. 145–180.<br />

Lambda-carrageenan 681

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