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Food additives data book - wordpres

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The viscosity of carboxymethyl celluloses is relatively constant between pH 4 and 10, but increases<br />

below pH 4 due to formation of the acid form of the molecule. Medium to high molecular-weight<br />

molecules with 0.9 to 1.2 substitutions per sugar unit exhibit pseudoplastic behaviour (shear-dependent<br />

thinning), whereas at 0.4 to 0.7% substitution the solutions exhibit thixotropy (time-dependent<br />

thinning). Gels can be formed in the presence of trivalent ions like aluminium<br />

SYNERGISTS: Trivalent cations, non-ionic polymers<br />

ANTAGONISTS: None known<br />

FOOD SAFETY ISSUES: Non-toxic; ADI 0–25mg/kg. The powder is combustible<br />

LEGISLATION: USA: UK and EUROPE: AUSTRALIA/PACIFIC RIM:<br />

FDA 21CFR § 133.134, 133.178, UK: approved. Japan: restricted (2% max)<br />

133.179, 1150.141, 150.161, 173.310, Europe: listed<br />

175.105, 175.300, 182.70, 182.1745,<br />

GRAS, USDA 9CFR § 318.7<br />

REFERENCES: Ash, M., and Ash, I. (1996) <strong>Food</strong> Additives. Gower Publishing Co., Brookfield, VT.<br />

Feedersen, R. L., and Thorp, S. N. (1993) Sodium carboxymethylcellulose. In: Whistler, R. L., and<br />

J. N. BeMiller (Eds.), Industrial Gums: Polysaccharides and Derivatives. 3rd edition, pp. 537–577.<br />

ANY OTHER RELEVANT INFORMATION: Chemically carboxymethylated natural cellulose.<br />

See also methyl ethyl cellulose (MEC); hydroxy propyl methyl cellulose (HPMC); hydroxy propyl<br />

cellulose (HPC); and methyl cellulose (MC)<br />

Carboxymethylcellulose 693

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