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Studies on the use of nano zinc oxide and modified silica in NR, CR ...

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Use <strong>of</strong> <strong>nano</strong> <strong>z<strong>in</strong>c</strong> <strong>oxide</strong> <strong>in</strong> chloroprene rubber<br />

VÉÇàxÇàá<br />

5.1 Introducti<strong>on</strong><br />

5.1 Introducti<strong>on</strong><br />

5.2 Experimental<br />

5.3 Results <strong>and</strong> discussi<strong>on</strong><br />

5.4 C<strong>on</strong>clusi<strong>on</strong>s<br />

5.5 References<br />

Syn<strong>the</strong>tic rubbers are more uniform <strong>in</strong> quality <strong>and</strong> compounds are<br />

more c<strong>on</strong>sistent <strong>in</strong> both process<strong>in</strong>g <strong>and</strong> product properties. 1 There are polar<br />

<strong>and</strong> n<strong>on</strong>-polar syn<strong>the</strong>tic rubbers. Polychloroprene known as neoprene is a<br />

polar rubber <strong>and</strong> is generally c<strong>on</strong>sidered as a special purpose rubber be<strong>in</strong>g<br />

<strong>use</strong>d for applicati<strong>on</strong>s requir<strong>in</strong>g oil <strong>and</strong> solvent resistance.<br />

There has been a l<strong>on</strong>g st<strong>and</strong><strong>in</strong>g commercial need for oil resistant<br />

elastomers. 2 For example, oil resistant materials are very important to <strong>the</strong><br />

automotive <strong>in</strong>dustry s<strong>in</strong>ce a variety <strong>of</strong> comp<strong>on</strong>ents may come <strong>in</strong> c<strong>on</strong>tact with<br />

a number <strong>of</strong> fluids. In <strong>the</strong> specific case <strong>of</strong> eng<strong>in</strong>e seals, it is important that<br />

<strong>the</strong>y be able to withst<strong>and</strong> <strong>the</strong> fluids <strong>the</strong>y are seal<strong>in</strong>g without los<strong>in</strong>g <strong>the</strong>ir<br />

ability to ma<strong>in</strong>ta<strong>in</strong> <strong>the</strong> seal ei<strong>the</strong>r by becom<strong>in</strong>g too s<strong>of</strong>t or too brittle. 3<br />

Exam<strong>in</strong><strong>in</strong>g <strong>the</strong> specific reas<strong>on</strong>s for <strong>the</strong> chemical resistance <strong>of</strong> polymers, it can<br />

be seen that polar side groups tend to provide resistance to swell<strong>in</strong>g <strong>in</strong><br />

hydrocarb<strong>on</strong> oils. 4 This <strong>in</strong>duces slight electr<strong>on</strong>egative charge <strong>on</strong> <strong>the</strong><br />

electr<strong>on</strong>egative atom with a slight positive around <strong>the</strong> carb<strong>on</strong> atom. The<br />

dipole moment produced tends to provide oil resistance. As <strong>the</strong><br />

electr<strong>on</strong>egativity <strong>of</strong> <strong>the</strong> side cha<strong>in</strong> group <strong>in</strong>creases <strong>on</strong> a polymer, so does its

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