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Studies on the use of nano zinc oxide and modified silica in NR, CR ...

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Chapter 1<br />

Mechanical process<br />

8<br />

These <strong>in</strong>clude gr<strong>in</strong>d<strong>in</strong>g, mill<strong>in</strong>g <strong>and</strong> mechanical alloy<strong>in</strong>g techniques.<br />

Provided that <strong>on</strong>e can produce a coarse powder as a feed stock, <strong>the</strong>se process<br />

utilize <strong>the</strong> age-old technique <strong>of</strong> physically pound<strong>in</strong>g coarse powders <strong>in</strong>to<br />

f<strong>in</strong>er <strong>and</strong> f<strong>in</strong>er <strong>on</strong>es, which is similar to <strong>the</strong> gr<strong>in</strong>d<strong>in</strong>g flour mills. Today, <strong>the</strong><br />

most comm<strong>on</strong> processes make <strong>use</strong> <strong>of</strong> ei<strong>the</strong>r planetary or rotat<strong>in</strong>g ball mills.<br />

The advantages <strong>of</strong> <strong>the</strong>se techniques are that <strong>the</strong>y are simple <strong>and</strong> require low-<br />

cost equipment. However, <strong>the</strong>re can be difficulties such as agglomerati<strong>on</strong> <strong>of</strong><br />

<strong>the</strong> powders, broad particle size distributi<strong>on</strong>s <strong>and</strong> c<strong>on</strong>tam<strong>in</strong>ati<strong>on</strong> from <strong>the</strong><br />

process equipment itself. Often <strong>the</strong>re would be difficulty <strong>in</strong> gett<strong>in</strong>g <strong>the</strong> very<br />

f<strong>in</strong>e particle sizes with viable yields. It is comm<strong>on</strong>ly <strong>use</strong>d for <strong>in</strong>organic<br />

materials <strong>and</strong> not for organic materials.<br />

Us<strong>in</strong>g templates to form <strong>nano</strong>particles<br />

Any materials c<strong>on</strong>ta<strong>in</strong><strong>in</strong>g regular <strong>nano</strong>-sized pores or voids can be<br />

<strong>use</strong>d as a template to form <strong>nano</strong>particles. Examples <strong>of</strong> such templates <strong>in</strong>clude<br />

porous alum<strong>in</strong>a, zeolites, diblock co-polymers, dendrimers, prote<strong>in</strong>s <strong>and</strong><br />

o<strong>the</strong>r molecules. The template does not have to be a 3D object. Artificial<br />

templates can be created <strong>on</strong> a plane surface or <strong>on</strong> a gas-liquid <strong>in</strong>terface by<br />

form<strong>in</strong>g self-assembled m<strong>on</strong>o layers.<br />

1.3 Polymer matrices - Elastomers<br />

Different types <strong>of</strong> polymers are <strong>use</strong>d as matrices <strong>in</strong> composites.<br />

Elastomers are <strong>on</strong>e <strong>of</strong> <strong>the</strong> most <strong>in</strong>terest<strong>in</strong>g materials <strong>on</strong> account <strong>of</strong> its range <strong>of</strong><br />

applicati<strong>on</strong>s. These polymers have unique properties <strong>of</strong> deformati<strong>on</strong> <strong>and</strong><br />

elastic recovery after vulcanizati<strong>on</strong> with sulphur or o<strong>the</strong>r cross l<strong>in</strong>k<strong>in</strong>g agent,<br />

which <strong>in</strong> effect change <strong>the</strong> polymer from <strong>the</strong>rmoplastic to <strong>the</strong>rmosett<strong>in</strong>g.<br />

Natural rubber (<strong>NR</strong>) is a comm<strong>on</strong>ly <strong>use</strong>d rubber <strong>and</strong> has been <strong>use</strong>d for <strong>the</strong><br />

producti<strong>on</strong> <strong>of</strong> different products.

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