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Studies on the use of nano zinc oxide and modified silica in NR, CR ...

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Chapter 7<br />

126<br />

Torque (dNm)<br />

12<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

0 20 40<br />

Time (m<strong>in</strong>)<br />

nr ppt<br />

10<br />

8<br />

neat<br />

6<br />

IPPD<br />

4<br />

nr brab<br />

2<br />

IPPD 0<br />

Torque (dNm)<br />

0 20<br />

Time (m<strong>in</strong>)<br />

40<br />

(a) (b)<br />

Torque (dNm)<br />

12<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

0 20 40<br />

Time (m<strong>in</strong>)<br />

(c)<br />

nr philflex<br />

neat<br />

nr philflex<br />

brab<br />

nr<br />

6ppd<br />

brab<br />

nr<br />

6ppd<br />

neat<br />

Figure 7.1 Cure graphs <strong>of</strong> compounds filled with antioxidant <strong>modified</strong> <strong>silica</strong> (nr<br />

IPPD, 6PPD,DPPD(philflex) brabender mixed) <strong>and</strong> with neat <strong>silica</strong><br />

(nr IPPD,6PPD,DPPD(philflex) neat)<br />

7.3.3 Tensile properties<br />

Tensile properties <strong>of</strong> <strong>NR</strong> vulcanizates with antioxidant <strong>modified</strong><br />

<strong>silica</strong> <strong>and</strong> with neat <strong>silica</strong> are shown <strong>in</strong> Table 7.4.<br />

Vulcanizate<br />

Table 7.4 Tensile properties <strong>of</strong> <strong>NR</strong> vulcanizates<br />

Tensile<br />

strength, Mpa<br />

Tensile modulus at<br />

300% el<strong>on</strong>gati<strong>on</strong>, Mpa<br />

El<strong>on</strong>gati<strong>on</strong> at break<br />

%<br />

Tear strength<br />

(N/mm)<br />

E-1 23.28 3.50 966 59<br />

E-2 22.60 3.27 1027 54<br />

F-1 21.05 2.93 1017 60<br />

F-2 20.58 2.76 1066 56<br />

G-1 16.27 2.60 995 56<br />

G-2 16.19 2.52 1036 54

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