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Studies on the use of nano zinc oxide and modified silica in NR, CR ...

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Nanophase material: They are same as <strong>nano</strong>structured material.<br />

Introducti<strong>on</strong><br />

Quantum dot: A particle that exhibits a size quantizati<strong>on</strong> effect <strong>in</strong> at least <strong>on</strong>e<br />

dimensi<strong>on</strong>.<br />

1.2.2 Preparati<strong>on</strong> <strong>of</strong> <strong>nano</strong>materials<br />

There are two general ways available to produce <strong>nano</strong>materials. The<br />

first way is to start with bulk material <strong>and</strong> <strong>the</strong>n break it <strong>in</strong>to smaller<br />

pieces us<strong>in</strong>g mechanical, chemical or o<strong>the</strong>r form <strong>of</strong> energy (top-down). An<br />

opposite approach is to syn<strong>the</strong>size <strong>the</strong> material from atomic or molecular<br />

species via chemical reacti<strong>on</strong>s <strong>and</strong> allow <strong>the</strong> precursor particles to grow <strong>in</strong><br />

size (bottom-up). Both approaches can be d<strong>on</strong>e <strong>in</strong> ei<strong>the</strong>r gas, liquid, super<br />

critical fluids, solid states or <strong>in</strong> vacuum. 5-9 Most <strong>of</strong> <strong>the</strong> manufacturers are<br />

<strong>in</strong>terested <strong>in</strong> <strong>the</strong> ability to c<strong>on</strong>trol: a) particle size b) particle shape c) size<br />

distributi<strong>on</strong> d) particle compositi<strong>on</strong> e) degree <strong>of</strong> particle agglomerati<strong>on</strong>. 10-12<br />

Process <strong>use</strong>d for bottom–up manufactur<strong>in</strong>g 13<br />

Methods to produce <strong>nano</strong>particles from atoms are chemical processes<br />

based <strong>on</strong> transformati<strong>on</strong>s <strong>in</strong> soluti<strong>on</strong>. (e.g., sol-gel process<strong>in</strong>g, chemical<br />

vapour depositi<strong>on</strong> (CVD), plasma or flame spray<strong>in</strong>g syn<strong>the</strong>sis, laser<br />

pyrolysis, 14 atomic or molecular c<strong>on</strong>densati<strong>on</strong>. These chemical processes rely<br />

<strong>on</strong> <strong>the</strong> availability <strong>of</strong> appropriate “metal-organic” molecules as precursors.<br />

Sol–gel process<strong>in</strong>g differs from o<strong>the</strong>r chemical processes due to its relatively<br />

low process<strong>in</strong>g temperature. This makes <strong>the</strong> sol–gel process cost effective <strong>and</strong><br />

versatile. In spray<strong>in</strong>g processes, <strong>the</strong> flow <strong>of</strong> reactants (gas, liquid <strong>in</strong> form <strong>of</strong><br />

aerosols or mixtures <strong>of</strong> both) is <strong>in</strong>troduced to high-energy flame produced by<br />

plasma spray<strong>in</strong>g equipments or carb<strong>on</strong> di<strong>oxide</strong> laser. The reactants<br />

decompose <strong>and</strong> particles are formed <strong>in</strong> a flame by homogeneous nucleati<strong>on</strong><br />

<strong>and</strong> growth. Rapid cool<strong>in</strong>g results <strong>in</strong> <strong>the</strong> formati<strong>on</strong> <strong>of</strong> <strong>nano</strong>scale particles.<br />

5

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