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Studies on the use of nano zinc oxide and modified silica in NR, CR ...

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Chapter 1<br />

<strong>the</strong> pa<strong>in</strong>t <strong>in</strong>dustry, <strong>in</strong> its c<strong>on</strong>stant development <strong>of</strong> improved products, has<br />

utilized various aspects <strong>of</strong> those properties to high degree.<br />

18<br />

Manufacturers discovered that <strong>the</strong>y could produce coat<strong>in</strong>gs <strong>of</strong><br />

brush<strong>in</strong>g c<strong>on</strong>sistency <strong>and</strong> good suspensi<strong>on</strong> properties by <strong>in</strong>corporati<strong>on</strong> <strong>of</strong><br />

ZnO <strong>in</strong>to <strong>the</strong>ir pastes. Pa<strong>in</strong>ters noted that <strong>the</strong>y furnished better hid<strong>in</strong>g power,<br />

whiteness, cleaner t<strong>in</strong>ts, t<strong>in</strong>t retenti<strong>on</strong> <strong>and</strong> durability as well as n<strong>on</strong>darken<strong>in</strong>g<br />

<strong>in</strong> <strong>the</strong> presence <strong>of</strong> sulfur fumes. French-process ZnO has been proved<br />

superior to American-process type <strong>in</strong> fungus resistance <strong>and</strong> less sulphide<br />

sta<strong>in</strong><strong>in</strong>g.<br />

Metal – protective coat<strong>in</strong>gs<br />

Z<strong>in</strong>c metal powder (<strong>z<strong>in</strong>c</strong> dust) <strong>and</strong> <strong>z<strong>in</strong>c</strong> compounds have l<strong>on</strong>g been<br />

utilized for <strong>the</strong>ir anticorrosive properties <strong>in</strong> metal-protective coat<strong>in</strong>gs, <strong>and</strong><br />

today <strong>the</strong>y are <strong>the</strong> basis <strong>of</strong> such important especially metal primers as <strong>z<strong>in</strong>c</strong><br />

chromate primers.<br />

Z<strong>in</strong>c dust-ZnO pa<strong>in</strong>ts are especially <strong>use</strong>ful as primers for new or<br />

wea<strong>the</strong>red galvanized ir<strong>on</strong>. Such surfaces are difficult to protect beca<strong>use</strong> <strong>the</strong>ir<br />

reactivity with organic coat<strong>in</strong>gs leads to brittleness <strong>and</strong> lack <strong>of</strong> adhesi<strong>on</strong>. Z<strong>in</strong>c<br />

dust- ZnO pa<strong>in</strong>ts however, reta<strong>in</strong> <strong>the</strong>ir flexibility <strong>and</strong> adherence <strong>on</strong> such<br />

surfaces for many years. These pa<strong>in</strong>ts also provide excellent protecti<strong>on</strong> to<br />

steel structures under normal atmospheric c<strong>on</strong>diti<strong>on</strong>s, as well as to steel<br />

surfaces <strong>in</strong> such under-water c<strong>on</strong>diti<strong>on</strong>s as dam faces <strong>and</strong> <strong>the</strong> <strong>in</strong>terior <strong>of</strong> fresh<br />

water tanks.<br />

Fire retardants<br />

ZnO <strong>and</strong> its derivatives were <strong>use</strong>d extensively <strong>in</strong> fire retardants for<br />

<strong>the</strong> military <strong>in</strong> World War II <strong>and</strong> those <strong>z<strong>in</strong>c</strong> compounds have s<strong>in</strong>ce been <strong>the</strong><br />

subject <strong>of</strong> extensive research <strong>and</strong> development for preparati<strong>on</strong> <strong>of</strong> fire-<br />

retardant compositi<strong>on</strong>s for a variety <strong>of</strong> substances. Soluti<strong>on</strong>s for firepro<strong>of</strong><strong>in</strong>g

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