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R. Meyer J. Köhler A. Homburg Explosives

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91 1,1-Diamino-2,2-dinitroethylene<br />

Dynamics of Explosions, Editor: Bowen, J. R., Leyer, J. C. and Soloukhin, R. I.,<br />

AIAA, New York 1986 (Progress in Astronautics and Aeronautics, Vol. 106)<br />

Dynamics of Explosions, Editor: Kuhl, A. L., Bowen, J. R., Leyer, J. C. and<br />

Borisov, A., AIAA, New York 1988 (Progress in Astronautics and Aeronautics,<br />

Vol. 114)<br />

Cheret, R.: La detonation des explosifs condenses, part 1 and 2, Masson, Paris<br />

1988/89 Medard, L.: Accidental Explosions, Vol. 1: Physical and Chemical<br />

Properties, Vol. 2: Types of Explosive Substances, Ellis Horwood Ltd. Chichester<br />

1989 (English translation)<br />

Detonator<br />

détonateur<br />

Part of an explosive train which initiates the W detonation of high<br />

explosives, especially of insensitive ones. It may itself be triggert by a<br />

seperate W primer of primary explosives or an integrated primer. Detonators<br />

are classified by the method of initiation: percussion, stab,<br />

electrical impulse, or flash. Laser initiation is also used. Depending on<br />

the application detornators can include a delay mechanism. Explosive<br />

charge placed in certain equipment and set to destroy the equipment<br />

under certain conditions (W Initiator).<br />

1,1-Diamino-2,2-dinitroethylene<br />

DADNE, DADE, FOX-7<br />

H 2 N<br />

H 2 N<br />

NO 2<br />

NO 2<br />

Yellow crystals<br />

sum formula: C2H4N4O4<br />

molecular weight: 148.08 g<br />

energy of formation: –119 kJ/mole<br />

enthalpy of formation: –133.9 kJ/mole<br />

oxygen balance: –21.61%<br />

volume of explosion gases 779 l/kg<br />

heat of explosion (calculated): 4091J/g (H2O gas);<br />

4442 J/g (H2O liq.)<br />

density:<br />

a polymorph 1.89 g/cm 3<br />

b polymorph 1.80 g/cm 3<br />

specific energy: 1156 J/g<br />

detonation velocity 8869 m/s<br />

deflagration point 215 °C<br />

mech. sensitivity 20– 40 Nm (impact); > 550 N (friction)

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