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R. Meyer J. Köhler A. Homburg Explosives

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Thermodynamic Calculation of Decomposition Reactions<br />

Table 33. (continued)<br />

Component Empirical Enthalpy Enthalpy Energy Energy Number of Atoms per kilogram Uses<br />

Formula of Forma- of Formationof Forma- of Formation<br />

tiontion<br />

kcal/kg kJ/kg kcal/kg kJ/kg C H O N<br />

326<br />

Hexanitrohexaaza-<br />

C6H6N12O12 + 299.0 + 920.5 + 240.3 + 1005.3 13.69 13.69 27.39 27.39 (2); (4)<br />

isowurtzitane (CL20)<br />

Hexogen (RDX) C3H6O6N6 + 72 + 301.4 + 96.0 + 401.8 13.50 27.01 27.01 17.01 (2)<br />

hydrazine H4N2 + 377.5 + 1580 + 433.1 + 1812 – 124.80 – 62.40 (6)<br />

hydrazine nitrate H5O3N3 – 620.7 – 2597 – 586.4 – 2453 – 52.60 31.56 31.56 (2); (4)<br />

iron acetylacetonate C15H21O6Fe – 859 – 3593 – 836 – 3498 42.47 59.46 16.99 – (9)<br />

kerosene – 540 – 2260 – 500 – 2100 71.90 135.42 – – (6)<br />

lead acetylsalicylate·H2O C18H16O9Pb – 823 – 3444 – 810 – 3391 30.85 27.42 15.42 – Fb:<br />

1.71 (9)<br />

lead azide N6Pb + 391.4 + 1638 + 397.5 + 1663 – – – 20.60 Pb:<br />

3.43 (1)<br />

lead ethylhexanoate C16H30O4Pb – 724 – 3027 – 703 – 2940 32.41 60.78 8.10 – Pb:<br />

2.03 (9)<br />

lead nitrate O6N2Pb – 326.1 – 1364 – 318.9 – 1334 – – 18.11 6.04 Fb:<br />

3.02 (5)<br />

lead styphnate C6H3O9N3Pb – 427.1 – 1787 – 417.6 – 1747 12.81 6.41 19.22 6.41 Pb:<br />

2.13 (1)<br />

magnesium carbonate O3CMg –3106 –12994 –3095 –12950 11.86 – 35.60 – Mg:<br />

11.86 (14); (15)<br />

mannitol hexanitrate C6H8O18N6 – 357.2 – 1494 – 336.2 – 1407 13.27 17.70 39.82 13.27 (2)<br />

methylamine<br />

CH6O3N2 – 896 – 3748 – 862 – 3604 10.63 63.78 31.89 21.26 (17)<br />

nitrate (MAN)<br />

metriol trinitrate C5H9O9N3 – 398.2 – 1666 – 373.8 – 1564 19.60 35.27 35.27 11.76 (4)<br />

Nitroaminoguanidine C1H5N5O2 + 44.3 + 185.5 + 74.2 + 310.2 8.40 41.99 16.79 41.99 (4)<br />

nitrocellulose, 13.3% N – 577.4 – 2416 – 556.1 – 2327 21.10 25.83 36.66 9.50 (4)<br />

nitrocellulose, 13.0% N – 596.1 – 2494 – 574.6 – 2404 21.55 26.64 36.52 9.28 (4)<br />

nitrocellulose, 12.5% N – 627.2 – 2624 – 605.6 – 2534 22.15 27.98 36.30 8.92 (4)

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