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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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Triethyleneglycol Dinitrate<br />

molecular weight: 240.1<br />

energy of formation: –598.9 kcal/kg = –2505.8 kJ/kg<br />

enthalpy of formation: –626.0 kcal/kg = –2619.2 kJ/kg<br />

oxygen balance: –66.7%<br />

nitrogen content: 11.67%<br />

volume of explosion gases: 1065 l/kg<br />

heat of explosion<br />

(H2O liq.): 793 kcal/kg = 3317 k/kg<br />

specific energy:<br />

91.7 mt/kg = 899 kJ/kg<br />

density: 1.335 g/cm3 lead block test: 320 cm3 /10 g<br />

deflagration point: 195 °C = 383 °F<br />

impact sensitivity: 1.3 kp m = 12.7 N m<br />

Triglycol dinitrate is less volatile than W Diethylenglycol Dinitrate. It<br />

gelatinizes nitrocellulose just as well as diglycol dinitrate, i.e., better<br />

than nitroglycerine.<br />

Its chemical stability is better than that of nitroglycerine or nitrocellulose,<br />

and at least as good as that of diglycol dinitrate.<br />

Triglycol dinitrate is prepared by nitration of triglycol with mixed acid.<br />

The solubility of triglycol dinitrate in the waste acid is very high (~9%).<br />

It is particularly suited for the production of low caloric W Double Base<br />

Propellants.<br />

Specifications<br />

density 20/4: 1.1230–<br />

1.1234 g/cm 3<br />

boiling analysis,<br />

start: not below 280 °C = 536 °F<br />

90 % distilled: not over 295 °C = 563 °F<br />

moisture: not more than 0.5 %<br />

chlorides: not more than traces<br />

acid, as H2SO4: not more than<br />

saponification value,<br />

0.02 %<br />

as Na2O: not more than<br />

reducing matter<br />

0.05 %<br />

(AgNO3-NH3-test): none<br />

344

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