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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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MAPO<br />

detonation velocity, confined:<br />

8260 m/s = 27100 ft/s at r = 1.73 g/cm3 deflagration point: 185 °C = 365 °F<br />

impact sensitivity: 0.08 kp m = 0.8 N m<br />

Nitromannitol is insoluble in water, but is soluble in acetone, ether and<br />

hot alcohol; it is difficult to stabilize.<br />

It is prepared by dissolving mannitol in cold concentrated nitric acid<br />

and precipitating it with cold concentrated sulfuric acid. The crude<br />

product is washed with a dilute bicarbonate solution and with water,<br />

and is then recrystallized from hot alcohol.<br />

In the USA nitromannitol was used as a filling for W Blasting Caps.<br />

MAPO<br />

Abbreviation for methylaziridine phosphine oxide, a bonding agent for<br />

AP containing W Composite Propellants.<br />

empirical formula: C9H18N3OP<br />

molecular weight: 215.14<br />

density: 1.08 g/cm 3<br />

boiling point at 0.004 bar: 120 °C = 248 °F<br />

Mass Explosion Risk<br />

208<br />

Massen-Explosionsfähigkeit, Massen-Explosionsgefährlichkeit;<br />

danger d’explosion en masse<br />

A term describing the behavior of explosive materials and items<br />

(chiefly ammunition) in bulk. The question to be answered is whether a<br />

local explosion or fire will or will not detonate the entire bulk of the<br />

explosive (a truckload, or even a shipload of explosives). A number of<br />

tests have been laid down, in which first a parcel, then a case, and<br />

finally a caseload – in the form in which it is to be dispatched – are<br />

primed or inflamed in the manner in which this is to be done in actual<br />

service. When testing a caseload, the cases are arranged in predetermined<br />

locations, covered by inert cases of identical construction,<br />

and ignited.<br />

Mass explosion risk does not depend solely on the properties of the<br />

explosive material, but also on the stacking height (in extreme cases,<br />

an entire shipload), on the nature of the confinement (e.g., buildings,

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