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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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131 <strong>Explosives</strong><br />

W Class A <strong>Explosives</strong> – Detonating, or otherwise maximum hazard.<br />

W Class S <strong>Explosives</strong> – Flammable hazard.<br />

W Class C <strong>Explosives</strong> – Minimum hazard.<br />

Oxidizing Material – A substance that yields oxygen readily to<br />

stimulate the combustion of organic matter<br />

(W Oxidizer)<br />

A list of energetic materials is also available from the German BAM.<br />

Explosive Train<br />

A train of combustible and explosive elements arranged in order of<br />

decreasing sensitivity. The explosive train accomplishes the controlled<br />

augmentation of a small impulse into one of suitable energy to actuate<br />

a main charge. A fuze explosive train may consist of a primer, a<br />

detonator, a delay, a relay, a lead and booster charge, one or more of<br />

which may be either omitted or combined. If the bursting charge is<br />

added to the foregoing train it becomes a bursting charge explosive<br />

train. A propelling charge explosive train might consist of a primer,<br />

igniter or igniting charge, usually black powder, and finally, any of the<br />

various types of propellants (W Igniter Train).<br />

<strong>Explosives</strong><br />

Explosivstoffe; explosifs<br />

1. Definition<br />

<strong>Explosives</strong> are solid or liquid*) substances, alone or mixed with one<br />

another, which are in a metastable state and are capable, for this<br />

reason, of undergoing a rapid chemical reaction without the participation<br />

of external reactants such as atmospheric oxygen. The reaction<br />

can be initiated by mechanical means (impact, W Impact Sensitivity;<br />

friction, W Friction Sensitivity), by the action of heat (sparks, open<br />

flame, red-hot or white-hot objects), or by detonating shock (W Blasting<br />

Cap with or without a W Booster charge). The resistance of the<br />

metastable state to heat is known as W Stability. The ease with which<br />

the chemical reaction can be initiated is known as W Sensitivity.<br />

The reaction products are predominantly gaseous (W Fumes). The<br />

propagation rate from the initiation site outwards through the explosive<br />

* Of course, gases and gaseous mixtures can also be explosive. Explosive<br />

mixtures are often generated spontaneously (leaks in gas pipes, solvent tanks;<br />

firedamp in coal mining).

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