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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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Diamyl Phthalate<br />

DADNE is a relatively new, low sensitive high explosive developed by<br />

the Swedish Defence Research Agency FOI. It is insoluble in cold<br />

water, slightly soluble in acetonitrile and cyclohexanone, soluble in<br />

DMSO, dimethylformamide and N-methylpyrrolidinone. Besides, it can<br />

cause allergic skin reactions.<br />

DADNE is of interest for the development of IM-propellants and explosives.<br />

Three polymorphs a, b and g were found by means of X-ray<br />

diffraction, but only a-polymorph is stable at room temperature. Transitions<br />

occur on heating from a to b and b to g at 113 and 173 °C,<br />

respectively.<br />

Diamyl Phthalate<br />

Diamylphthalat; phthalate diamylique<br />

colorless liquid<br />

empirical formula: C18H26O4<br />

molecular weight: 306.4<br />

energy of formation: –692.0 kcal/kg = –2895.2 kJ/kg<br />

enthalpy of formation: –721.0 kcal/kg = –3016.5 kJ/kg<br />

oxygen balance: –235.0%<br />

Diamyl phthalate is used as an additive to gunpowders, both for the<br />

purpose of gelatinization and to effect W Surface Treatment.<br />

Diazodinitrophenol<br />

diazodinitrophénol; Dinol, Diazol; D.D.N.P.<br />

red yellow amorphous powder<br />

empirical formula: C6H2N4O5<br />

molecular weight: 210.1<br />

energy of formation: +236.4 kcal/kg = +988.9 kJ/kg<br />

enthalpy of formation: +220.8 kcal/kg = +924.0 kJ/kg<br />

oxygen balance: –60.9%<br />

nitrogen content: 26.67%<br />

density: 1.63 g/cm 3<br />

lead block test: 326 cm 3 /10 g<br />

detonation velocity, confined: 6600 m/s = 21700 ft/s<br />

92

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