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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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351 2,4,6-Trinitrocresol<br />

Pressure Temperature<br />

millibar °C °F<br />

0.05 83 181 melting point<br />

0.2 100 212<br />

2.0 150 302<br />

12.5 200 392<br />

100 270 518<br />

lead block test: 315 cm3 /10 g<br />

detonation velocity, confined:<br />

7200 m/s = 23600ft/s at r = 1.74 g/cm3 deflagration point: 395– 400 °C<br />

impact sensitivity: 1.6 kp m = 16 N m<br />

friction sensitivity: up to 36 kp = 353 N<br />

pistil load no reaction<br />

Trinitrochlorobenzene is sparingly soluble in alcohol and benzene,<br />

somewhat more soluble in ether, and insoluble in water.<br />

It is prepared by nitration of dinitrochlorobenzene. Manufacture is<br />

difficult, and highly concentrated acid must be employed.<br />

Trinitrochlorobenzene is just as insensitive as TNT, its brisance is<br />

somewhat higher, and its density and heat stability are excellent.<br />

2,4,6-Trinitrocresol<br />

Trinitrometakresol; trinitrométacrésol<br />

yellow needles<br />

empirical formula: C7H5N3O7<br />

molecular weight: 243.1<br />

energy of formation: –229.7 kcal/kg = –961.2 kJ/kg<br />

enthalpy of formation: –248.0 kcal/kg = –1038 kJ/kg<br />

oxygen balance: –62.5%<br />

nitrogen content: 17.95%<br />

volume of explosion gases: 844 l/kg<br />

heat of explosion<br />

(H2O liq.): 805 kcal/kg = 3370 kJ/kg<br />

(H2O gas): 776 kcal/kg = 3248 kJ/kg<br />

specific energy: 87.8 mt/kg = 861 kJ/kg

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